Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received January 28, 2020
Accepted June 8, 2020
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
PDMS/ceramic composite membrane synthesis and evaluation of ciprofloxacin removal efficiency
1CSIR-Central Glass and Ceramic Research Institute, Academy of Scientific and Innovative Research (AcSIR), India 2CSIR-Central Glass and Ceramic Research Institute, Ceramic Membrane Division, 196, Raja SC Mullick road, Kolkata 700032, India
sourja@cgcri.res.in, sourja.g@gmail.com
Korean Journal of Chemical Engineering, November 2020, 37(11), 1985-1998(14), 10.1007/s11814-020-0608-0
Download PDF
Abstract
The present study employs an unexplored, one-step route for remediation of ciprofloxacin, an emerging contaminant, using hydrophobically modified ceramic membranes. Hydrophobic interaction between the membrane and the target contaminant, i.e., ciprofloxacin, is the governing factor responsible for its removal. The hydrophilic surface of hollow, single channel, macroporous clay-alumina membranes was made hydrophobic using cross-linked polydimethylsiloxane. The influencing parameters--concentration of polymer, cross-linking agent, catalyst and coating time--were optimized by Taguchi analysis to yield a membrane with enhanced ciprofloxacin rejection and high permeate flux. The synthesized membrane was characterized for its contact angle, clean water permeability, degree of swelling, degree of cross-linking, X-Ray diffraction, atomic fluorescence microscopy, field emission scanning electron microscopy. Effect of various operating parameters--cross flow velocity, transmembrane pressure, filtration time, solution pH--was investigated upon removal of ciprofloxacin in cross flow membrane filtration. Maximum rejection of 99.3% was obtained by the hydrophobic membrane having contact angle of 138.5 ° for 5mg/L feed solution. The stability of the membrane was judged in terms of change in ciprofloxacin rejection upon filtration for five consecutive cycles, each cycle being 180min. The developed PDMS/ceramic composite membranes could have great prospect for longterm application in removal of emerging contaminants from water.
References
Kummerer K, Chemosphere, 75, 417 (2009)
Baquero F, Martinez JL, Canton R, Curr. Opin. Biotechnol., 19, 260 (2008)
Ollivier J, Kleineidam K, Reichel R, Thiele-Bruhn S, Kotzerke A, Kindler R, Wilke BM, Schloter M, Appl. Environ. Microbiol., 76, 7903 (2010)
Ma J, Yang M, Yu F, Zheng J, Sci. Rep., 5, 13578 (2015)
Beier S, Koster S, Veltmann K, Schroder HF, Pinnekamp J, Water Sci. Technol., 61, 1691 (2010)
Wei XY, Wang Z, Fan FH, Wang JX, Wang SC, Desalination, 251(1-3), 167 (2010)
Rakshit S, Sarkarm D, Elzingam E, Punamiyam P, Datta R, J. Hazard. Mater., 246247, 221 (2013)
Voogt P, Janex-Habibi ML, Sacher F, Puijker L, Mons M, IWA World Water Congress and Exhibition, Vienna, Austria (2008).
De Witte B, Langenhove H, Demeestere K, Saerens K, Wispelaere P, Dewulf J, Chemosphere, 78, 1142 (2010)
Hughes SR, Kay P, Brown LE, Environ. Sci. Technol., 47, 661 (2013)
Larsson DGJ, de Pedro C, Paxeus N, J. Hazard. Mater., 148(3), 751 (2007)
Sun SP, Hatton TA, Chung TS, Environ. Sci. Technol., 45, 4003 (2011)
Genc N, Can-Dogan E, Yurtsever M, Water Sci. Technol., 68, 848 (2013)
Jiang WT, Cheng PH, Wang YS, Tsai Y, Jean JS, Li Z, Krukowski K, J. Hazard. Mater., 250-251, 362 (2013)
Wu SL, Zhao XD, Li YH, Zhao CT, Du QJ, Sun JK, Wang YH, Peng XJ, Xia YZ, Wang ZH, Xia LH, Chem. Eng. J., 230, 389 (2013)
Jiang JQ, Zhou ZW, Pahl O, Sep. Purif. Technol., 88, 95 (2012)
Zhou Z, Jiang J, Chemosphere, 119, 95 (2015)
Urtiaga AM, Perez G, Ibanez R, Ortiz I, Desalination, 331, 26 (2013)
Zhuang Y, Yu F, Ma J, J. Nanomater., 675862 (2015).
