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Received November 26, 2018
Accepted February 11, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Fabrication of magnetically recyclable ZrO2-TiO2/CoFe2O4 hollow core/shell photocatalysts: Improving photocatalytic efficiency under sunlight irradiation
Department of Chemistry, School of Science, North University of China, Taiyuan 030051, China
jhx820215@126.com
Korean Journal of Chemical Engineering, April 2019, 36(4), 605-612(8), 10.1007/s11814-019-0241-y
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Abstract
iO2 is an important material for photocatalytic oxidation to degrade organic pollutants, but its utilization under visible light is low, recovery is difficult, and stability is poor. We prepared ZrO2-TiO2/CoFe2O4 (Zr-Ti/Co) photocatalyst with hollow core-shell structure by sol-gel method and layer-by-layer self-assembly method with tetrabutyl titanate and Zirconium n-butoxide as main raw materials. The samples were characterized and analyzed by X-ray diffraction (XRD), transmission electron microscopy (TEM), solid ultraviolet visible diffuse reflection (UV-Vis DRS), fluorescence (FL), ultraviolet visible absorption (UV), vibrating sample magnetometer (VSM). It is concluded that the TiO2 maintains a good anatase phase structure in the Zr-Ti-Co photocatalyst. Under UV light and sunlight, the degradation rate of the photocatalyst reached 96.1% and 99.7% for 60 min, respectively, for Rhodamine B (10mg/L) reaction system. And after repeated use for five times, it still showed better regeneration and reuse.
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Lucky RA, Sui R, Lo JMH, Charpentier PA, Cryst. Growth Des., 10, 1598 (2010)
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Ayanda OS, Nelana SM, Petrik LF, Naidoo EB, J. Water Health, 15, 1015 (2017)
