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Received December 13, 2018
Accepted May 25, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Superhydrophobic and superoleophilic nickel foam for oil/water separation
Department of Applied Chemistry & Biotechnology, Hanbat National University, 125 Dongseo-daero, Yuseong-gu, Daejeon 34152, Korea 1HanKook Tech, 199, Techno 2-ro, Yuseong-gu, Daejeon 34025, Korea 2Agency for Defense Development (ADD), Yuseong P.O. Box 35-5, Daejeon 34602, Korea
jmko@hanbat.ac.kr
Korean Journal of Chemical Engineering, August 2019, 36(8), 1313-1320(8), 10.1007/s11814-019-0308-9
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Abstract
Superhydrophobic and superoleophilic Ni foam was fabricated by immersion coating and drying method. The Ni foam was immersed in a mixture containing polytetrafluoroethylene (PTFE) and hydrophobic fumed silica (R805). The mixture was dispersed in a poly(vinylidene fluoride) (PVDF) solution and the PVDF was used as a binder. The as-prepared Ni foam showed superhydrophobic and superoleophilic properties simultaneously and had a water contact angle (WCA) of 155° for water and an oil contact angle (OCA) of 0° for oil. The PTFE-coated Ni foam maintained high separation efficiency after repeated separations (40 times) above 96% for the more viscous olive oil/water mixture and above 99% for the hexane/water mixture. The as-prepared nickel foam proved to be an excellent candidate for the separation of oil and water mixtures.
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Youngblood JP, Mccarthy TJ, Macromol., 32, 6800 (1999)
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