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Received January 3, 2019
Accepted April 1, 2019
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Removal of cadmium from aqueous solutions using inorganic porous nanocomposites
Catalin Ianasi1
Mirela Piciorus1
Roxana Nicola1
Mihaela Ciopec2
Adina Negrea2
Daniel Niznansky3
Adel Len4
Laszlo Almasy5 6
Ana-Maria Putz1†
1Coriolan Dragulescu Institute of Chemistry, Bv. Mihai Viteazul, No. 24, RO-300223, Timisoara, Romania 2Faculty of Industrial Chemistry and Environmental Engineering, Politehnica University of Timisoara, Vasile Parvan Bd., No. 6 300223, Timisoara, Romania 3Faculty of Science, Charles University in Prague, Albertov 6 128 43, Prague, Czech Republic 4Centre for Energy Research, Hungarian Academy of Sciences, POB 49 Budapest 1525, Hungary 5Wigner Research Centre for Physics, Institute for Solid State Physics and Optics, Hungarian Academy of Sciences, POB 49 Budapest 1525, Hungary 6State Key Laboratory of Environment-Friendly Energy Materials, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China
Korean Journal of Chemical Engineering, May 2019, 36(5), 688-700(13), 10.1007/s11814-019-0262-6
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Abstract
The present paper reports a one-pot synthesis of magnetic nanocomposites samples through acid catalyzed sol-gel method. Fe(III) acetylacetonate was used as precursor of the iron oxide phase: tetraethylortosilicate for the silica phase and polyvinyl alcohol (PVA, molecular mass 49000) as pore former. Different concentrations of Fe2O3 in composites matrices were prepared and studied ranging from 0% to 20%. All reactions took place in one pot at room temperature; the materials were subsequently heat treated at 300 oC, to ensure the crystallinity for the iron oxide having spinel structure, forming nanoparticles confined in the silica matrix. The materials were characterized using X-ray diffraction, small-angle neutron scattering, FT-IR spectroscopy, nitrogen adsorption, Mossbauer spectroscopy and magnetization measurements. The maximum value of room temperature saturation magnetization of ~54 emu/g and 0.11 kOe coercive field was achieved for the magnetic nanocomposite sample with 20% Fe2O3. The highest surface area of 680m2/g was obtained for the sample with 10% Fe2O3. The potential applicability of the obtained materials was studied for adsorption performance for cadmium in aqueous solutions. The Langmuir isotherm model described well the adsorption data, indicating monolayer adsorption of Cd(II) on the heterogeneous composite surface.
Keywords
References
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Naushad M, AL-Othman ZA, Islam M, Int. J. Environ. Sci. Technol., 10, 567 (2013)
Naushad M, Inamuddin, Rangreez TA, Desalin. Water Treat., 55, 463 (2014)
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Bediako JK, Wei W, Yun YS, J. Ind. Eng. Chem., 43, 61 (2016)
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Naushad M, Ahamad T, Alothman ZA, Shar MA, AlHokbany NS, Alshehri SM, J. Ind. Eng. Chem., 29, 78 (2015)
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Hlihor R, Gavrilescu M, Environ. Eng. Manag. J., 8, 353 (2009)
Sailo L, Pachuau L, Yang JK, Lee SM, Tiwari D, Environ. Eng. Res., 20, 89 (2015)
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Phuengprasop T, Sittiwong J, Unob F, J. Hazard. Mater., 186(1), 502 (2011)
Zhang M, Song W, Chen Q, Miao B, He W, ACS Appl. Mater. Interfaces, 7, 1533 (2015)
Zheng W, Li XM, Wang F, Yang Q, Deng P, Zeng GM, J. Hazard. Mater., 157(2-3), 490 (2008)
Rosta L, Appl. Phys. A-Mater. Sci. Process., 74, S52 (2002)
Mihalca I, Ercuta A, J. Optoelectron. Adv. Mater., 5, 245 (2003)
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Ianasi C, Costisor O, Putz AM, Lazau R, Negrea A, Niznansky D, Sacarescu L, Savii, Process. Appl. Ceram., 10, 265 (2016)
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Sidhu PS, Clay Clay Min., 36, 31 (1988)
Gruskiene R, Krivorotova T, Staneviciene R, Ratautas D, Serviene E, Sereikaite J, Colloids Surf. B: Biointerfaces, 8, 126 (2018)
el Shafei GMS, Adsorption on Silica Surfaces, Marcel Dekker, New York (2000).
Nagorna TV, Kyzyma OA, Chudoba D, Nagornyi AV, J. Mol. Liq., 235, 111 (2017)
Savii C, Almasy L, Ionescu C, Szekely NK, Enache C, Popovici M, Sora I, Nicoara D, Savii GG, Resiga DS, Subrt J, Stengl V, Process. Appl. Ceram., 3, 59 (2009)
Guinier A, Fournet G, Small angle scattering of X.rays, John Wiley and Son, New York (1955).
Almasy L, Putz AM, Len A, Plestil J, Savii C, Process. Appl. Ceram., 11, 229 (2017)
Dudas Z, Fagadar-Cosma E, Len A, Romanszki L, Almasy L. Vlad-Oros B, et al., Materials, 11, 565 (2018)
Fagadar-Cosma E, Dudas Z, Birdeanu M, Almasy L, Mater. Chem. Phys., 148(1-2), 143 (2014)
Gubanova NN, Baranchikov AY, Kopitsa GP, Almasy L, Angelov B, Yapryntsev AD, Rosta L, Ivanov VK, Ultrason. Sonochem., 24, 230 (2014)
Goulart AT, de Jesus Filho MF, Fabris JD, Coey JMD, Hyperfine Interact., 83, 451 (1994)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Mustafa S, Waseem M, Naeem A, Shah KH, Ahmad T, Hussain SY, Chem. Eng. J., 157(1), 18 (2010)
Llorente I, Fajardo S, Bastidas JM, J. Solid State Electrochem., 18, 293 (2014)
Ghasemi M, Naushad M, Ghasemi N, Khosravi-fard Y, J. Ind. Eng. Chem., 20(4), 2193 (2014)
Markin VS, Gugeshashvili MI, Volkov AG, Munger G, Leblanc RM, J. Colloid Interface Sci., 154, 264 (1992)
Al-Othman ZA, Ali R, Naushad M, Chem. Eng. J., 184, 238 (2012)
Chowdhury S, Mishra R, Saha P, Kushwaha P, Desalination, 265(1-3), 159 (2011)
Naushad M, Chem. Eng. J., 235, 100 (2014)
Naushad M, Ahamad T, Sharma G, Al-Muhtaseb AH, Albadarin AB, Alam MM, ALOthman ZA, Alshehri SM, Ghfar AA, Chem. Eng. J., 300, 306 (2016)
Naushad M, Ahamad T, Al-Maswari BM, Alqadami AA, Alshehri SM, Chem. Eng. J., 330, 1351 (2017)
Negrea A, Muntean C, Bodnarescu I, Ciopec M, Motoc M, Rev. Chim., 64, 397 (2013)
Ciopec M, Davidescu CM, Negrea A, Duteanu N, Rusu G, Grad O, Negrea P, Pure Appl. Chem., 91, 375 (2018)
