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In relation to this article, we declare that there is no conflict of interest.
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Received July 10, 2018
Accepted October 8, 2018
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Ultrasound-assisted green synthesis and application of recyclable nanoporous chromium-based metal-organic framework

Department of Environmental Research, Institute for Color Science and Technology, Tehran, Iran
Korean Journal of Chemical Engineering, February 2019, 36(2), 287-298(12), 10.1007/s11814-018-0162-1
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Abstract

We studied the synthesis, characterization clarification, and dye adsorption ability of chromium-based metalorganic framework (Materials Institute Lavoisier: MIL-101(Cr)). MIL-101(Cr) with 1 : 1 molar ratio of metal to ligand was ultrasound-assisted green synthesized in a DMF-free way and its adsorption capacity for pollutant remediation was studied. Several analyses were applied to clarify the characterization of materials, including TGA, SEM, XRD, FTIR, BET, and Zeta potential. Direct Red 80 (DR80) and Acid Blue 92 (AB92) were used to make model dye bearing wastewater. Response surface methodology (RSM) historical modeling was applied to the data to achieve an accurate model of the experiment. Adsorption kinetics and isotherms models were fully studied. The powerful adsorbent was the MIL- 101(Cr) with the M/L=1 : 1, which represented the high specific surface area (SSA) of 2,420m2/g and surface charge of +27.2mV. The maximum adsorption capacity was obtained 227mg/g for DR80 and 185mg/g for AB92. With an eye to the real-world application, the synthesized adsorbent well operated by removing dyes from the wastewater and high reusability after four cycles.

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