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Received October 18, 2018
Accepted December 18, 2018
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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New insights into mechanistic aspects and structure of polycrystalline Cu/Cr/Ni metal oxide nanoclusters synthesized using Eryngium campestre and Froriepia subpinnata
School of Chemical Engineering, College of Engineering, University of Tehran, Tehran 14176, Iran 1Chemical Engineering Department, University of Mohaghegh Ardabili, P. O. Box 179, Ardabil, Iran
otavakoli@ut.ac.ir
Korean Journal of Chemical Engineering, March 2019, 36(3), 489-499(11), 10.1007/s11814-018-0216-4
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Abstract
Novel nanoclusters (NCs) of Cu/Cr/Ni/O were produced by a green synthesis approach using leaf extracts of E. campestre and F. subpinnata at room temperature and pH 7. Characterization of the produced NCs using EDS, XRD, and FESEM revealed that E. campestre results in CuO-Cr2O3-NiO nanocomposites with average crystallite size of 29.2 nm, while binary and ternary Cu-Cr-Ni-O nanoalloys of averaged 9.8 nm crystallite size are produced using F. subpinnata leaf extract. In addition, bioreduction mechanism of the metal ions was investigated for both plant extracts by evaluating total phenolics/total flavonoids, HPLC chromatograms of the leaf extracts, and FTIR spectra of the extracts before and after the bioreduction reaction. It was found that phenolic acids are the main responsibility for the bioreduction of the metal ions. In particular, chlorogenic acid, rosmarinic acid, and syringic acids for the nanoalloys produced by reducing potential of F. subpinnata, and rosmarinic acid for the nanocomposites synthesized using E. campestre were identified as the main reducing agents. FTIR studies revealed that in CuO-Cr2O3-NiO nanocomposites, aliphatic and aldehyde amine groups and in Cu-Cr-Ni-O nanoalloys, aliphatic and aldehyde amine, and nitrile groups act as both capping and stabilizing ligands.
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Patra N, Taviti AC, Sahoo A, Pal A, Beuria TK, Behera A, Patra S, RSC Adv., 7, 35111 (2017)
Lankiang SD, Baranton S, Coutanceau C, Electrochim. Acta, 242, 287 (2017)
Gu Z, Xu H, Bin D, Yan B, Li S, Xiong Z, Zhang K, Du Y, Colloids Surf. A: Physicochem. Eng. Asp., 529, 651 (2017)
Cao Y, Denny MS, Caspar JV, Farneth WE, Guo Q, Ionkin AS, Johnson LK, Lu M, Malajovich I, Radu D, J. Am. Ceram. Soc., 134, 15644 (2012)
Moran M, Rosell N, Ruano G, Busquets M, Vinardell M, Colloids Surf. B: Biointerfaces, 134, 156 (2015)
Gu J, Chen X, Xin H, Fang X, Sha X, Int. J Pharm., 461, 559 (2014)
He SN, Li YL, Yan JJ, Zhang W, Du YZ, Yu HY, Hu FQ, Yuan H, Int. J. Nanomed, 8, 2859 (2013)
Shaikh FI, Chikhale LP, Mulla IS, Suryavanshi SS, Powder Technol., 326, 479 (2018)
Elavarthi P, Kumar AA, Murali G, Reddy DA, Gunasekhar K, J. Alloy. Compd., 656, 510 (2016)
Weihua W, Xuelin T, Kai C, Gengyu C, Colloids Surf. A: Physicochem. Eng. Asp., 273, 35 (2006)
