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Received August 27, 2018
Accepted November 25, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Reactive insights into the hydrogen production from ammonia borane facilitated by phosphonium based ionic liquid
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati -781039, Assam, India 1Department of Chemical Engineering, Indian Institute of Science Education and Research Bhopal, Bhopal - 462 066, Madhya Pradesh, India
tamalb@iitg.ac.in
Korean Journal of Chemical Engineering, March 2019, 36(3), 456-467(12), 10.1007/s11814-018-0196-4
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Abstract
The current work presents a mechanistic insight of hydrogen production from ammonia borane (AB) facilitated by the phosphonium based ionic liquid (IL), trihexyl(tetradecyl)phosphonium bis (2,4,4-trimethylpentyl) phosphinate ([TDTHP][Phosph]). Prior to experiments, the IL was screened from a pool of 11 phosphonium ILs with the infinite dilution activity coefficients (IDAC) values as predicted by conductor like screening model segment activity coefficient (COSMO-SAC) theory. Thereafter, a dehydrogenation experiment of AB/[TDTHP][Phosph] was carried out at 105 °C and 4 x10-2mbar of gauge pressure, which yielded 2.07 equivalent hydrogen production. At higher temperature, the 11B NMR characterization shows the suppression of induction period at 105 °C and appearance of borohydride anion after 1 min of dehydrogenation. Further, time-resolved characterization of AB/[TDTHP][Phosph] at 105 °C confirmed the appearance of polymeric aminoborane after 10min with a subsequent formation of polyborazylene. HR-MS characterization coupled with 1H resonance spectrum confirmed structural integrity of IL. The dual characterization of NMR and HR-MS led us to propose a dehydrogenation mechanism of AB/[TDTHP][Phosph] system.
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Rekken BD, Carre-Burritt AE, Scott BL, Davis BL, J. Mater. Chem. A, 2, 16507 (2014)
Blundell RK, Licence P, Phys. Chem. Chem. Phys., 16, 15278 (2014)
Atefi F, Garcia MT, Singer RD, Scammells PJ, Green Chem., 11, 1595 (2009)
Del Sesto RE, Corley C, Robertson A, Wilkes JS, J. Organomet. Chem., 690, 2536 (2005)
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Kundu D, Chakma S, Pugazhenthi G, Banerjee T, ACS Omega, 3, 2273 (2018)
Stowe AC, Shaw WJ, Linehan JC, Schmid B, Autrey T, Phys. Chem. Chem. Phys., 9, 1831 (2007)
Smythe NC, Gordon JC, Eur. J. Inorg. Chem., 210, 509 (2010)
Sahler S, Sturm S, Kessler MT, Prechtl MHG, Chem. Eur. J., 20, 8934 (2014)
