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Received June 3, 2019
Accepted September 4, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Green and low-cost preparation of CIGSe thin film by a nanocrystals ink based spin-coating method
Trang Thi Thuy Le
Nam Le
Mohan Reddy Pallavolu
Yoonchang Jeon
Dong-seob Jeong
Babu Pejjai
Vasudeva Reddy Minnam Reddy
Nguyen Tam Nguyen Truong
Chinho Park†
School of Chemical Engineering, Yeungnam University, 280 Dae-dong, Gyeongsan 38541, Korea
Korean Journal of Chemical Engineering, December 2019, 36(12), 2110-2117(8), 10.1007/s11814-019-0386-8
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Abstract
An “ink” solution based process, using spin-coating technique, followed by annealing in selenium environment with different temperature programs was utilized to prepare CIGSe thin films. Herein, the CuIn0.7Ga0.3Se2 nanocrystals were synthesized using ethanol - a “green” solvent. Three different solvents: 2-propanol, 2-methoxyethanol, and their 2 : 1 mixture (v/v ratio), were investigated as a dispersion medium for the as-synthesized CIGSe nanocrystals to form a stable ink solution. The last one- a mixture of 2-propanol : 2-methoxyethanol=2 : 1 (v/v), was found to be the most suitable. Furthermore, the influences of various annealing modes on the CIGSe grain size and density in the resulting film were also studied. The as-prepared CIGSe thin film was around 1μm thick and possessed a tetragonal structure. A newly developed cheaper and “greener” non-vacuum process was applied successfully from the synthesis of nanocrystals to the formation of ink solution, and produced high quality thin films; this opens a new route to the cost-competitive commercialization of CIGSe thin film solar cells.
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Cahen D, Ireland PJ, Kazmerski LL, Thiel FA, J. Appl. Phys., 57, 4761 (1985)
Vegard L, Zeitschrift fur Physik, 5, 17 (1921)
Denton AR, Ashcroft NW, Phys. Rev. A., 43, 3161 (1991)
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Krishnan R, Payzant EA, Acnyzki RK, Schoop U, Britt J, Noufi R, Anderson TJ, Proceedings of the 35th IEEE PVSC Honolulu, 1006 (2010).
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Caballero R, Kaufmann CA, Eisenbarth T, Grimm A, Lauermann I, Unold T, Klenk R, Schock HW, Appl. Phys. Lett., 96, 092104 (2010)
Caballero R, Nichterwitz M, Steigert A, Eicke A, Lauermann I, Schock HW, Kaufmann CA, Acta Mater., 63, 54 (2014)
