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Received April 28, 2019
Accepted August 5, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Bagasse as functional fillers to improve and control biodegradability of soy oil-based rigid polyurethane foams
School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430073, Hubei, China 1Key laboratory of Processing and Quality Evaluation Technology of Green Plastics of China National Light Industry Council, Beijing Technology and Business University, Beijing 100048, China 2Key Laboratory of Environment Correlative Dietology of Ministry of Education, College of Food Science & Technology, Huazhong Agricultural University, Wuhan, Hubei, 430070, China 3Guangdong Provincial Bioengineering Institute (Guangzhou Sugarcane Industry Research Institute), Guangdong Provincial Key Laboratory of Sugarcane Improvement and Biorefinery, Guangzhou, 510316, Guangdong, China
tianhuafeng@th.btbu.edu.cn
Korean Journal of Chemical Engineering, October 2019, 36(10), 1740-1745(6), 10.1007/s11814-019-0349-0
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Abstract
Using agricultural wastes (bagasse) and polyol derived from soy oil as raw materials to develop biodegradable rigid polyurethane foams (RPUFs) is beneficial to reduce the dependence on petroleum resources and promote the sustainable socioeconomic and environmental development. This study focuses on bagasse as a functional filler to improve and control the mechanical properties and biodegradability of the RPUFs. With the increasing levels of bagasse content, the density and mechanical properties of RPUFs increase. The biodegradation of RPUFs has a greater enhancement compared to the foam without bagasse, and all bio-foams have excellent thermal insulation properties. All changes in foam performance are due to the fact that the active hydroxyl groups on bagasse react with excess isocyanate to form urethane, which affects the structure of RPUFs. In this study, scientific design and molecular regulation theory were applied to improve the utilization value of bagasse and develop high-performance biodegradable RPUFs for thermal insulation materials.
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Xue BL, Wen JL, Sun RC, ACS Sustain. Chem. Eng., 2, 1474 (2014)
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Fan HY, Tekeei A, Suppes GJ, Hsieh FH, J. Appl. Polym. Sci., 127(3), 1623 (2013)
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Hakim AAA, Nassar M, Emam A, Sultan M, Mater. Chem. Phys., 129(1-2), 301 (2011)
Kurimoto Y, Takeda M, Koizumi A, Yamauchi S, Doi S, Tamura Y, Bioresour. Technol., 74(2), 151 (2000)
Wang HJ, Rong MZ, Zhang MQ, Hu J, Chen HW, Czigany T, Biomacromolecules, 9(2), 615 (2008)
Garrison T, Murawski A, Quirino R, Polymers, 8, 262 (2016)
Savelyev Y, Markovskaya L, Savelyeva O, Akhranovich E, Parkhomenko N, Travinskaya T, J. Appl. Polym. Sci., 132 (2015)
Oprea S, Polym.-Plast. Technol. Eng., 54, 342 (2015)
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da Silva VR, Mosiewicki MA, Yoshida MI, da Silva MC, Stefani PM, Marcovich NE, Polym. Test, 32, 665 (2013)
