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Received April 3, 2019
Accepted July 23, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Polyethylenimine-crosslinked chitin flake as a biosorbent for removal of Acid Blue 25
1Department of Marine Environmental Engineering, Gyeongsang National University, 2 Tongyeonghaean-ro, Tongyeong, Gyeongnam 53064, Korea 2Department of Ocean System Engineering, Gyeongsang National University, 2 Tongyeonghaean-ro, Tongyeong, Gyeongnam 53064, Korea
Korean Journal of Chemical Engineering, September 2019, 36(9), 1455-1465(11), 10.1007/s11814-019-0347-2
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Abstract
A chitin-based biosorbent that can be used to effectively remove dyes, typical color inducers in industrial wastewater, was developed. The crosslinking agent glutaraldehyde was bonded to the hydroxyl and/or amine groups of chitin, and then polyethylenimine (PEI), a cationic polymer, was cross-linked to produce PEI-chitin. The successful preparation of PEI-chitin was confirmed using FE-SEM, BET and FTIR analysis and simple adsorption evaluation. The adsorption performance of PEI-chitin was assessed by Acid Blue 25, in terms of the pH effect, isotherm adsorption, adsorption kinetic and thermodynamic parameters. Based on the Langmuir model the maximum dye uptake at pH 2 was 177.32mg/g, and the adsorption equilibrium was attained within 120 and 500 min for two different dye concentrations (50 and 100mg/L). Desorption experiments were evaluated using 0.001-1 M NaOH, NaHCO3, and Na2CO3 as eluents. The desorption rate was highest (85.2%) when 0.01 M NaOH was employed as the eluent. It was found that the developed biosorbent could be repeatedly used three times through adsorption-desorption of Acid Blue 25.
References
Gholivand MB, Yamini Y, Dayeni M, Seidi S, Environ. Prog. Sustain. Energy, 34, 1683 (2015)
Sadeghi-Kiakhani M, Arami M, Gharanjig K, J. Appl. Polym. Sci., 127(4), 2607 (2013)
Gupta VK, Suhas, J. Environ. Manage., 90, 2313 (2009)
Marungrueng K, Pavasant P, J. Environ. Manage., 78, 268 (2006)
Gottlieb A, Shaw C, Smith A, Wheatley A, Forsythe S, J. Biotechnol., 10, 49 (2003)
Choy KKH, Porter JF, Mckay G, Chem. Eng. J., 103(1-3), 133 (2004)
Sartape AS, Mandhare AM, Jadhav VV, Raut PD, Anuse MA, Kolekar SS, Arab. J. Chem., 10, S3299 (2017)
Aksu Z, Process Biochem., 40(3-4), 997 (2005)
Rangabhashiyam S, Anu N, Giri Nandagopal MS, Selvaraju N, J. Environ. Chem. Eng., 2, 398 (2014)
Mahmoodi NM, Sadeghi U, Maleki A, Hayati B, Najafi F, J. Ind. Eng. Chem., 20(5), 2745 (2014)
Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, Gholami Z, Amouzgar P, Carbohydr. Polym., 113, 115 (2014)
Dotto GL, Santos JMN, Rodrigues IL, Rosa R, Pavan FA, Lima EC, J. Colloid Interface Sci., 446, 133 (2015)
Guo Y, Duan B, Cui L, Zhu P, Cellulose, 22, 2035 (2015)
Cao YL, Pan ZH, Shi QX, Yu JY, Int. J. Biol. Macromol., 114, 392 (2018)
You L, Huang C, Lu F, Wang A, Liu X, Zhang Q, Int. J. Biol. Macromol., 107, 1620 (2018)
Ma Y, Liu WJ, Zhang N, Li YS, Jiang H, Sheng GP, Bioresour. Technol., 169, 403 (2014)
Won SW, Kwak IS, Yun YS, Bioresour. Technol., 160, 93 (2014)
Li R, An QD, Xiao ZY, Zhai B, Zhai SR, Shi Z, RSC Adv., 7, 40227 (2017)
Yang Q, Dou F, Liang B, Shen Q, Carbohydr. Polym., 59, 205 (2005)
Choi HA, Park HN, Won SW, J. Environ. Manage., 204, 200 (2017)
Wong YC, Szeto YS, Cheung WH, McKay G, Langmuir, 19(19), 7888 (2003)
Sun XF, Wang SG, Cheng W, Fan MH, Tian BH, Gao' BY, Li XM, J. Hazard. Mater., 189(1-2), 27 (2011)
Tan IAW, Ahmad AL, Hameed BH, J. Hazard. Mater., 154(1-3), 337 (2008)
Fytianos K, Voudrias E, Kokkalis E, Chemosphere, 40, 3 (2000)
