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Received June 20, 2019
Accepted November 3, 2019
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Extraction of reactive dye via synergistic Aliquat 336/D2EHPA using emulsion liquid membrane system
Raja Norimie Raja Sulaiman1
Hilmi Abdul Rahman1
Norasikin Othman1 2†
Muhammad Bukhari Rosly1
Norela Jusoh1
Norul Fatiha Mohd Noah1
1School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bahru, Johor, Malaysia 2Centre of Lipids Engineering and Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bahru, Johor, Malaysia
Korean Journal of Chemical Engineering, January 2020, 37(1), 141-150(10), 10.1007/s11814-019-0418-4
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Abstract
Facilitated transport of Orange 3R was performed by means of emulsion liquid membrane (ELM) technique containing double extractants of Aliquat 336 and D2EHPA as extractant and synergist extractant, respectively. Cooking palm oil, sorbitan monooleate (Span 80), and sodium hydroxide were used as diluent, surfactant and stripping agent, respectively. Several parameters influencing the extraction of Orange 3R via ELM, namely effect of extraction time, agitator speed, Span 80 concentration and treatment ratio, were experimentally investigated and optimized using response surface methodology (RSM). Results demonstrated that about 91% of Orange 3R was successfully extracted under optimum conditions of 12minutes of extraction time, 413 rpm of agitator speed, 3.2% (w/v) of sorbitan monooleate, and 1 : 9.8 of treatment ratio. Additionally, the aforementioned optimum conditions were found to be more suitable to treat low concentration of Orange 3R (less than 100 ppm) from simulated textile wastewater. The findings reveal that reactive Orange 3R dye is able to be selectively extracted using double extractants via sustainable ELM process as well as providing high potential application in the dye removal from industrial textile wastewater.
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Mokhtari B, Pourabdollah K, Chin. J. Chem. Eng., 23(4), 641 (2015)