Golet EM, Xifra I, Siegrist H, Alder AC, Giger W, Environ. Eng. Sci., 37, 3243 (2003)
Shah AD, Huang CH, Kim JH, J. Membr. Sci., 389, 234 (2012)
Dogan EC, Global Nest J., 18, 291 (2016)
Sarkar S, Trans. Indian Ceram. Soc., 73, 239 (2014)
Xiangli FJ, Wei W, Chen YW, Jin WQ, Xu NP, J. Membr. Sci., 311(1-2), 23 (2008)
Stafie N, Stamatialis DF, Wessling A, J. Membr. Sci., 228(1), 103 (2004)
Yang LJ, J. Mater. Process Technol., 113, 521 (2001)
Benyounis K, Olabi A, Adv. Eng. Softw., 39, 483 (2008)
Kumar A, Bhunia B, Dasgupta D, Mandal T, Dey A, Datta S, Bhattacharya P, Desalin. Water Treat., 51, 3153 (2013)
Reyhani A, Rekabdar F, Hemmati M, Safe-Kordi AA, Ahmadi M, Desalin. Water Treat., 51, 7499 (2013)
Shahavi MH, Hosseini M, Jahanshahi M, Meyer RK, Darzi GN, Desalin. Water Treat., 57, 18379 (2015)
Gu J, Bai Y, Zhang L, Deng L, Zhang C, Sun Y, Chen C, Int. J. Polym. Sci., 529474 (2013).
Genc N, Can-Dogan E, Yurtsever M, Water Sci. Technol., 68, 848 (2013)
Natraj Y, Prasanti SG, Saikumar SV, Int. Res. J. Pharm., 4, 178 (2013)
Mukherjee M, Panda SR, De S, J. Chem. Technol. Biotechnol., 92, 408 (2016)
Dafinov A, Font J, Garcia-Valls R, Desalination, 173(1), 83 (2005)
Wei W, Xia S, Liu G, Gu X, Jin W, Xu N, AIChE J., 56, 6 (2009)
Wanqin J, et al., Organic-inorganic composite membranes for molecular separation, World Scientific Publishing Europe Ltd., London (2017).
Atisha A, Electronic Thesis and Dissertation Repository, 4370 (2017).
Esteves ACC, Brokken-Zijp J, Laven J, Huinink HP, Reuvers NJW, Van MP, de With G, Polymer, 50(16), 3955 (2009)
Stein J, Lewis L, Smith K, Lettko K, J. Inorg. Organomet., 1, 325 (1991)
Gongping L, Wang W, Wanqin J, Nanping XU, Chin. J. Chem. Eng., 20, 62 (2012)
Wei W, Xia SS, Liu GP, Dong XL, Jin WQ, Xu NP, J. Membr. Sci., 375(1-2), 334 (2011)
Al-Rashdi BAM, Johnson DJ, Hilal N, Desalination, 315, 2 (2013)
Gherasim CV, Mikulasek P, Desalination, 343, 67 (2014)
Gzara L, Dhahbi M, Desalination, 137(1-3), 241 (2001)
Alventosa-deLara E, Barredo-Damas S, Alcaina-Miranda MI, Iborra-Clar MI, J. Hazard. Mater., 209, 492 (2012)
Saffaj N, Loukili H, Younssi SA, Albizane A, Bouhria M, Persin M, Larbot A, Desalination, 168, 301 (2004)
Palacio DA, Rivas BL, Urbano BF, Chem. Eng. J., 351, 85 (2018)
Jalil R, Baschini M, Sapag K, Eugenia M, Materials, 10, 1345 (2017)
Futrega K, Yu J, Jones JW, Kane MA, Lott WB, Atkinson K, Doran MR, Lab Chip, 16, 1473 (2016)
Zhu D, Hyun S, Pignatello JJ, Lee LS, Environ. Sci. Technol., 38, 4361 (2004)
Chang R, Physical chemistry for the biosciences, University Science, Sausalito (2005).
