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Received October 14, 2018
Accepted December 13, 2018
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Cell structure destruction and its kinetics during hydrothermal treatment of sewage sludge
1Department of Mechanical Sciences and Engineering, Hiroshima University, Higashi-Hiroshima, Japan 2Original Affiliation: Department of Mechanical Engineering, Lambung Mangkurat University, Banjarmasin, South Kalimantan, Indonesia
mat@hiroshima-u.ac.jp
Korean Journal of Chemical Engineering, March 2019, 36(3), 433-438(6), 10.1007/s11814-018-0212-8
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Abstract
During hydrothermal treatment (HT) of sewage sludge (SS), its cell structure is decomposed and its organic content is released. An increase in the total organic carbon content in the liquid phase was experimentally determined in the temperature range of 130-250 °C with a fixed pressure of 5MPa and residence time of 10min. By using the Arrhenius equation, the pre-exponential factor and activation energy were successfully determined for the first time for the degradation of SS cells as 3.96 X 1010 s-1 and 115 kJ mol-1, respectively, for the temperature range of 130-250 °C. Increasing the HT temperature increasingly destroyed the cell structure of SS.
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Li H, Jin YY, Mahar RB, Wang ZY, Nie YF, J. Hazard. Mater., 161(2-3), 1421 (2009)
Diak J, Ormeci B, Proux C, Water Sci. Technol., 63, 1309 (2011)
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Wu Y, Song K, Jiang Y, Sun X, Li L, Biochem. Eng. J., 139, 132 (2018)
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Titirici MM, Thomas A, Antonietti M, New J. Chem., 31, 787 (2007)
Libra JA, Ro KS, Kammann C, Funke A, Berge ND, Neubauer Y, Titirici MM, Fuhner C, Bens O, Kern J, Emmerich KH, Biofuels, 2, 89 (2011)
Kato A, Matsumura Y, J. Jpn. Inst. Energy, 82, 97 (2003)
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Everett JG, J. Water Pollut. Control. Fed., 44, 92 (1972)
Wang L, Zhang L, Li A, Water Res., 65, 85 (2014)
Imbierowicz M, Chacuk A, Water Res., 46, 5747 (2012)
Mohamad R, Aki T, Nakashimada Y, Okamura Y, Tajima T, Matsumura Y, J. Japan Pet. Inst., 59, 149 (2016)
Goto M, Nada T, Kodama A, Hirose T, Ind. Eng. Chem. Res., 38(5), 1863 (1999)
Bougrier C, Delgenes JP, Carrere H, Chem. Eng. J., 139(2), 236 (2008)
