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Received May 11, 2019
Accepted August 8, 2019
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A new type of [PEI-glycidyl POSS] nanofiltration membrane with enhanced separation and antifouling performance
Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran
a-moghadassi@araku.ac.ir
Korean Journal of Chemical Engineering, October 2019, 36(10), 1657-1668(12), 10.1007/s11814-019-0359-y
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Abstract
A new type of polyether-imide (PEI)-based nanofiltration membranes was prepared by introducing octaglycidyloxypropyl- silsesquioxane (Glycidyl POSS) into PEI matrix for heavy metals ions removal from water. The separation performance of fabricated membranes in Na2SO4, Pb(NO3)2, Ni(NO3)2 and Cu(NO3)2 removal from water as well as their flux and antifouling property was evaluated. Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) analytical method, atomic force microscope (AFM), porosity, contact angle, and water content were also used in membrane characterization. The results indicated higher hydrophilicity, pure water flux (PWF) and salt rejection for PEI-POSS membranes compared to neat PEI ones. The morphological images showed good tuning porosity, finger- and spongy-like structure. The highest porosity observed for [PEI-1 wt% glycidyl POSS] with the best antifouling property. The surface roughness also decreased by incorporating of POSS into PEI matrix. The pure water flux increased from 14.3 (L/m2h) for neat PEI membrane to 36 (L/m2h) for [PEI-0.1 wt% glycidyl POSS]. Moreover, Na2SO4, Pb(NO3)2, Cu(NO3)2 and Ni(NO3)2 rejection measured 78%, 94%, 99%, 42% for [PEI-1 wt% glycidyl POSS] membrane, whereas they were 69%, 44%, 40% and 16% for the virgin PEI membrane, respectively. Results showed a good potential for [PEI-POSS] membrane in Cu and Pb ions removal beside its high PWF and antifouling ability.
Keywords
References
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Gholami N, Mahdavi H, Adv. Polym. Tech., 37, 3529 (2018)
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Zaman NK, Rohani R, Mohammad AW, Isloor AM, Chem. Eng. Sci., 177, 218 (2018)
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Abdi G, Alizadeh A, Zinadini S, Moradi G, J. Membr. Sci., 552, 326 (2018)
Gherasim CV, Mikulasek P, Desalination, 343, 67 (2014)
Nayak V, Jyothi MS, Balakrishna RG, Padaki M, Deon S, J. Hazard. Mater., 331, 289 (2017)
Zeng GY, He Y, Zhan YQ, Zhang L, Pan Y, Zhang CL, Yu ZX, J. Hazard. Mater., 317, 60 (2016)
Ansari S, Bagheripour E, Moghadassi A, Hosseini SM, J. Polym. Eng., 37, 61 (2017)
Amiri F, Moghadassi A, Bagheripour E, Parvizian F, J. Membr. Sci. Res., 3, 50 (2017)
You X, Wu H, Su Y, Yuan J, Zhang R, Yu Q, Wu M, Jiang Z, Cao X, J. Mater. Chem. A, 6, 13191 (2018)
Ansari S, Moghadassi AR, Hosseini SM, Desalination, 357, 189 (2015)
Bagheripour E, Moghadassi A, Hosseini S, Arabian J. Sci. Eng., 41, 2545 (2016)
Azari A, Rezaei R, Sanaeepur H, Desalination Water Treatment, 124, 308 (2018)
Zhou H, Chua MH, Xu J, Polymer composites with functionalized nanoparticles, Elsevier, 179 (2019).
Kausar A, Polym. Plast. Technol. Eng., 56, 1401 (2017)
Ayandele E, Sarkar B, Alexandridis P, Nanomaterials, 2, 445 (2012)
Hosseini SM, Afshari M, Fazlali AR, Farahani SK, Bandehali S, Van der Bruggen B, Bagheripour E, Chem. Eng. Res. Des., 147, 390 (2019)
Chen X, Dumee LF, Adv. Eng. Mater., 21, 180066 (2019)
Koutahzadeh N, Esfahani MR, Bailey F, Taylor A, Esfahani ARJJOECE
Dalwani M, Zheng J, Hempenius M, Raaijmakers MJ, Doherty CM, Hill AJ, Wessling M, Benes NE, J. Mater. Chem. A, 22, 14835 (2012)
Duan JT, Litwiller E, Pinnau I, J. Membr. Sci., 473, 157 (2015)
