Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received January 25, 2019
Accepted March 27, 2019
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Synthesis of phosphate functionalized highly porous activated carbon and its utilization as an efficient copper (II) adsorbent
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati 781039, India
somen.mondal@iitg.ac.in
Korean Journal of Chemical Engineering, May 2019, 36(5), 701-712(12), 10.1007/s11814-019-0260-8
Download PDF
Abstract
The effects of activating agents on the characteristics of the activated carbons prepared from the tea waste were investigated. A three-step chemical activation process consisting of impregnation, carbonization and the secondary activation or phosphate functionalization was followed for the synthesis of the activated carbons. The surface area and the total pore volume of the best-activated carbon prepared in the present investigation at optimized conditions were found to be 1,329m2/g and 0.4167 cm3/g. The potentiality of the copper adsorption onto the best quality activated carbon with the highest surface area and pore volume was investigated. The maximum adsorption capacity of the activated carbon was 76.22mg/gat room temperature (28 oC). The copper (II) adsorption onto the activated carbon followed the pseudo-second-order kinetics which satisfied the Langmuir and Dubinin-Radushkevich (D-R) adsorption isotherms. Best activated carbon obtained from the present investigation may be recommended to use in water purification processes as a revamped copper (II) bio-adsorbent.
Keywords
References
Ahmaruzzaman M, Gayatri SL, J. Chem. Eng. Data, 55(11), 4614 (2010)
Tiryaki B, Yagmur E, Banford A, Aktas Z, J. Anal. Appl. Pyrolysis, 105, 276 (2014)
Gokce Y, Aktas Z, Appl. Surf. Sci., 313, 352 (2014)
Inal IIG, Holmes SM, Banford A, Aktas Z, Appl. Surf. Sci., 357, 696 (2015)
Goswami M, Phukan P, J. Environ. Chem. Eng., 5, 3508 (2017)
Kan Y, Yue Q, Li D, Wu Y, Gao B, J. Taiwan Inst. Chem. E., 71, 494 (2017)
Yagmur E, Turkoglu S, Banford A, Aktas Z, J. Clean Prod., 149, 1109 (2017)
Wong S, Lee Y, Ngadi N, Inuwa IM, Mohamed NB, Chinese J. Chem. Eng., 26, 1003 (2018)
Akar E, Altinis A, Seki Y, Ecol. Eng., 52, 19 (2013)
Islam MA, Benhouria A, Asif M, Hameed BH, J. Taiwan Inst. Chem. E., 52, 57 (2015)
Auta M, Int. J. Adv. Res. Technol., I(IV), 50 (2012).
Menon R, Singh J, Doshi V, Lim XY, J. Eng. Sci. Technol., Special Issue, 50 (2015).
Peng C, Yan XB, Wang RT, Lang JW, Ou YJ, Xue QJ, Electrochim. Acta, 87, 401 (2013)
DeokSeo S, Choi C, Kim BK, Kim DW, Ceram. Int., 43, 2836 (2017)
Gundogdu A, Duran C, Senturk HB, Soylak M, Imamoglu M, Onal Y, J. Anal. Appl. Pyrolysis, 104, 249 (2013)
Chen PA, Cheng HC, Wang HP, J. Clean Prod., 174, 927 (2018)
Auta M, Hameed BH, Chem. Eng. J., 175, 233 (2011)
Duran C, Ozdes D, Gundogdu A, Imamoglu M, Senturk HB, Anal. Chim. Acta, 688, 75 (2011)
Auta M, Hameed BH, Chem. Eng. J., 171(2), 502 (2011)
Kalyani P, Anitha A, Port. Electrochim. Acta, 31, 165 (2013)
Borah L, Goswami M, Phukan P, J. Environ. Chem. Eng., 3, 1018 (2015)
Garba ZN, Soib SFB, Rahim AA, J. Chem. Eng. Chem. Res., 2, 623 (2015)
Fan S, Wang Y, Tang J, Li H, Zhang H, Tang J, Wang Z, Li X, J. Mol. Liq., 220, 432 (2016)
Hettiarachchi AHP, Rajapakse CSK, J. Chem. Sci., 8, 7 (2018)
Zuorro A, Santarelli ML, Lavecchia R, Adv. Mater. Res., 803, 26 (2013)
Rani KM, Palanisamy PN, Gayathri S, Tamilselvi S, Int. J. Innov. Res. Sci. Eng. Technol., 4, 6845 (2015)
