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Received August 28, 2018
Accepted January 19, 2019
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Surface modification of polysulfone ultrafiltration membrane by in-situ ferric chloride based redox polymerization of aniline-surface characteristics and flux analyses
University School of Chemical Technology, Guru Gobind Singh Indraprastha University, Sector 16 C, Dwarka, New Delhi-110078, India
vrindagoel1991@gmail.com
Korean Journal of Chemical Engineering, April 2019, 36(4), 573-583(11), 10.1007/s11814-019-0233-y
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Abstract
On the basis of the water-loving nature of Polyaniline (PANI), super hydrophilic polysulfone (PS) ultrafiltration membranes were prepared via in-situ polymerization of aniline on the surface of the membrane. Growing polyaniline in-situ leads to permeability enhancement of the ultrafiltration membrane. Surface-attenuated total reflection Fourier transform infrared spectroscopy, Atomic force microscopy, Scanning electron microscopy and energy dispersive X-spectroscopy and water contact angle demonstrated the successful attachment of PANI on PS membrane surface. Modified membranes containing increased amount of PANI were compared to the unmodified PS membrane to estimate the change in membrane performance, hydrophilicity and anti-fouling properties. PANI modified membranes showed higher water fluxes in comparison to unmodified membranes, while protein rejection was almost similar in both PANI modified and unmodified PS membranes. Atomic force microscopy and contact angle measurements confirmed increased membrane surface hydrophilicity with increasing PANI content. Fouling study and flux recovery experiments revealed that modified membranes exhibit higher flux recovery ratio (65%) and more stability to strong cleaning agents.
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Zhao S, Wang Z, Wei X, Zhao BR, Wang JX, Yang SB, Wang SC, J. Membr. Sci., 385(1-2), 251 (2011)
Nishigochi S, Ishigami T, Maruyama T, Hao Y, Ohmukai Y, Iwasaki Y, Matsuyama H, Ind. Eng. Chem. Res., 53(6), 2491 (2014)
Wu DH, Liu XS, Yu SC, Liu MH, Gao CJ, J. Membr. Sci., 352(1-2), 76 (2010)
Nazri NAM, Lau WJ, Ismail AF, Korean J. Chem. Eng., 32(9), 1853 (2015)
Ardeshiri F, Akbari A, Peyravi M, Jahanshahi M, Korean J. Chem. Eng., 36(2), 255 (2019)
Bahrami M, Karimi-Sabet J, Hatamnejad A, Dastbaz A, Moosavian MA, Korean J. Chem. Eng., 35(11), 2241 (2018)
Caldera-Villalobos M, Pelaez-Cid AA, Martins-Alho MA, Herrera-Gonzalez AM, Korean J. Chem. Eng., 35(12), 2394 (2018)
Li Z, Shi T, Zhang T, Guo Q, Qiu F, Yue X, Yang D, Korean J. Chem. Eng., 36(1), 92 (2019)
Park JY, Acar MH, Akthakul A, Kuhlman W, Mayes AM, Biomaterials, 27, 856 (2006)
Qiu JH, Zhang YW, Shen YB, Zhang YT, Zhang HQ, Liu JD, Appl. Surf. Sci., 256(10), 3274 (2010)
Akamatsu K, Mitsumori K, Han F, Nakao S, Ind. Eng. Chem. Res., 50(21), 12281 (2011)