Barka N, Ouzaouit K, Abdennouri M, El Makhfouk M, J. Taiwan Inst. Chem. Eng., 44, 52 (2013)
Ferrero F, J. Hazard. Mater., 142(1-2), 144 (2007)
Hanafiah MAKM, Ngah WSW, Zolkafly SH, Teong LC, Majid ZAA, J. Environ. Sci., 24, 261 (2012)
Jain SN, Gogate PR, Int. J. Environ. Sci. Technol., 14, 531 (2017)
Auta M, Hameed BH, Chem. Eng. J., 171(2), 502 (2011)
Kooh MRR, Dahri MK, Lim LBL, Lim LH, Chan CM, Appl. Water Sci., 8, 61 (2018)
Kooh MRR, Dahri MK, Lim LBL, Lim LH, Arab. J. Sci. Eng., 41, 2453 (2016)
Mawad AMM, Yousef NMH, Shoreit AMM, Catrina Int. J. Environ. Sci., 10, 53 (2015)
Al-Degs YS, El-Barghouthi MI, El-Sheikh AH, Walker GM, Dyes Pigment., 77, 16 (2008)
Gercel O, Ozcan A, Ozcan AS, Gercel HF, Appl. Surf. Sci., 253(11), 4843 (2007)
Dogan M, Alkan M, Demirbas O, Ozdemir Y, Ozmetin C, Chem. Eng. J., 124(1-3), 89 (2006)
Gu B, Schmitt J, Chen Z, Liang L, McCarthy JF, Environ. Sci. Technol., 28, 38 (1994)
Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)
Sadeghi-Kiakhani M, Arami M, Gharanjig K, J. Appl. Polym. Sci., 127(4), 2607 (2013)
Gupta VK, Suhas, J. Environ. Manage., 90, 2313 (2009)
Marungrueng K, Pavasant P, J. Environ. Manage., 78, 268 (2006)
Gottlieb A, Shaw C, Smith A, Wheatley A, Forsythe S, J. Biotechnol., 10, 49 (2003)
Choy KKH, Porter JF, Mckay G, Chem. Eng. J., 103(1-3), 133 (2004)
Sartape AS, Mandhare AM, Jadhav VV, Raut PD, Anuse MA, Kolekar SS, Arab. J. Chem., 10, S3299 (2017)
Aksu Z, Process Biochem., 40(3-4), 997 (2005)
Rangabhashiyam S, Anu N, Giri Nandagopal MS, Selvaraju N, J. Environ. Chem. Eng., 2, 398 (2014)
Mahmoodi NM, Sadeghi U, Maleki A, Hayati B, Najafi F, J. Ind. Eng. Chem., 20(5), 2745 (2014)
Vakili M, Rafatullah M, Salamatinia B, Abdullah AZ, Ibrahim MH, Tan KB, Gholami Z, Amouzgar P, Carbohydr. Polym., 113, 115 (2014)
Dotto GL, Santos JMN, Rodrigues IL, Rosa R, Pavan FA, Lima EC, J. Colloid Interface Sci., 446, 133 (2015)
Guo Y, Duan B, Cui L, Zhu P, Cellulose, 22, 2035 (2015)
Cao YL, Pan ZH, Shi QX, Yu JY, Int. J. Biol. Macromol., 114, 392 (2018)
You L, Huang C, Lu F, Wang A, Liu X, Zhang Q, Int. J. Biol. Macromol., 107, 1620 (2018)
Ma Y, Liu WJ, Zhang N, Li YS, Jiang H, Sheng GP, Bioresour. Technol., 169, 403 (2014)
Won SW, Kwak IS, Yun YS, Bioresour. Technol., 160, 93 (2014)
Li R, An QD, Xiao ZY, Zhai B, Zhai SR, Shi Z, RSC Adv., 7, 40227 (2017)
Yang Q, Dou F, Liang B, Shen Q, Carbohydr. Polym., 59, 205 (2005)
Choi HA, Park HN, Won SW, J. Environ. Manage., 204, 200 (2017)
Wong YC, Szeto YS, Cheung WH, McKay G, Langmuir, 19(19), 7888 (2003)
Sun XF, Wang SG, Cheng W, Fan MH, Tian BH, Gao' BY, Li XM, J. Hazard. Mater., 189(1-2), 27 (2011)
Tan IAW, Ahmad AL, Hameed BH, J. Hazard. Mater., 154(1-3), 337 (2008)
Fytianos K, Voudrias E, Kokkalis E, Chemosphere, 40, 3 (2000)
Barka N, Ouzaouit K, Abdennouri M, El Makhfouk M, J. Taiwan Inst. Chem. Eng., 44, 52 (2013)
Ferrero F, J. Hazard. Mater., 142(1-2), 144 (2007)
Hanafiah MAKM, Ngah WSW, Zolkafly SH, Teong LC, Majid ZAA, J. Environ. Sci., 24, 261 (2012)
Jain SN, Gogate PR, Int. J. Environ. Sci. Technol., 14, 531 (2017)
Auta M, Hameed BH, Chem. Eng. J., 171(2), 502 (2011)
Kooh MRR, Dahri MK, Lim LBL, Lim LH, Chan CM, Appl. Water Sci., 8, 61 (2018)
Kooh MRR, Dahri MK, Lim LBL, Lim LH, Arab. J. Sci. Eng., 41, 2453 (2016)
Mawad AMM, Yousef NMH, Shoreit AMM, Catrina Int. J. Environ. Sci., 10, 53 (2015)
Al-Degs YS, El-Barghouthi MI, El-Sheikh AH, Walker GM, Dyes Pigment., 77, 16 (2008)
Gercel O, Ozcan A, Ozcan AS, Gercel HF, Appl. Surf. Sci., 253(11), 4843 (2007)
Dogan M, Alkan M, Demirbas O, Ozdemir Y, Ozmetin C, Chem. Eng. J., 124(1-3), 89 (2006)
Gu B, Schmitt J, Chen Z, Liang L, McCarthy JF, Environ. Sci. Technol., 28, 38 (1994)
Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)
