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Received August 30, 2018
Accepted December 27, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Effects of montmorillonite on the enhancement of physicochemical, optical and photocatalytic properties of TiO2/chitosan bilayer photocatalyst
School of Chemical Sciences, Universiti Sains Malaysia, 11800 Minden, Penang, Malaysia
Korean Journal of Chemical Engineering, March 2019, 36(3), 478-488(11), 10.1007/s11814-018-0221-7
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Abstract
Chitosan-montmorillonite (CS-MT) composites of different MT composition were prepared in 5% of acetic acid solution and fabricated on glass plates. The composite film was then combined with TiO2 in an immobilized layer-layer manner for removing methyl orange dye via synergistic photocatalytic-adsorption processes. The effects of MT addition to the CS matrix were investigated with respect to the physicochemical and optical properties. The presence of MT within the composite reduced the swelling and improved the adhesiveness as well as the thermal stability of CS. The MT clay assisted in producing higher hydroxyl radicals and improving the solid-state oxidation of CS within the adsorbent sub-layer for the photocatalytic enhancement of TiO2/CS-MT than its counterpart TiO2/CS. Subsequently, the photocatalytic activity of the TiO2/CS-MT was 1.3 and 4.2-times better than the TiO2/CS and TiO2 photocatalysts, respectively. This TiO2/CS-MT photocatalyst was also reusable for at least ten cycles of application.
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References
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Celis R, Adelino MA, Hermosin MC, Cornejo J, J. Hazard. Mater., 209, 67 (2012)
Kamal T, Anwar Y, Khan SB, Chani MTS, Asiri AM, Carbohydr. Polym., 148, 153 (2016)
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Yan H, Yang H, Li AM, Cheng RS, Chem. Eng. J., 284, 1397 (2016)
Zhang T, Luo Y, Jia B, Li Y, Yuan L, Yu J, J. Environ. Sci., 32, 108 (2015)
Dou BL, Dupont V, Pan WG, Chen BB, Chem. Eng. J., 166(2), 631 (2011)
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Bahrudin NN, Nawi MA, React. Kinet. Mech. Cat., 124, 153 (2018)
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Nawi MA, Zain SM, Appl. Surf. Sci., 258(16), 6148 (2012)
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Katti KS, Katti DR, Dash R, Biomed. Mater., 3, 034122 (2008)
Sun Q, Zhang W, Qian H, Environ. Earth Sci., 75, 610 (2016)
Nawi MA, Jawad AH, Sabar S, Ngah WSW, Carbohydr. Polym., 83, 1146 (2011)
Pereira FAR, Sousa KS, Cavalcanti GRS, Fonseca MG, de Souza AG, Alves APM, Int. J. Biol. Macromol., 61, 471 (2013)
Nakabayashi Y, Nosaka Y, Phys. Chem. Chem. Phys., 17, 30570 (2015)
Nawi MA, Ngoh YS, Zain SM, Int. J. Photoenergy, 2012, 12 (2012)
Mucha M, Pawlak A, Polimery, 47, 509 (2002)
Bahrudin NN, Nawi MA, Ismail WINW, Korean J. Chem. Eng., 35(7), 1450 (2018)
Zhang X, Xiao G, Wang Y, Zhao Y, Su H, Tan T, Carbohydr. Polym., 169, 101 (2017)
Balaji J, Sethuraman M, Int. J. Biol. Macromol., 104, 1730 (2017)
Sun H, Peng T, Liu B, Xian H, Appl. Clay Sci., 114, 440 (2015)
Bahranowski K, Gaweł A, Klimek A, Michalik-Zym A, Napruszewska B, Nattich-Rak M, Rogowska M, Serwicka E, Appl. Clay Sci., 140, 75 (2017)