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Xia Y, Sun B, Wei Y, Tao B, Zhao Y, J. Alloy. Compd., 705, 58 (2017)
Gashti MP, Burgener M, Stir M, Hulliger J, J. Colloid Interface Sci., 431, 149 (2014)
Gashti MP, Helali M, Karimi S, Int. J. Appl. Ceram. Technol., 13, 1069 (2016)
Gashti MP, Stir M, Hulliger J, New J. Chem., 40, 5495 (2016)
Gashti MP, Shokri A, J. Aust. Ceram. Soc., 54, 601 (2018)
Dong Y, Yang Z, Sheng Q, Zheng J, Colloids Surf. A: Physicochem. Eng. Asp., 538, 371 (2018)
Wang G, Wen Z, Du L, Li S, Ji S, Sun J, RSC Adv., 6, 39728 (2016)
Liu JC, He F, Gunn TM, Zhao DY, Roberts CB, Langmuir, 25(12), 7116 (2009)
Duan H, Wang D, Li Y, Chem. Soc. Rev, 44, 5778 (2015)
Osonga FJ, Yazgan I, Kariuki V, Luther D, Jimenez A, Le P, Sadik OA, RSC Adv, 6, 2302 (2016)
Rao KJ, Paria S, ACS Appl. Mater. Interfaces, 7, 14018 (2015)
Zhan G, Huang J, Du M, Abdul-Rauf I, Ma Y, Li Q, Mater. Lett., 65, 2989 (2011)
Xia BH, He F, Li LD, Langmuir, 29(15), 4901 (2013)
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Kesharwani J, Yoon KY, Hwang J, Rai M, J. Bionanosci., 3, 39 (2009)
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Vaseghi Z, Tavakoli O, Nematollahzadeh A, J. Environ. Chem. Eng., 6, 1898 (2018)
Vaseghi Z, Tavakoli O, Nematollahzadeh A, Int. Proc Chem. Biol. Environ. Eng., 101, 62 (2017)
Singleton VL, Rossi JA, Am. J. Enol. Vitic., 16, 144 (1965)
Zhishen J, Mengcheng T, Jianming W, Food Chem., 64, 555 (1999)
Fuku X, Matinise N, Masikini M, Kasinathan K, Maaza M, Mater. Res. Bull., 97, 457 (2018)
Khan SA, Noreen F, Kanwal S, Iqbal A, Hussain G, Mater. Sci. Eng., 82, 46 (2018)
Sone B, Manikandan E, Gurib-Fakim A, Maaza M, Green Chem. Lett. Rev., 9, 85 (2016)
Pandian CJ, Palanivel R, Dhananasekaran S, Chinese J. Chem. Eng., 23, 1307 (2015)
Chen H, Wang J, Huang D, Chen X, Zhu J, Sun D, Huang J, Li Q, Mater. Lett., 122, 166 (2014)
Ajitha B, Reddy YAK, Jeon HJ, Ahn CW, Adv. Powder Technol., 29(1), 86 (2018)
Ataei-Germi T, Nematollahzadeh A, J. Colloid Interface Sci., 470, 172 (2016)
Singh PK, Bhardwaj K, Dubey P, Prabhune A, RSC Adv., 5, 24513 (2015)
Dhamecha D, Jalalpure S, Jadhav K, J. Photochem. Photobiol., 154, 108 (2016)
Fazlzadeh M, Rahmani K, Zarei A, Abdoallahzadeh H, Nasiri F, Khosravi R, Adv. Powder Technol., 28(1), 122 (2017)
Balalakshmi C, Gopinath K, Govindarajan M, Lokesh R, Arumugam A, Alharbi NS, Kadaikunnan S, Khaled JM, Benelli G, J. Photochem. Photobiol. B-Biol., 173, 598 (2017)
Kasithevar M, Saravanan M, Prakash P, Kumar H, Ovais M, Barabadi H, Shinwari ZK, J. Interdiscip. Nanomed., 2, 131 (2017)
Shahid M, Farooqi ZH, Begum R, Naseem K, Ajmal M, Irfan A, Korean J. Chem. Eng., 35(5), 1099 (2018)
Deokar GK, Ingale AG, RSC Adv., 6, 74620 (2016)
Nasrollahzadeh M, Sajadi SM, J. Colloid Interface Sci., 462, 243 (2016)
Ravichandran V, Vasanthi S, Shalini S, Shah SAA, Harish R, Mater. Lett., 180, 264 (2016)
Conea S, Vlase L, Chirila I, Cellul. Chem. Technol., 50, 473 (2016)
Hohmann J, Pall Z, Gunther G, Mathe I, Planta Medica, 63, 96 (1997)
Mohsen SM, Ammar AS, Food Chem., 112, 595 (2009)
Edison TJI, Sethuraman MG, Process Biochem., 47(9), 1351 (2012)