Vithanage M, Mayakaduwa SS, Herath I, Ok YS, Chemosphere, 150, 781 (2016)
Gundogdu A, Duran C, Senturk HB, Soylak M, Ozdes D, Serencam H, Imamoglu M, J. Chem. Eng. Data, 57(10), 2733 (2012)
Rajapaksha AU, Vithanage M, Zhang M, Ahmad M, Mohan D, Chang SX, Ok YS, Bioresour. Technol., 166, 303 (2014)
Dutta M, Das U, Mondal S, Bhattachriya S, Khatun R, Bagal R, Int. J. Environ. Sci., 6, 270 (2015)
Li J, Yu G, Pan L, Li C, You F, Xie S, Wang Y, Ma J, Shang X, J. Environ. Sci., 73, 20 (2018)
Borah L, Senapati KK, Borgohain C, Sarma S, Roy S, Phukan P, J. Porous Mat., 19, 1 (2011)
Isah UA, Lawal M, Adv. Appl. Sci. Res., 3, 4033 (2012)
Wang XJ, Liang X, Wang Y, Wang X, Liu MA, Yin DQ, Xia SQ, Zhao JF, Zhang YL, Desalination, 278(1-3), 231 (2011)
Demirbas E, Dizge N, Sulak MT, Kobya M, Chem. Eng. J., 148(2-3), 480 (2009)
Pirajan JCM, Giraldo L, J. Anal. Appl. Pyrolysis, 87, 188 (2010)
Bouhamed F, Elouear Z, Bouzid J, J. Taiwan Inst. Chem. E., 43, 741 (2012)
Demiral H, Gungor C, J. Clean Prod., 124, 103 (2016)
Badmus MOA, Audu TOK, Anyata B, Korean J. Chem. Eng., 24(2), 246 (2007)
Sayan E, Chem. Eng. J., 115(3), 213 (2006)
Kalavathy MH, Karthikeyan T, Rajgopal S, Miranda LR, J. Colloid Interface Sci., 292(2), 354 (2005)
Periasamy K, Namasivayam C, Chemosphere, 32, 769 (1996)
Namasivayam C, Kadirvelu K, Chemosphere, 34, 377 (1997)
Rao MM, Ramesh A, Rao GPC, Seshaiah K, J. Hazard. Mater., B129, 123 (2006)
Du J, Liu L, Zhang L, Yu Y, Zhang Y, Chen A, J. Renew. Sustain. Energy, 9, 1 (2017)
Hu Z, Srinivasan MP, Ni Y, Carbon, 39, 877 (2001)
Bansal RC, Goyal M, Activated Carbon Adsorption, Taylor and Francis Group, CRC Press, Boca Raton, FL (2005).
Tang L, Yu JF, Pang Y, Zeng GM, Deng YC, Wang JJ, Ren XY, Ye SJ, Peng B, Feng HP, Chem. Eng. J., 336, 160 (2018)
Yu JF, Tang L, Pang Y, Zeng GM, Wang JJ, Deng YC, Liu YN, Feng HP, Chen S, Ren XY, Chem. Eng. J., 364, 146 (2019)
Budinova T, Ekinci E, Yardim F, Grimm A, Bjornbom E, Minkova V, Goranova M, Fuel Process. Technol., 87(10), 899 (2006)
Wang Z, Nie E, Li J, Yang M, Zhao Y, Luo X, Zheng Z, Environ. Sci. Pollut. Res., 19, 2908 (2012)
Li Y, Jin H, Liu W, Su H, Lu Y, Li J, Sci. Rep., 8, 1 (2018)
Danish M, Hashim R, Ibrahim MNM, Sulaiman OJ, Anal. Appl. Pyrolysis, 104, 418 (2013)
Luo Z, Yu T, Ni Z, Lim S, Hu H, Shang J, Liu L, Shen Z, Lin J, J. Phys. Chem. C, 115, 1422 (2011)
Liu Y, Liu X, Dong W, Zhang L, Kong Q, Wang W, Sci. Rep., 7, 1 (2017)
Ozcan A, Ozcan AS, Tunali S, Akar T, Kiran I, J. Hazard. Mater., B124, 200 (2005)
Sandy, Maramis V, Kurniawan A, Ayucitra A, Sunarso J, Ismadji S, Front. Chem. Sci. Eng., 6, 58 (2012)
Homagai PL, Ghimire KN, Inoue K, Bioresour. Technol., 101(6), 2067 (2010)
Gao X, Wu L, Xu Q, Tian W, Li Z, Kobayashi N, Environ. Sci. Pollut. Res., 25, 7907 (2018)
Cheng Z, Zhang L, Guo X, Jiang X, Li T, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 137, 1126 (2015)
Ghaedi M, Ansari A, Habibi MH, Habibi AR, J. Ind. Eng. Chem., 20(1), 17 (2014)
Gonzalez PG, Pliego-Cuervo YB, Chem. Eng. Res. Des., 92(11), 2715 (2014)
Kose TE, Demiral H, Ozturk N, Desalin. Water Treat., 29, 110 (2011)
Ahmad A, Rafatullah M, Sulaiman O, Ibrahim MH, Chii YY, Siddique BM, Desalination, 247(1-3), 636 (2009)
Infrared spectroscopy adsorption table, chemistry, LibreTextsTM https://chem.libretexts.org/Reference/Reference_Tables/Spectroscopic_Parameters/Infrared_Spectroscopy_Absorption_Table.
