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Received January 23, 2019
Accepted May 25, 2019
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Effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst for water-gas shift reaction
Hyun-Suk Na
Seon-Yong Ahn
Jae-Oh Shim
Kyung-Won Jeon
Hak-Min Kim
Yeol-Lim Lee
Won-Jun Jang1
Byong-Hun Jeon2†
Hyun-Seog Roh†
Department of Environmental Engineering, Yonsei University, 1 Yonseidae-gil, Wonju, Gangwon 26493, Korea 1Department of Environmental and Energy Engineering, Kyungnam University, 7 Kyungnamdaehak-ro, Changwon-si, Gyeongsangnam-do 51767, Korea 2Department of Earth Resources and Environmental Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Korea
Korean Journal of Chemical Engineering, August 2019, 36(8), 1243-1248(6), 10.1007/s11814-019-0309-8
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Abstract
To investigate the effect of precipitation on physico-chemical and catalytic properties of Cu-Zn-Al catalyst, the pH value and injection rate in the precipitation process were systematically changed, and the water-gas shift reaction was carried out. The Cu-Zn-Al catalyst showed the highest CO conversion when the optimized synthesis parameters (i.e., pH=10-10.5 and injection rate=30ml/min) were employed. This is mainly due to the enhanced physicochemical properties such as a high Brunauer-Emmett-Teller surface area, small crystallite size, high Cu dispersion, and easier reducibility.
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Yahiro H, Murawaki K, Saiki K, Yamamoto T, Yamaura H, Catal. Today, 126(3-4), 436 (2007)
Shishido T, Yamamoto M, Li DL, Tian Y, Morioka H, Honda M, Sano T, Takehira K, Appl. Catal. A: Gen., 303(1), 62 (2006)
Fu W, Bao Z, Ding W, Chou K, Li Q, Catal. Commun., 12, 505 (2011)
Simson G, Prasetyo E, Reiner S, Hinrichsen O, Appl. Catal. A: Gen., 450, 1 (2013)
Kowalik P, Prochniak W, Konkol M, Borowiecki T, Appl. Catal. A: Gen., 423-424, 15 (2012)
Kowalik P, Prochniak W, Borowiecki T, Catal. Today, 176(1), 144 (2011)
Lima AAG, Nele M, Moreno EL, Andrade HMC, Appl. Catal. A: Gen., 171(1), 31 (1998)
Xiao S, Zhang YF, Gao P, Zhong LS, Li XP, Zhang ZZ, Wang H, Wei W, Sun YH, Catal. Today, 281, 327 (2017)
Shen JP, Song CS, Catal. Today, 77(1-2), 89 (2002)
Guo Y, Meyer-Zaike W, Muhler M, Vukojevi S. Epple M, Eur. J. Inorg. Chem., 2006, 4774 (2006)
Saedy S, Haghighi M, Amirkhosrow M, Particuology, 10, 729 (2012)
Behrens M, Brennecke D, Girgsdies F, Kissner S, Trunschke A, Nasrudin N, Zakaria S, Idris NF, Abd Hamid SB, Kniep B, Fischer R, Busser W, Muhler M, Schlogl R, Appl. Catal. A: Gen., 392(1-2), 93 (2011)
Budiman A, Ridwan M, Kim SM, Choi JW, Yoon CW, Ha JM, Suh DJ, Suh YW, Appl. Catal. A: Gen., 462-463, 220 (2013)
Kuhl S, Friedrich M, Armbruster M, Behrens M, J. Mater. Chem., 22, 9632 (2012)
