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Received October 31, 2018
Accepted January 17, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Surface-enhanced infrared detection of benzene in air using a porous metal-organic-frameworks film
Department of Chemical and Biological Engineering, Sookmyung Women’s University, 100 Cheongpa-ro 47 gil, Yongsan-gu, Seoul 04310, Korea 1Department of Materials Science & Engineering, KAIST, Daejeon 34141, Korea
Korean Journal of Chemical Engineering, June 2019, 36(6), 975-980(6), 10.1007/s11814-018-0231-0
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Abstract
Infrared (IR) spectroscopy is a powerful technique for observing organic molecules, as it combines sensitive vibrational excitations with a non-destructive probe. However, gaseous volatile compounds in the air are challenging to detect, as they are not easy to immobilize in a sensing device and give enough signal by themselves. In this study, we fabricated a thin nanocrystalline metal-organic framework (nMOF) film on a surface plasmon resonance (SPR) substrate to enhance the IR vibration signal of the gaseous volatile compounds captured within the nMOF pores. Specifically, we synthesized nanocrystalline HKUST-1 (nHKUST-1) particles of ca. 80 nm diameter and used a colloidal dispersion of these particles to fabricate nHKUST-1 films by a spin-coating process. After finding that benzene was readily adsorbed onto nHKUST-1, an nHKUST-1 film deposited on a plasmonic Au substrate was successfully applied to the IR detection of gaseous benzene in air using surface-enhanced IR spectroscopy.
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References
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Osawa M, Top. Appl. Phys., 81, 163 (2001)
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Jeffers JD, Roller CB, Namjou K, Anal. Chem., 76, 424 (2004)
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Etzkorn JM, Davey NG, Thompson AJ, Creba AS, LeBlanc CW, Simpson CD, Krogh ET, Gill CG, J. Chromatogr. Sci., 47, 57 (2009)
Chui SSY, Lo SMF, Charmant JPH, Orpen AG, Williams ID, Science, 283(5405), 1148 (1999)
Okada K, Ricco R, Tokudome Y, Styles MJ, Hill AJ, Takahashi M, Falcaro P, Adv. Funct. Mater., 24(14), 1969 (2014)
Zhao ZX, Wang S, Yang Y, Li XM, Li J, Li Z, Chem. Eng. J., 259, 79 (2015)
Choi KM, Park JH, Kang JK, Chem. Mater., 27, 5088 (2015)
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Sugikawa K, Nagata S, Furukawa Y, Kokado K, Sada K, Chem. Mater., 25, 2565 (2013)
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Xian S, Yu Y, Xiao J, Zhang Z, Xia Q, Wang H, Li Z, RSC Adv., 5, 1827 (2015)
Chen X, Guo Z, Xu WH, Yao HB, Li MQ, Liu JH, Huang XJ, Yu SH, Adv. Funct. Mater., 21(11), 2049 (2011)
Tian ZQ, Ren B, Wu DY, J. Phys. Chem. B, 106(37), 9463 (2002)
Talley CE, Jackson JB, Oubre C, Grady NK, Hollars CW, Lane SM, Huser TR, Nordlander P, Halas NJ, Nano Lett., 5, 1569 (2005)
Pirzadeh K, Ghoreyshi AA, Rahimnejad M, Mohammadi M, Korean J. Chem. Eng., 35(4), 974 (2018)
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