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Received February 20, 2019
Accepted June 12, 2019
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Aminosilane cross-linked poly ether-block-amide PEBAX 2533: Characterization and CO2 separation properties
Hamidreza Sanaeepur1†
Samaneh Mashhadikhan1
Ghassem Mardassi2
Abtin Ebadi Amooghin1
Bart Van der Bruggen3 4
Abdolreza Moghadassi1
1Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran 2Faculty of Chemical Engineering, Islamic Azad University, Mahshahr Branch, Mahshahr, Iran 3Department of Chemical Engineering, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium 4Faculty of Engineering and the Built Environment, Tshwane University of Technology, Private Bag X680, Pretoria 0001, South Africa
Korean Journal of Chemical Engineering, August 2019, 36(8), 1339-1349(11), 10.1007/s11814-019-0323-x
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Abstract
Commercial poly (ether-block-amide) (Pebax®) copolymers are thermoplastic elastomers that have attracted attention as membrane materials due to their high performance in CO2 separation. In this study, a cross-linking reaction is reported as a viable strategy to improve the gas separation performance of a highly permeable but low selective Pebax 2533 membrane. To this end, a new bi-functional aminosilane cross-linker (3-aminopropyl(diethoxy)methylsilane (APDEMS)) was applied. Cross-linked Pebax 2533 membranes were prepared via solution-casting with different amounts of APDEMS ranging from 0.5 to 4 wt%, to investigate the effect of the aminosilane concentration on the membrane performance. Gas separation with prepared membranes was studied for CO2/N2 at the feed pressure ranges of 2-10 bar. Instrumental analyses were applied to investigate the effect of the cross-linking reaction on the structure and properties of the membranes. The results showed that a 2 wt% APDEMS cross-linked Pebax 2533 membrane has the best gas separation performance. The CO2/N2 ideal selectivity of the cross-linked Pebax 2533 increased twice compared to the neat Pebax 2533 membrane at the feed pressure of 2 bar, while the CO2 permeability experienced a slight decrease by cross-linking, but still remains higher than the permeability of other Pebax grades.
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Rajabi Z, Taromi FA, Kargari A, Sanaeepur H, Iranian J. Polym. Sci. Technol., 28, 211 (2015)
Esmaeilipur M, Kargari A, Sanaeepur H, Iranian J. Polym. Sci. Technol., 29, 505 (2017)
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Liu Y, Yu SN, Wu H, Li YF, Wang SF, Tian ZZ, Jiang ZY, J. Membr. Sci., 469, 198 (2014)
Wang L, Li Y, Li S, Ji P, Jiang C, J. Energy Chem., 2, 717 (2014)
Amooghin AE, Pedram MZ, Omidkhah M, Yegani R, Greenh. Gases Sci. Technol., 3, 378 (2013)
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Katsumata T, Shiotsuki M, Sanda F, Masuda T, Polymer, 50(6), 1389 (2009)
Saied O, Maris T, Wuest JD, J. Am. Chem. Soc., 125(49), 14956 (2003)
Bermeshev MV, Syromolotov AV, Starannikova LE, Gringolts ML, Lakhtin VG, Yampolskii YP, Finkelshtein ES, Macromolecules, 46(22), 8973 (2013)
Sanaeepur H, Kargari A, Nasernejad B, RSC Adv., 4, 63966 (2014)
Amooghin AE, Omidkhah M, Kargari A, J. Membr. Sci., 490, 364 (2015)
Nik OG, Chen XY, Kaliaguine S, J. Membr. Sci., 379(1-2), 468 (2011)
Jusoh N, Yeong YF, Lau KK, Shariff AM, J. Clean Prod., 166, 1043 (2017)
Car A, Stropnik C, Yave W, Peinemann KV, Sep. Purif. Technol., 62(1), 110 (2008)
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Chung TS, Jiang LY, Li Y, Kulprathipanja S, Prog. Polym. Sci, 32, 483 (2007)
Le NL, Wang Y, Chung TS, J. Membr. Sci., 379(1-2), 174 (2011)
Azizi N, Mahdavi HR, Isanejad M, Mohammadi T, J. Polym. Res., 24, 141 (2017)
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Amooghin AE, Lashani M, Sharifzadeh MMM, Sanaeepur H, Sep. Purif. Technol., 225, 112 (2019)
Labreche Y, J. Membr. Sci. Res., 2, 59 (2016)
Kargari A, Sanaeepur H, in: Advances in Petroleum EngineeringI: Studium Press LLC, Houston, USA (2015).
