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Received November 1, 2018
Accepted December 20, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Pd nanoparticles immobilized on TiO2 nanotubes-functionalized ceramic membranes for flow-through catalysis
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China
rizhichen@njtech.edu.cn
Korean Journal of Chemical Engineering, March 2019, 36(3), 385-392(8), 10.1007/s11814-018-0219-1
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Abstract
A high performance catalytic membrane was fabricated with Pd nanoparticles supported by TiO2 nanotubes, where the TiO2 nanotubes were synthesized on the ceramic membrane via a simple hydrothermal etching. A flow-through catalytic membrane reactor was developed for testing the catalytic properties in the p-nitrophenol reduction. The effect of etching time was investigated in detail and an optimal etching time was determined to be 16 h. The characterization results highlighted that the as-prepared bouquet-like TiO2 nanotubes could significantly improve the loading amount and dispersity of Pd nanoparticles. The fabricated catalytic membrane exhibited considerably improved catalytic activity and stability, with a 100% conversion of p-nitrophenol and no loss in catalytic activity during five reaction cycles. The obtained activation energy was much lower than the values in literatures, implying that the p-nitrophenol reduction could take place more easily on our catalytic membranes compared to other catalysts.
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References
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Li D, Cheng XW, Yu XJ, Xing ZP, Chem. Eng. J., 279, 994 (2015)
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Lv MQ, Zheng DJ, Ye MD, Sun L, Xiao J, Guo WX, Lin CJ, Nanoscale, 4, 5872 (2012)
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Ao C, Tian PF, Ouyang L, Da GJ, Xu XY, Xu J, Han YF, Catal. Sci. Technol., 6, 5060 (2016)
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Bi SY, Li K, Chen X, Fu WG, Chen L, Sheng HY, Yang Q, Polym. Compos., 35, 2251 (2015)