Sizes of Atoms and Ions, LibreTextsTMhttps://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_Chemistry_-_The_Central_Science_(Brown_et_al.)/07._Periodic_Properties_of_the_Elements/7.3%3A_Sizes_of_Atoms_and_Ions.
Tiryaki B, Yagmur E, Banford A, Aktas Z, J. Anal. Appl. Pyrolysis, 105, 276 (2014)
Gokce Y, Aktas Z, Appl. Surf. Sci., 313, 352 (2014)
Inal IIG, Holmes SM, Banford A, Aktas Z, Appl. Surf. Sci., 357, 696 (2015)
Goswami M, Phukan P, J. Environ. Chem. Eng., 5, 3508 (2017)
Kan Y, Yue Q, Li D, Wu Y, Gao B, J. Taiwan Inst. Chem. E., 71, 494 (2017)
Yagmur E, Turkoglu S, Banford A, Aktas Z, J. Clean Prod., 149, 1109 (2017)
Wong S, Lee Y, Ngadi N, Inuwa IM, Mohamed NB, Chinese J. Chem. Eng., 26, 1003 (2018)
Akar E, Altinis A, Seki Y, Ecol. Eng., 52, 19 (2013)
Islam MA, Benhouria A, Asif M, Hameed BH, J. Taiwan Inst. Chem. E., 52, 57 (2015)
Auta M, Int. J. Adv. Res. Technol., I(IV), 50 (2012).
Menon R, Singh J, Doshi V, Lim XY, J. Eng. Sci. Technol., Special Issue, 50 (2015).
Peng C, Yan XB, Wang RT, Lang JW, Ou YJ, Xue QJ, Electrochim. Acta, 87, 401 (2013)
DeokSeo S, Choi C, Kim BK, Kim DW, Ceram. Int., 43, 2836 (2017)
Gundogdu A, Duran C, Senturk HB, Soylak M, Imamoglu M, Onal Y, J. Anal. Appl. Pyrolysis, 104, 249 (2013)
Chen PA, Cheng HC, Wang HP, J. Clean Prod., 174, 927 (2018)
Auta M, Hameed BH, Chem. Eng. J., 175, 233 (2011)
Duran C, Ozdes D, Gundogdu A, Imamoglu M, Senturk HB, Anal. Chim. Acta, 688, 75 (2011)
Auta M, Hameed BH, Chem. Eng. J., 171(2), 502 (2011)
Kalyani P, Anitha A, Port. Electrochim. Acta, 31, 165 (2013)
Borah L, Goswami M, Phukan P, J. Environ. Chem. Eng., 3, 1018 (2015)
Garba ZN, Soib SFB, Rahim AA, J. Chem. Eng. Chem. Res., 2, 623 (2015)
Fan S, Wang Y, Tang J, Li H, Zhang H, Tang J, Wang Z, Li X, J. Mol. Liq., 220, 432 (2016)
Hettiarachchi AHP, Rajapakse CSK, J. Chem. Sci., 8, 7 (2018)
Zuorro A, Santarelli ML, Lavecchia R, Adv. Mater. Res., 803, 26 (2013)
Rani KM, Palanisamy PN, Gayathri S, Tamilselvi S, Int. J. Innov. Res. Sci. Eng. Technol., 4, 6845 (2015)
Vithanage M, Mayakaduwa SS, Herath I, Ok YS, Chemosphere, 150, 781 (2016)
Gundogdu A, Duran C, Senturk HB, Soylak M, Ozdes D, Serencam H, Imamoglu M, J. Chem. Eng. Data, 57(10), 2733 (2012)
Rajapaksha AU, Vithanage M, Zhang M, Ahmad M, Mohan D, Chang SX, Ok YS, Bioresour. Technol., 166, 303 (2014)
Dutta M, Das U, Mondal S, Bhattachriya S, Khatun R, Bagal R, Int. J. Environ. Sci., 6, 270 (2015)
Li J, Yu G, Pan L, Li C, You F, Xie S, Wang Y, Ma J, Shang X, J. Environ. Sci., 73, 20 (2018)
Borah L, Senapati KK, Borgohain C, Sarma S, Roy S, Phukan P, J. Porous Mat., 19, 1 (2011)
Isah UA, Lawal M, Adv. Appl. Sci. Res., 3, 4033 (2012)
Wang XJ, Liang X, Wang Y, Wang X, Liu MA, Yin DQ, Xia SQ, Zhao JF, Zhang YL, Desalination, 278(1-3), 231 (2011)
Demirbas E, Dizge N, Sulak MT, Kobya M, Chem. Eng. J., 148(2-3), 480 (2009)
