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Received March 7, 2019
Accepted September 2, 2019
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Enhanced oxygen evolution reaction over glassy carbon electrode modified with NiOx and Fe3O4
Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt
reham_tammam@cu.edu.eg
Korean Journal of Chemical Engineering, November 2019, 36(11), 1932-1939(8), 10.1007/s11814-019-0381-0
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Abstract
Magnetite iron oxide (Fe3O4)/nickel oxide (NiOx) modified glassy carbon (GC) electrode shows enhancement of oxygen evolution reaction (OER) compared to GC electrode modified with single NiOx or Fe3O4 nanoparticles. Many techniques such as linear and cyclic sweep voltammetry, electrochemical impedance spectroscopy (EIS) have been employed. Field-emission scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) are both used for characterization of the electrocatalysts. Effect of loading amount of both NiOx and Fe3O4 and the order of deposition on the OER was studied. A significant improvement of the electrocatalytic properties of the Fe3O4/NiOx binary catalyst modified GC is obtained when NiOx is electrodeposited on GC/Fe3O4 (i.e. GC/Fe3O4/NiOx) compared to GC/NiOx/Fe3O4 (where NiOx is deposited first on the GC then Fe3O4). The use of GC/Fe3O4/NiOx (where Fe3O4 is deposited first on the GC then NiOx) for OER in alkaline solution support higher currents and consequently negative shifts of the onset potential of OER compared to that of GC/NiOx or GC/Fe3O4. The obtained electrochemical impedance parameters confirmed the above conclusions. Tafel parameters confirm the superior activity of GC/Fe3O4/ NiOx and give insight into the mechanism of the OER on the above electrodes.
Keywords
References
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Cibrev D, Jankulovska M, Lana-Villarreal T, Gomez R, Int. J. Hydrog. Energy, 38(6), 2746 (2013)
Kibria MF, Mridha MS, Int. J. Hydrog. Energy, 21, 179 (1996)
Tammam RH, Saleh MM, J. Electroanal. Chem., 794, 189 (2017)
Roca-Ayats M, Herreros E, Garcia G, Pena MA, Martinez-Huerta MV, Appl. Catal. B: Environ., 183, 53 (2016)
Chen DY, Minteer SD, J. Power Sources, 284, 27 (2015)
Liang YH, Liu Q, Asiri AM, Sun XP, He YQ, Int. J. Hydrog. Energy, 40(39), 13258 (2015)
Zhang BB, Xu JC, Wang PF, Han YB, Hong B, Jin HX, Jin DF, Peng XL, Li J, Gong J, Ge HL, Zhu ZW, Wang XQ, J. Alloy. Compd., 662, 348 (2016)
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Akihiko K, Yugo M, Chem. Soc. Rev., 38, 253 (2009)
Cheng FY, Chen J, Chem. Soc. Rev., 41, 2172 (2012)
Lu YC, Xu ZC, Gasteiger HA, Chen S, Hamad-Schifferli K, Shao-Horn Y, J. Am. Chem. Soc., 132(35), 12170 (2010)
Lyons MEG, Brandon MP, J. Electroanal. Chem., 641(1-2), 119 (2010)
Zhang Y, Cao X, Yuan H, Zhang W, Zhou Z, Int. J. Hydrog. Energy, 24, 529 (1999)
King WJ, Tseung AC, Electrochim. Acta, 19, 493 (1974)
Haenen J, Visscher W, Barendrecht E, J. Electroanal. Chem., 208, 297 (1986)
Lee YM, Suntivich J, May KJ, Perry EE, Shao-Horn Y, J. Phys. Chem. Lett, 3, 399 (2012)
Lee WH, Kim H, Catal. Commun., 12, 408 (2011)
Hu W, Wang YQ, Hu XH, Zhou YQ, Chen SL, J. Mater. Chem., 22, 6010 (2012)
Suntivich J, May KJ, Gasteiger HA, Goodenough JB, Shao-Horn Y, Science, 334(6061), 1383 (2011)
Jin C, Cao XC, Zhang LY, Zhang C, Yang RZ, J. Power Sources, 241, 225 (2013)
Gao MR, Xu YF, Jiang J, Zheng YR, Yu SH, J. Am. Chem. Soc., 134(6), 2930 (2012)
