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Received November 7, 2018
Accepted April 27, 2019
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A comparative study on dynamic Hg(II) and MeHg(II) removal by functionalized agrowaste adsorbent: breakthrough analysis and adsorber design
Norasikin Saman1
Helen Kong2
Safia Syazana Mohtar1
Khairiraihanna Johari3
Azmi Fadziyana Mansor1
Onn Hassan1
Noorhalieza Ali1
Hanapi Mat1 4†
1Advanced Materials and Process Engineering Laboratory, School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia 2Centre of Lipid Engineering and Applied Research, Level 2, Block C08, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia 3Department of Chemical Engineering, Faculty of Engineering, Universiti Teknologi PETRONAS, 32610, Bandar Seri Iskandar, Perak, Malaysia 4Advanced Materials and Separation Technologies (AMSET) Research Group, Health and Wellness Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
Korean Journal of Chemical Engineering, July 2019, 36(7), 1069-1081(13), 10.1007/s11814-019-0285-z
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Abstract
The adsorption dynamics of inorganic mercury, Hg(II) and organic methylmercury, MeHg(II) removal by low-cost reactive agrowaste adsorbents namely CP-Pure, CP-MPTES and CP-RR was investigated in a fixed-bed adsorber. The results show that the breakthrough and saturation times were delayed with decreasing flow rate (F) and initial concentration (Co), and increasing bed height (Z). The Hg(II) possessed better adsorption performance than MeHg(II). The isotherm and kinetic model analyses of adsorption data followed the Temkin isotherm and the pseudosecond order kinetic models, respectively. The breakthrough curve was simulated well by the Thomas and Yoon-Nelson models, and then was further used for scale-up studies. The empty bed contact time (EBCT) concept was successfully demonstrated for the adsorber design and scale-up studies. The regeneration studies showed that the regenerated CP-Pure and CP-MPTES have a high regeneration efficiency up to third adsorption cycle.
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