Atkins P, de Paula J, Physical chemistry for the life sciences, Oxford University Press, UK (2006).
Schwarzenbach RP, Gschwend PM, Imboden DM, Environmental Organic Chemistry, Wiley-Interscience, New York (2003).
Ojajuni O, Holder S, Cavalli G, Lee J, Saroj DP, Ind. Eng. Chem. Res., 55(8), 2417 (2016)
Kochan J, Wintgens T, Wong JE, Melin T, Desalination, 250(3), 1008 (2010)
Johnson LM, Gao L, Shields CW, Smith M, Efimenko K, Cushing K, Genzer J, Lopez GP, J. Nanobiotechnol., 11, 22 (2013)
Baquero F, Martinez JL, Canton R, Curr. Opin. Biotechnol., 19, 260 (2008)
Ollivier J, Kleineidam K, Reichel R, Thiele-Bruhn S, Kotzerke A, Kindler R, Wilke BM, Schloter M, Appl. Environ. Microbiol., 76, 7903 (2010)
Ma J, Yang M, Yu F, Zheng J, Sci. Rep., 5, 13578 (2015)
Beier S, Koster S, Veltmann K, Schroder HF, Pinnekamp J, Water Sci. Technol., 61, 1691 (2010)
Wei XY, Wang Z, Fan FH, Wang JX, Wang SC, Desalination, 251(1-3), 167 (2010)
Rakshit S, Sarkarm D, Elzingam E, Punamiyam P, Datta R, J. Hazard. Mater., 246247, 221 (2013)
Voogt P, Janex-Habibi ML, Sacher F, Puijker L, Mons M, IWA World Water Congress and Exhibition, Vienna, Austria (2008).
De Witte B, Langenhove H, Demeestere K, Saerens K, Wispelaere P, Dewulf J, Chemosphere, 78, 1142 (2010)
Hughes SR, Kay P, Brown LE, Environ. Sci. Technol., 47, 661 (2013)
Larsson DGJ, de Pedro C, Paxeus N, J. Hazard. Mater., 148(3), 751 (2007)
Sun SP, Hatton TA, Chung TS, Environ. Sci. Technol., 45, 4003 (2011)
Genc N, Can-Dogan E, Yurtsever M, Water Sci. Technol., 68, 848 (2013)
Jiang WT, Cheng PH, Wang YS, Tsai Y, Jean JS, Li Z, Krukowski K, J. Hazard. Mater., 250-251, 362 (2013)
Wu SL, Zhao XD, Li YH, Zhao CT, Du QJ, Sun JK, Wang YH, Peng XJ, Xia YZ, Wang ZH, Xia LH, Chem. Eng. J., 230, 389 (2013)
Jiang JQ, Zhou ZW, Pahl O, Sep. Purif. Technol., 88, 95 (2012)
Zhou Z, Jiang J, Chemosphere, 119, 95 (2015)
Urtiaga AM, Perez G, Ibanez R, Ortiz I, Desalination, 331, 26 (2013)
Zhuang Y, Yu F, Ma J, J. Nanomater., 675862 (2015).