Thomas J, Thomas N, Girgsdies F, Beherns M, Huang X, Sudheesh VD, Sebastian V, New J. Chem., 41, 7356 (2017)
Jang WJ, Kim HM, Shim JO, Yoo SY, Jeon KW, Na HS, Lee YL, Jeong DW, Bae JW, Nah IW, Green Chem., 20, 1621 (2018)
Li JL, Inui T, Appl. Catal. A: Gen., 137(1), 105 (1996)
Jung H, Yang DR, Joo OS, Jung KD, Bull Korean Chem. Soc., 31, 1241 (2010)
Baltes C, Vukojevic S, Schuth F, J. Catal., 258(2), 334 (2008)
Bems B, Schur M, Dassenoy A, Junkes H, Herein D, Schlogl R, Chem. Eur. J., 9, 2039 (2003)
Na HS, Shim JO, Jang WJ, Jeon KW, Kim HM, Lee YL, Lee DW, Yoo SY, Bae JW, Rode CV, Roh HS, Catal. Today, 309, 83 (2018)
Allahyari S, Haghighi M, Ebadi A, Saeedi HQ, J. Power Sources, 272, 929 (2014)
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Na HS, Ahn CI, Jha A, Park KS, Jang WJ, Shim JO, Jeong DW, Roh HS, Bae JW, RSC Adv., 6, 52754 (2016)
Jeong DW, Na HS, Shim JO, Jang WJ, Roh HS, Jung UH, Yoon WL, Int. J. Hydrog. Energy, 39(17), 9135 (2014)
Jeong DW, Jang WJ, Shim JO, Han WB, Roh HS, Jung UH, Yoon WL, Renew. Energy, 65, 102 (2014)
Na HS, Shim JO, Ahn SY, Jang WJ, Jeon KW, Kim HM, Lee YL, Kim KJ, Roh HS, Int. J. Hydrog. Energy, 43(37), 17718 (2018)
Na HS, Jeong DW, Jang WJ, Shim JO, Roh HS, Int. J. Hydrog. Energy, 40(36), 12268 (2015)
Shim JO, Hong YJ, Na HS, Jang WJ, Kang YC, Roh HS, ACS Appl. Mater. Interfaces, 8, 17239 (2016)
Jeon KW, Shim JO, Jang WJ, Lee DW, Na HS, Kim HM, Lee YL, Yoo SY, Roh HS, Jeon BH, Bae JW, Ko CH, Renew. Energy, 131, 144 (2019)
Lee YL, Jha A, Jang WJ, Shim JO, Jeon KW, Na HS, Kim HM, Lee DW, Yoo SY, Jeon BH, Bae JW, Roh HS, Top Catal., 60, 721 (2017)
Amirsalari A, Shayesteh SF, Superlattices Microstruct., 82, 507 (2015)
Amin G, Asif M, Zainelabdin A, Zaman S, Nur O, Willander M, J. Nanomaterials, 2011, 1 (2011)
Chu YY, Wang ZB, Jiang ZZ, Gu DM, Yin GP, Fuel Cells, 10, 914 (2010)
Wang Q, Cui M, Hou Y, Zhong Q, Yue M, Huang X, J. Alloy. Compd., 712, 431 (2017)
Sun YZ, Ma L, Zhou BB, Gao P, Int. J. Hydrog. Energy, 37(3), 2336 (2012)
Guo PJ, Chen LF, Yang QY, Qiao MH, Li H, Li HX, Xu HL, Fan KN, Int. J. Hydrog. Energy, 34(5), 2361 (2009)
Yao SY, Xu WQ, Johnston-Peck AC, Zhao FZ, Liu ZY, Luo S, Senanayake SD, Martinez-Arias A, Liu WJ, Rodriguez JA, Phys. Chem. Chem. Phys., 16, 17183 (2014)
Jeong DW, Jang WJ, Shim JO, Han WB, Jeon KW, Seo YC, Roh HS, Gu JH, Lim YT, J. Mater. Cycles Waste Manage., 16, 650 (2014)
Gomez-Cuaspud JA, Schmal M, Int. J. Hydrog. Energy, 38(18), 7458 (2013)
Yang XH, Wang W, Xiong JL, Chen L, Ma Y, Int. J. Hydrog. Energy, 40(36), 12604 (2015)
Wang Y, Li ZB, Demopoulos GP, J. Cryst. Growth, 310(6), 1220 (2008)
Kramer E, Podurgiel J, Wei M, Mater. Lett., 131, 145 (2014)
Yahiro H, Murawaki K, Saiki K, Yamamoto T, Yamaura H, Catal. Today, 126(3-4), 436 (2007)