Seman MNA, Hilal N, Khayet M, Desalin. Water Treat., 51, 4855 (2013)
Afsarian Z, Mansourpanah Y, Korean J. Chem. Eng., 35(9), 1867 (2018)
Chen GE, Sun L, Xu ZL, Yang H, Hunag HH, Liu YJ, Korean J. Chem. Eng., 32(12), 2492 (2015)
Shi H, He Y, Pan Y, Di HH, Zeng GY, Zhang L, Zhang CL, J. Membr. Sci., 506, 60 (2016)
Mukherjee R, Sharma R, Saini P, Sirshendu, Environ. Sci.: Water Res. Technol., 1, 893 (2015)
Alam J, Dass LA, Alhoshan MS, Ghasemi M, Mohammad AW, Appl. Water Sci., 2, 37 (2012)
Nemati M, Hosseini SM, Bagheripour E, Madaeni SS, Korean J. Chem. Eng., 33(3), 1037 (2016)
Huang X, McVerry BT, Jones CM, Wong MCY, Hoek EMV, Kaner RB, J. Mater. Chem. A, 3, 8725 (2015)
Guillen GR, Farrell TP, Kaner RB, Hoek EMV, J. Mater. Chem., 20, 4621 (2010)
D’Arcya JM, Tranb HD, Tungc VC, Schwartza AKT, Wonga RP, Yangc Y, Kaner RB, PNAS, 107, 19673 (2010)
Zhao S, Wang Z, Wang JX, Wang SC, Ind. Eng. Chem. Res., 53(28), 11468 (2014)
Mansourpanah Y, Kakanejadifard A, Dehrizi FG, Tabatabaei M, Afarani HS, Korean J. Chem. Eng., 32(1), 149 (2015)
Rahimi M, Dadari S, Zeinaddini S, Mohamadian E, Korean J. Chem. Eng., 34(5), 1444 (2017)
Fan ZF, Wang Z, Duan MR, Wang JX, Wang SC, J. Membr. Sci., 310(1-2), 402 (2008)
Fan ZF, Wang Z, Sun N, Wang JX, Wang SC, J. Membr. Sci., 320(1-2), 363 (2008)
Chakrabarty B, Ghoshal AK, Purkait AK, J. Membr. Sci., 315(1-2), 36 (2008)
Nestorovic GD, Jeremic KB, Jovanovic SM, J. Serb. Chem. Soc., 71, 895 (2006)
Huang J, Kaner RB, Angew. Chem., 116, 5941 (2004)
Zhang LJ, Wan MX, Wei Y, Macromol. Rapid Commun., 27(5), 366 (2006)
Gospodinova N, Terlemezyan L, Prog. Polym. Sci, 23, 1443 (1998)
Li J, Yoon SJ, Hsieh BY, Tai W, O’Donnell M, Gao X, Nano Lett., 15, 8217 (2015)
Yin J, Kim ES, Yang J, Deng BL, J. Membr. Sci., 423, 238 (2012)
Liao Y, Li XG, Hoek EMV, Kaner RB, J. Mater. Chem. A, 1, 15390 (2013)
Dallas P, Stamopoulos D, Boukos N, Tzitzios V, Niarchos D, Petridis D, Polymer, 48(11), 3162 (2007)
Kumar S, Singh V, Aggarwal S, Mandal UK, Kotnala RK, Compos. Sci. Technol., 70, 249 (2010)
Xu J, Bhattacharyya D, Ind. Eng. Chem. Res., 46(8), 2348 (2007)
Zhu LP, Yu JZ, Xu YY, Xi ZY, Zhu BK, Colloids Surf. B: Biointerfaces, 69, 152 (2009)
McVerry BT, Temple JAT, Huang X, Marsh KL, Hoek EMV, Kaner RB, Chem. Mater., 25, 3597 (2013)
Teli SB, Molina S, Sotto A, Garcia-Calvo E, de Abajo J, Ind. Eng. Chem. Res., 52(27), 9470 (2013)
Zhao X, He C, Appl. Mater. Interfaces, 7, 17947 (2015)
Saranya R, Kumar M, Tamilarasan R, Ismail AF, Arthanareeswaran G, J. Chem. Technol. Biotechnol., 91(3), 748 (2016)
Li F, Meng JQ, Ye JF, Yang B, Tian Q, Deng CH, Desalination, 344, 422 (2014)
Madaeni SS, Samieirad S, Desalination, 257(1-3), 80 (2010)
Al-Amoudi A, Williams P, Al-Hobaib AS, Lovitt RW, Appl. Surf. Sci., 254(13), 3983 (2008)
Shi X, Tal G, Hankins NP, Gitis V, J. Water Process Eng., 1, 121 (2014)
Xi ZY, Xu YY, Zhu LP, Wang Y, Zhu BK, J. Membr. Sci., 327(1-2), 244 (2009)