Zamiri MA, Kargari A, Sanaeepur H, Greenh. Gases Sci. Technol., 5, 668 (2015)
Wang S, Li X, Wu H, Tian Z, Xin Q, He G, Peng D, Chen S, Yin Y, Jiang Z, Guiver MD, Energy. Environ. Sci., 9, 1863 (2016)
Ebadi Amooghin A, Mashhadikhan S, Sanaeepur H, Moghadassi A, Matsuura T, Ramakrishna S, Prog. Mater Sci., 102, 222 (2019)
Sanaeepur H, Ebadi amooghin A, Moghadassi A, Kargari A, Ghanbari D, Sheikhi Mehrabadi Z, Nademi M, Iranian J. Polym. Sci. Technol., 23, 17 (2010)
Bandehali S, Kargari A, Moghadassi A, Saneepur H, Ghanbari D, Asia.Pac. J. Chem. Eng., 9, 638 (2014)
Rezakazemi M, Amooghin AE, Montazer-Rahmati MM, Ismail AF, Matsuura T, Prog. Polym. Sci, 39, 817 (2014)
Amooghin AE, Sanaeepur H, Moghadassi A, Kargari A, Ghanbari D, Mehrabadi ZS, Sep. Sci. Technol., 45(10), 1385 (2010)
Sanaeepur H, Amooghin AE, Moghadassi A, Kargari A, Moradi S, Ghanbari D, Polym. Adv. Technol., 23, 1207 (2012)
Sanaeepur H, Amooghin AE, Moghadassi A, Kargari A, Sep. Purif. Technol., 80(3), 499 (2011)
Amooghin AE, Omidkhah M, Kargari A, RSC Adv., 5, 8552 (5)
Robeson LM, J. Membr. Sci., 62, 165 (1991)
Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)
Kim S, Lee YM, Prog. Polym. Sci, 43, 1 (2015)
Li Y, He G, Wang S, Yu S, Pan F, Wu H, Jiang Z, J. Mater. Chem. A, 1, 10058 (2013)
Sanaeepur H, Amooghin AE, Bandehali S, Theoretical Gas Permeation Models for Mixed Matrix Membranes, LAP Lambert Academic Publishing, Beau Bassin, Mauritius (2018).
Amooghin AE, Sanaeepur H, Omidkhah M, Kargari A, J. Mater. Chem. A., 6, 1751 (2018)
Sanaeepur H, Amooghin AE, Khademian E, Kargari A, Omidkhah M, Polym. Composite., 39, 4560 (2018)
George G, Bhoria N, AlHallaq S, Abdala A, Mittal V, Sep. Purif. Technol., 158, 333 (2016)
Liu J, Hou X, Park HB, Lin H, Chem. Eur. J., 22, 15980 (2016)
Sanaeepur H, Amooghin AE, Bandehali S, Moghadassi A, Matsuura T, Van der Bruggen B, Prog. Polym. Sci, 91, 80 (2019)
Azari A, Abbasi MA, Sanaeepur H, Int. J. Greenh. Gas Con., 49, 81 (2016)
Alavi SA, Kargari A, Sanaeepur H, Karimi M, Res. Chem. Intermed., 43, 2959 (2017)
Ranjbaran F, Omidkhah MR, Amooghin AE, J. Taiwan Inst. Chem. Eng., 49, 220 (2015)
Li M, Zhang X, Zeng S, Gao H, Deng J, Yang Q, Zhang S, RSC Adv., 7, 6422 (2017)
Zhao D, Ren JZ, Wang Y, Qiu YT, Li H, Hua KS, Li XX, Ji JM, Deng MC, J. Membr. Sci., 521, 104 (2017)
Khalilinejad I, Sanaeepur H, Kargari A, J. Membr. Sci. Res., 1, 124 (2015)
Sanaeepur H, Ahmadi R, Amooghin AE, Ghanbari D, J. Membr. Sci., 573, 234 (2019)
Sanaeepur H, Ahmadi R, Sinaei M, Kargari A, J. Membr. Sci. Res., 5, 25 (2019)
Ahmadi R, Sanaeepur H, Amooghin AE, Heydari A, Iranian J. Polym. Sci. Technol., 31, 461 (2019)
Nafisi V, Hagg MB, J. Membr. Sci., 459, 244 (2014)
Bondar VI, Freeman BD, Pinnau I, J. Polym. Sci. B: Polym. Phys., 38(15), 2051 (2000)
Estahbanati EG, Omidkhah M, Amooghin AE, J. Ind. Eng. Chem., 51, 77 (2017)
Lee S, Park SC, Kim TY, Kang SW, Kang YS, J. Membr. Sci., 548, 358 (2018)
Estahbanati EG, Omidkhah M, Amooghin AE, ACS Appl. Mater. Interfaces, 9, 10094 (2017)
Zhang Y, Shen Q, Hou J, Sutrisna PO, Chen V, J. Mater. Chem. A, 5, 7732 (2017)
Khalilinejad I, Kargari A, Sanaeepur H, Chem. Pap., 71, 803 (2017)