Chen SC, Fu XZ, Chung TS, Desalination, 335(1), 17 (2014)
Sun J, Wu L, Hu F, RSC Adv., 5, 40753 (2015)
You XD, Ma TY, Su YL, Wu H, Wu MY, Cai HW, Sun GM, Jiang ZY, J. Membr. Sci., 540, 454 (2017)
Liu YW, Liu C, Fu X, Lin OK, Wang ZQ, Wang C, Zhang CH, J. Membr. Sci., 586, 211 (2019)
Bahrami Z, Akbari A, Eftekhari-Sis B, Int. J. Biol. Macromol., 129, 187 (2019)
Lu C, Su C, Cao H, Ma X, Duan F, Chang J, Li Y, Mater. Lett., 228, 85 (2018)
Yamamoto K, Koge S, Gunji T, Kanezashi M, Tsuru T, Ohshita J, Desalination, 404, 322 (2017)
Zareei F, Hosseini SM, Sep. Purif. Technol., 226, 48 (2019)
He YR, Tang YP, Chung TS, Ind. Eng. Chem. Res., 55(50), 12929 (2016)
Kucuk AC, Urucu OA, React. Funct. Polym., 140, 22 (2019)
Hebbar RS, Isloor AM, Ismail A, Shilton SJ, Obaid A, Fun HK, New J. Chem., 39, 6141 (2015)
Hebbar RS, Isloor AM, Ismail A, RSC Adv., 4, 55773 (2014)
Hebbar RS, Isloor AM, Ananda K, Ismail A, J. Mater. Chem. A, 4, 764 (2016)
Rahimpour A, Desalination, 265(1-3), 93 (2011)
Mansourpanah Y, Madaeni SS, Rahimpour A, Farhadian A, Taheri AH, J. Membr. Sci., 330(1-2), 297 (2009)
Bagheripour E, Moghadassi AR, Hosseini SM, Van der Bruggen B, Parvizian F, J. Ind. Eng. Chem., 62, 311 (2018)
Chang YW, Wang E, Shin G, Han JE, Mather PT, Polym. Adv. Technol., 18, 535 (2007)
Xia JZ, Liu SL, Pallathadka PK, Chng ML, Chung TS, Ind. Eng. Chem. Res., 49(23), 12014 (2010)
Moochani M, Moghadassi A, Hosseini SM, Bagheripour E, Parvizian F, J. Chem. Eng., 33, 2674 (2016)
Bagheripour E, Moghadassi A, Hosseini SM, Int. J. Eng., 30, 821 (2017)
Rakhshan N, Pakizeh M, J. Ind. Eng. Chem., 34, 51 (2016)
Safarpour M, Vatanpour V, Khataee A, Desalination, 393, 65 (2016)
Zhang HZ, Xu ZL, Ding H, Tang YJ, Desalination, 420, 158 (2017)
Ansari S, Moghadassi AR, Hosseini SM, Desalination, 357, 189 (2015)
Sivakumar M, Mohan DR, Rangarajan R, J. Membr. Sci., 268(2), 208 (2006)
Mobarakabad P, Moghadassi AR, Hosseini SM, Desalination, 365, 227 (2015)
Gursel IV, Noel T, Wang Q, Hessel V, Green Chem., 17, 2012 (2015)
Semiao AJC, Schafer AI, J. Membr. Sci., 381(1-2), 132 (2011)
Zhu WP, Sun SP, Gao J, Fu FJ, Chung TS, J. Membr. Sci., 456, 117 (2014)
Chitpong N, Husson SM, J. Membr. Sci., 523, 418 (2017)
Maurer M, Pronk W, Larsen T, Water Res., 40, 3151 (2006)
Yaser AZ, Development of integrated nanofiltration system for highly concentrated dye removal, in, Swansea University (2011).
Al-Rashdi BAM, Johnson DJ, Hilal N, Desalination, 315, 2 (2013)
Tanninen J, Manttari M, Nystrom M, Desalination, 189(1-3), 92 (2006)
Ortega LM, Lebrun R, Blais JF, Hausler R, Desalination, 227(1-3), 204 (2008)
Nghiem L, Schafer A, Environ. Eng. Sci., 19, 441 (2002)
Hua M, Zhang SJ, Pan BC, Zhang WM, Lv L, Zhang QX, J. Hazard. Mater., 211, 317 (2012)
Ganesh BM, Isloor AM, Ismail AF, Desalination, 313, 199 (2013)
Bellona C, Drewes JE, J. Membr. Sci., 249(1-2), 227 (2005)
Kochkodan V, Hilal N, Desalination, 356, 187 (2015)
Zhang Y, Zhang S, Gao J, Chung TS, J. Membr. Sci., 515, 230 (2016)
Gholami N, Mahdavi H, Adv. Polym. Tech., 37, 3529 (2018)
Zhang Y, Zhang S, Chung TS, Environ. Sci. Technol., 49, 10235 (2015)
Daraei P, Madaeni SS, Ghaemi N, Salehi E, Khadivi MA, Moradian R, Astinchap B, J. Membr. Sci., 415, 250 (2012)
Zhang HZ, Xu ZL, Sun JY, RSC Adv., 8, 29455 (2018)
Zaman NK, Rohani R, Mohammad AW, Isloor AM, Chem. Eng. Sci., 177, 218 (2018)
Ma XH, Yang Z, Yao ZK, Xu ZL, Tang CYY, J. Membr. Sci., 525, 269 (2017)
Abdi G, Alizadeh A, Zinadini S, Moradi G, J. Membr. Sci., 552, 326 (2018)
Gherasim CV, Mikulasek P, Desalination, 343, 67 (2014)
Nayak V, Jyothi MS, Balakrishna RG, Padaki M, Deon S, J. Hazard. Mater., 331, 289 (2017)
Zeng GY, He Y, Zhan YQ, Zhang L, Pan Y, Zhang CL, Yu ZX, J. Hazard. Mater., 317, 60 (2016)