Pirajan JCM, Giraldo L, J. Anal. Appl. Pyrolysis, 87, 188 (2010)
Bouhamed F, Elouear Z, Bouzid J, J. Taiwan Inst. Chem. E., 43, 741 (2012)
Demiral H, Gungor C, J. Clean Prod., 124, 103 (2016)
Badmus MOA, Audu TOK, Anyata B, Korean J. Chem. Eng., 24(2), 246 (2007)
Sayan E, Chem. Eng. J., 115(3), 213 (2006)
Kalavathy MH, Karthikeyan T, Rajgopal S, Miranda LR, J. Colloid Interface Sci., 292(2), 354 (2005)
Periasamy K, Namasivayam C, Chemosphere, 32, 769 (1996)
Namasivayam C, Kadirvelu K, Chemosphere, 34, 377 (1997)
Rao MM, Ramesh A, Rao GPC, Seshaiah K, J. Hazard. Mater., B129, 123 (2006)
Du J, Liu L, Zhang L, Yu Y, Zhang Y, Chen A, J. Renew. Sustain. Energy, 9, 1 (2017)
Hu Z, Srinivasan MP, Ni Y, Carbon, 39, 877 (2001)
Bansal RC, Goyal M, Activated Carbon Adsorption, Taylor and Francis Group, CRC Press, Boca Raton, FL (2005).
Tang L, Yu JF, Pang Y, Zeng GM, Deng YC, Wang JJ, Ren XY, Ye SJ, Peng B, Feng HP, Chem. Eng. J., 336, 160 (2018)
Yu JF, Tang L, Pang Y, Zeng GM, Wang JJ, Deng YC, Liu YN, Feng HP, Chen S, Ren XY, Chem. Eng. J., 364, 146 (2019)
Budinova T, Ekinci E, Yardim F, Grimm A, Bjornbom E, Minkova V, Goranova M, Fuel Process. Technol., 87(10), 899 (2006)
Wang Z, Nie E, Li J, Yang M, Zhao Y, Luo X, Zheng Z, Environ. Sci. Pollut. Res., 19, 2908 (2012)
Li Y, Jin H, Liu W, Su H, Lu Y, Li J, Sci. Rep., 8, 1 (2018)
Danish M, Hashim R, Ibrahim MNM, Sulaiman OJ, Anal. Appl. Pyrolysis, 104, 418 (2013)
Luo Z, Yu T, Ni Z, Lim S, Hu H, Shang J, Liu L, Shen Z, Lin J, J. Phys. Chem. C, 115, 1422 (2011)
Liu Y, Liu X, Dong W, Zhang L, Kong Q, Wang W, Sci. Rep., 7, 1 (2017)
Ozcan A, Ozcan AS, Tunali S, Akar T, Kiran I, J. Hazard. Mater., B124, 200 (2005)
Sandy, Maramis V, Kurniawan A, Ayucitra A, Sunarso J, Ismadji S, Front. Chem. Sci. Eng., 6, 58 (2012)
Homagai PL, Ghimire KN, Inoue K, Bioresour. Technol., 101(6), 2067 (2010)
Gao X, Wu L, Xu Q, Tian W, Li Z, Kobayashi N, Environ. Sci. Pollut. Res., 25, 7907 (2018)
Cheng Z, Zhang L, Guo X, Jiang X, Li T, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 137, 1126 (2015)
Ghaedi M, Ansari A, Habibi MH, Habibi AR, J. Ind. Eng. Chem., 20(1), 17 (2014)
Gonzalez PG, Pliego-Cuervo YB, Chem. Eng. Res. Des., 92(11), 2715 (2014)
Kose TE, Demiral H, Ozturk N, Desalin. Water Treat., 29, 110 (2011)
Ahmad A, Rafatullah M, Sulaiman O, Ibrahim MH, Chii YY, Siddique BM, Desalination, 247(1-3), 636 (2009)
Infrared spectroscopy adsorption table, chemistry, LibreTextsTM https://chem.libretexts.org/Reference/Reference_Tables/Spectroscopic_Parameters/Infrared_Spectroscopy_Absorption_Table.
Sizes of Atoms and Ions, LibreTextsTMhttps://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_Chemistry_-_The_Central_Science_(Brown_et_al.)/07._Periodic_Properties_of_the_Elements/7.3%3A_Sizes_of_Atoms_and_Ions.