Golet EM, Xifra I, Siegrist H, Alder AC, Giger W, Environ. Eng. Sci., 37, 3243 (2003)
Shah AD, Huang CH, Kim JH, J. Membr. Sci., 389, 234 (2012)
Dogan EC, Global Nest J., 18, 291 (2016)
Sarkar S, Trans. Indian Ceram. Soc., 73, 239 (2014)
Xiangli FJ, Wei W, Chen YW, Jin WQ, Xu NP, J. Membr. Sci., 311(1-2), 23 (2008)
Stafie N, Stamatialis DF, Wessling A, J. Membr. Sci., 228(1), 103 (2004)
Yang LJ, J. Mater. Process Technol., 113, 521 (2001)
Benyounis K, Olabi A, Adv. Eng. Softw., 39, 483 (2008)
Kumar A, Bhunia B, Dasgupta D, Mandal T, Dey A, Datta S, Bhattacharya P, Desalin. Water Treat., 51, 3153 (2013)
Reyhani A, Rekabdar F, Hemmati M, Safe-Kordi AA, Ahmadi M, Desalin. Water Treat., 51, 7499 (2013)
Shahavi MH, Hosseini M, Jahanshahi M, Meyer RK, Darzi GN, Desalin. Water Treat., 57, 18379 (2015)
Gu J, Bai Y, Zhang L, Deng L, Zhang C, Sun Y, Chen C, Int. J. Polym. Sci., 529474 (2013).
Genc N, Can-Dogan E, Yurtsever M, Water Sci. Technol., 68, 848 (2013)
Natraj Y, Prasanti SG, Saikumar SV, Int. Res. J. Pharm., 4, 178 (2013)
Mukherjee M, Panda SR, De S, J. Chem. Technol. Biotechnol., 92, 408 (2016)
Dafinov A, Font J, Garcia-Valls R, Desalination, 173(1), 83 (2005)
Wei W, Xia S, Liu G, Gu X, Jin W, Xu N, AIChE J., 56, 6 (2009)
Wanqin J, et al., Organic-inorganic composite membranes for molecular separation, World Scientific Publishing Europe Ltd., London (2017).
Atisha A, Electronic Thesis and Dissertation Repository, 4370 (2017).
Esteves ACC, Brokken-Zijp J, Laven J, Huinink HP, Reuvers NJW, Van MP, de With G, Polymer, 50(16), 3955 (2009)
Stein J, Lewis L, Smith K, Lettko K, J. Inorg. Organomet., 1, 325 (1991)
Gongping L, Wang W, Wanqin J, Nanping XU, Chin. J. Chem. Eng., 20, 62 (2012)
Wei W, Xia SS, Liu GP, Dong XL, Jin WQ, Xu NP, J. Membr. Sci., 375(1-2), 334 (2011)
Al-Rashdi BAM, Johnson DJ, Hilal N, Desalination, 315, 2 (2013)
Gherasim CV, Mikulasek P, Desalination, 343, 67 (2014)
Gzara L, Dhahbi M, Desalination, 137(1-3), 241 (2001)
Alventosa-deLara E, Barredo-Damas S, Alcaina-Miranda MI, Iborra-Clar MI, J. Hazard. Mater., 209, 492 (2012)
Saffaj N, Loukili H, Younssi SA, Albizane A, Bouhria M, Persin M, Larbot A, Desalination, 168, 301 (2004)
Palacio DA, Rivas BL, Urbano BF, Chem. Eng. J., 351, 85 (2018)
Jalil R, Baschini M, Sapag K, Eugenia M, Materials, 10, 1345 (2017)
Futrega K, Yu J, Jones JW, Kane MA, Lott WB, Atkinson K, Doran MR, Lab Chip, 16, 1473 (2016)
Zhu D, Hyun S, Pignatello JJ, Lee LS, Environ. Sci. Technol., 38, 4361 (2004)
Chang R, Physical chemistry for the biosciences, University Science, Sausalito (2005).
Atkins P, de Paula J, Physical chemistry for the life sciences, Oxford University Press, UK (2006).
Schwarzenbach RP, Gschwend PM, Imboden DM, Environmental Organic Chemistry, Wiley-Interscience, New York (2003).
Ojajuni O, Holder S, Cavalli G, Lee J, Saroj DP, Ind. Eng. Chem. Res., 55(8), 2417 (2016)
Kochan J, Wintgens T, Wong JE, Melin T, Desalination, 250(3), 1008 (2010)
Johnson LM, Gao L, Shields CW, Smith M, Efimenko K, Cushing K, Genzer J, Lopez GP, J. Nanobiotechnol., 11, 22 (2013)