Bediako DK, Lassalle-Kaiser B, Surendranath Y, Yano J, Yachandra VK, Nocera DG, J. Am. Chem. Soc., 134(15), 6801 (2012)
Kadakia K, Datta MK, Jampani PH, Park SK, Kumta PN, J. Power Sources, 222, 313 (2013)
Lu BA, Cao DX, Wang P, Wang GL, Gao YY, Int. J. Hydrog. Energy, 36(1), 72 (2011)
Bian WY, Yang ZR, Strasser P, Yang RZ, J. Power Sources, 250, 196 (2014)
Kumar B, Saha S, Ojha K, Ganguli AK, Mater. Res. Bull., 64, 283 (2015)
Danial AS, Saleh MM, Salih SA, Awad MI, J. Power Sources, 293, 101 (2015)
Ghonim AM, El-Anadouli BE, Saleh MM, Electrochim. Acta, 114, 713 (2013)
Tammam RH, Fekry AM, Saleh MM, Int. J. Hydrog. Energy, 40(1), 275 (2015)
Hameed RMA, El-Sherif RM, Appl. Catal. B: Environ., 162, 217 (2015)
Gorlin M, Gliech M, de Araujo JF, Dresp S, Bergmann A, Strasser P, Catal. Today, 262, 65 (2016)
Yoon S, Yun JY, Lim JH, Yoo B, J. Alloy. Compd., 693, 964 (2017)
Lu BP, Bai J, Bo XJ, Zhu LD, Guo LP, Electrochim. Acta, 55(28), 8724 (2010)
Corrigan DA, J. Electrochem. Soc., 134, 377 (1987)
Dionigi F, Strasser P, Adv. Eng. Mater., 6, 160062 (2016)
Galan.Mascaros JR, Chem. Electrochem., 2, 37 (2015)
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Klaus S, Cai Y, Louie MW, Trotochaud L, Bell AT, J. Phys. Chem. C, 119, 7243 (2015)
Moghaddam AB, Ganjali MR, Dinarvand R, Razavi T, Saboury AA, Moosavi-Movahedi AA, Norouzi P, J. Electroanal. Chem., 614(1-2), 83 (2008)
El-Refaei SM, Saleh MM, Awad MI, J. Power Sources, 223, 125 (2013)
Laouini E, Berghoute Y, Douch J, Mendonca MH, Hamdani M, Pereira MIS, J. Appl. Electrochem., 39(12), 2469 (2009)
Ding Z, Yang CC, Wu Q, Electrochim. Acta, 49(19), 3155 (2004)
Kumar M, Awasthi R, Sinha ASK, Singh RN, Int. J. Hydrog. Energy, 36(15), 8831 (2011)
Godinho MI, Catarino MA, Pereira MID, Mendonca MH, Costa FM, Electrochim. Acta, 47(27), 4307 (2002)
Mendonca MH, Godinho MI, Catarino MA, da Silva Pereira MI, Costa FM, Solid State Sci., 4, 175 (2002)
Jiang N, Meng HM, Surf. Coat. Technol., 206, 4362 (2012)
Rosalbino F, Delsante S, Borzone G, Scavino G, Int. J. Hydrog. Energy, 38(25), 10170 (2013)
El-Refaei SM, Saleh MM, Awad MI, J. Solid-State Electrochem., 18, 5 (2014)
El-Refaei SM, Awad MI, El-Anadouli BE, Saleh MM, Electrochim. Acta, 92, 460 (2013)
Goncalves JM, Matias TA, Saravia LPH, Nakamura M, Bernardes JS, Bertotti M, Araki K, Electrochim. Acta, 267, 161 (2018)
Trotochaud L, Young SL, Ranney JK, Boettcher SW, J. Am. Chem. Soc., 136(18), 6744 (2014)
Liu QY, Wang H, Wang XN, Tong R, Zhou XL, Peng XN, Wang HB, Tao HL, Zhang ZH, Int. J. Hydrog. Energy, 42(8), 5560 (2017)
Luo Q, Peng MY, Sun XP, Luo YL, Asiri AM, Int. J. Hydrog. Energy, 41(21), 8785 (2016)
Yang XJ, Pan JQ, Nie YJ, Sun YZ, Wan PY, Int. J. Hydrog. Energy, 42(43), 26575 (2017)
Zhang C, Xie YC, Deng H, Zhang C, Su JW, Dong Y, Lin J, Int. J. Hydrog. Energy, 43(15), 7299 (2018)
Hassan HB, Tammam RH, Solid State Ion., 320, 325 (2018)
Tammam RH, Hassan HB, J. Electrochem. Soc., 166(12), F729 (2019)
Macdonald DD, Electrochim. Acta, 51(8-9), 1376 (2006)
Fekry AM, Tammam RH, Ind. Eng. Chem. Res. J., 53, 2911 (2014)
Tammam RH, Fekry AM, J. Mater. Eng. Perform., 23, 715 (2014)
Gombos E, Barkacs K, Felfoldi T, Vertes C, Mako M, Palko G, Zaray G, Microchem. J., 107, 115 (2013)
Sharma VK, Coord. Chem. Rev., 257, 495 (2013)
Kubisztal J, Budniok A, Int. J. Hydrog. Energy, 33(17), 4488 (2008)
Cibrev D, Jankulovska M, Lana-Villarreal T, Gomez R, Int. J. Hydrog. Energy, 38(6), 2746 (2013)
Kibria MF, Mridha MS, Int. J. Hydrog. Energy, 21, 179 (1996)
Tammam RH, Saleh MM, J. Electroanal. Chem., 794, 189 (2017)
