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Received February 20, 2020
Accepted June 12, 2020
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A thermo-kinetic study on co-pyrolysis of oil shale and polyethylene terephthalate using TGA/FT-IR
Faculty of Engineering, Department of Chemical Engineering, Bilecik Seyh Edebali University, 11210, Bilecik, Turkey 1Faculty of Engineering, Department of Chemical Engineering, Eskisehir Technical University, 26555, Eskişehir, Turkey 2Faculty of Engineering, Department of Chemical Engineering, Anadolu University, 26555, Eskisehir, Turkey 3Faculty of Engineering, Department of Materials Science and Engineering Engineering, Anadolu University, 26555, Eskisehir, Turkey
gozsin@anadolu.edu.tr, gamzenur.ozsin@bilecik.edu.tr
Korean Journal of Chemical Engineering, November 2020, 37(11), 1888-1898(11), 10.1007/s11814-020-0614-2
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Abstract
This study explored the effects of polyethylene terephthalate (PET) blending during the pyrolysis of oil shale (OS). Dynamic pyrolysis and co-pyrolysis tests at heating rates in the range from 5 to 40 °C/min were carried out using a thermogravimetric analyzer (TGA) coupled to a Fourier transform infrared spectrometer (FT-IR) to determine the kinetic parameters of the process and for online detection of evolved gasses. Pyrolytic decomposition of OS included a multi-stage decomposition process, while PET decomposed only in a single step. The kinetics of pyrolysis and co-pyrolysis was determined via model-free iso-conversional methods, namely Friedman, FWO, Starink, Vyazovkin, in a conversion degree range of 0.1-0.9. The kinetic models were validated with the obtained data to describe pyrolytic and copyrolytic degradation mechanisms, and the regression coefficients were between 0.9823 and 0.9999. The results showed that the activation energy of co-pyrolysis was evidently lower than that of PET or OS pyrolysis. This led to the conclusion that co-pyrolysis could be a potential method for obtaining shale oil due to the synergy between OS and PET.
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Cepeliogullar O, Putun AE, J. Anal. Appl. Pyrolysis, 110, 363 (2014)
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Boytsova A, Kondrasheva N, Ancheyta J, Energy Fuels, 32(2), 1132 (2018)
Yao C, Tian H, Hu Z, Yin Y, Chen D, Yan X, Korean J. Chem. Eng., 35(2), 511 (2018)
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Flynn JH, Wall LA, J. Res. Nat. Bur. Stand, 70, 487 (1966)
Ozawa T, Bull. Chem. Soc. Jpn., 38, 1881 (1965)
Starink MJ, Thermochim. Acta, 288(1-2), 97 (1996)
Vyazovkin S, J. Therm. Anal., 49, 1493 (1997)
Niu SL, Zhou Y, Yu HW, Lu CM, Han KH, Energy Conv. Manag., 149, 495 (2017)
Wang XB, Deng SH, Tan HZ, Adeosun A, Vujanovic M, Yang FX, Duic N, Energy Conv. Manag., 118, 399 (2016)
Lai DG, Zhang GY, Xu GW, Fuel Process. Technol., 158, 191 (2017)
Holland BJ, Hay JN, Polymer, 43(6), 1835 (2002)
Williams PT, Ahmad N, Appl. Energy, 66(2), 113 (2000)
Jaber JO, Probert SD, Williams PT, Energy, 24(9), 761 (1999)
Williams PT, Ahmad N, Fuel, 78, 653 (1999)
Chen ZH, Zhu QJ, Wang X, Xiao B, Liu SM, Energy Conv. Manag., 105, 251 (2015)
Tang L, Yang Y, Meng Y, Wang J, Jiang P, Pang CH, Wu T, Energy Procedia, 158, 1694 (2019)
Yuan XS, He T, Cao HL, Yuan QX, Renew. Energy, 107, 489 (2017)
Zhao S, Liu M, Zhao L, Lu J, Korean J. Chem. Eng., 34(12), 3077 (2017)
Dai MQ, Yu ZS, Fang SW, Ma XQ, Energy Conv. Manag., 192, 1 (2019)