Zhang N, Peng DD, Wu H, Ren YX, Yang LX, Wu XY, Wu YZ, Qu ZH, Jiang ZY, Cao XZ, J. Membr. Sci., 549, 670 (2018)
Xiang L, Pan YC, Zeng GF, Jiang JL, Chen J, Wang CQ, J. Membr. Sci., 500, 66 (2016)
Hosseinkhani O, Kargari A, Sanaeepur H, J. Membr. Sci., 469, 151 (2014)
Mane S, Ponrathnam S, Chavan N, Can. Chem. Trans., 3, 473 (2015)
Rajabi Z, Taromi FA, Kargari A, Sanaeepur H, Iranian J. Polym. Sci. Technol., 28, 211 (2015)
Esmaeilipur M, Kargari A, Sanaeepur H, Iranian J. Polym. Sci. Technol., 29, 505 (2017)
Jia R, Jin J, Lin S, Wang Y, Curr. Org. Chem., 20, 1945 (2016)
Sridhar S, Suryamurali R, Smitha B, Aminabhavi TM, Colloids Surf. A: Physicochem. Eng. Asp., 297, 267 (2007)
Liu Y, Yu SN, Wu H, Li YF, Wang SF, Tian ZZ, Jiang ZY, J. Membr. Sci., 469, 198 (2014)
Wang L, Li Y, Li S, Ji P, Jiang C, J. Energy Chem., 2, 717 (2014)
Amooghin AE, Pedram MZ, Omidkhah M, Yegani R, Greenh. Gases Sci. Technol., 3, 378 (2013)
Tetsuka H, Hagiwara M, Kaita S, Polym. J., 43, 97 (2011)
Katsumata T, Shiotsuki M, Sanda F, Masuda T, Polymer, 50(6), 1389 (2009)
Saied O, Maris T, Wuest JD, J. Am. Chem. Soc., 125(49), 14956 (2003)
Bermeshev MV, Syromolotov AV, Starannikova LE, Gringolts ML, Lakhtin VG, Yampolskii YP, Finkelshtein ES, Macromolecules, 46(22), 8973 (2013)
Sanaeepur H, Kargari A, Nasernejad B, RSC Adv., 4, 63966 (2014)
Amooghin AE, Omidkhah M, Kargari A, J. Membr. Sci., 490, 364 (2015)
Nik OG, Chen XY, Kaliaguine S, J. Membr. Sci., 379(1-2), 468 (2011)
Jusoh N, Yeong YF, Lau KK, Shariff AM, J. Clean Prod., 166, 1043 (2017)
Car A, Stropnik C, Yave W, Peinemann KV, Sep. Purif. Technol., 62(1), 110 (2008)
Mulder M, Basic principles of membrane technology, 2nd Ed., Kluwer Academic Publishers, Dordrecht, The Netherlands (1996).
Chung TS, Jiang LY, Li Y, Kulprathipanja S, Prog. Polym. Sci, 32, 483 (2007)
Le NL, Wang Y, Chung TS, J. Membr. Sci., 379(1-2), 174 (2011)
Azizi N, Mahdavi HR, Isanejad M, Mohammadi T, J. Polym. Res., 24, 141 (2017)
Coates J, Encyclopedia of analytical chemistry: applications, theory and instrumentation, John Wiley & Sons, Ltd., West Sussex, United Kingdom (2006).
Rahman MM, Filiz V, Shishatskiy S, Abetz C, Neumann S, Bolmer S, Khan MM, Abetz V, J. Membr. Sci., 437, 286 (2013)
Choi MC, Jung JY, Yeom HS, Chang YW, Polym. Eng. Sci., 53(5), 982 (2013)
Guan P, Luo J, Li W, Si Z, Macromol. Res., 25(10), 1007 (2017)
Tan S, Fu Q, Scofield JMP, Kim J, Gurr PA, Ladewig K, Blencowe A, Qiao GG, J. Mater. Chem. A, 3, 14876 (2015)
Fu Q, Halim A, Kim J, Scofield JMP, Gurr PA, Kentish SE, Qiao GG, J. Mater. Chem. A, 1, 13769 (2013)
Nguyen QT, Sublet J, Langevin D, Chappey C, Marais S, Valleton JM, Poncin-Epaillard F, in: Membrane gas separation, West Sussex, United Kingdom (2010).
Xiang L, Pan YC, Zeng GF, Jiang JL, Chen J, Wang CQ, J. Membr. Sci., 500, 66 (2016)
Murali RS, Sridhar S, Sankarshana T, Ravikumar YVL, Ind. Eng. Chem. Res., 49(14), 6530 (2010)
Kim JH, Ha SY, Lee YM, J. Membr. Sci., 190(2), 179 (2001)
Sharifzadeh MMM, Pedram MZ, Amooghin AE, Greenh. Gases Sci. Technol., (2019).
Amooghin AE, Lashani M, Sharifzadeh MMM, Sanaeepur H, Sep. Purif. Technol., 225, 112 (2019)
