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Received April 4, 2020
Accepted May 31, 2020
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Experimental and modeling study of CO2 separation by modified Pebax 1657 TFC membranes
Esfarayen University of Technology, Esfarayen, North Khorasan, Iran 1Department of Design and Engineering, School of Creative Arts and Engineering, Staffordshire University, Stoke-on-Trent, ST4 2DE, United Kingdom, UK 2Gas Engineering Department, Ahvaz Faculty of Petroleum Engineering, Petroleum University of Technology (PUT), Ahvaz, Iran
behbahani@put.ac.ir
Korean Journal of Chemical Engineering, November 2020, 37(11), 2020-2040(21), 10.1007/s11814-020-0598-y
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Abstract
Ionic liquid modified Pebax 1657 thin-film composite (TFC) membranes were synthesized on different porous supports for improved separation of CO2 from CH4 and N2. XRD, SEM, FTIR, TGA, DFT, and BJH tests were utilized for the characterization of TFC membranes and supports. The incorporation of 1,3-Di-n-butyl-2-methylimidazolium chloride ionic liquid into the Pebax 1657 solution led to better compatibility between selective layer and support. The results of gas permeation tests showed an enhanced CO2/CH4 and CO2/N2 selectivity for most of the ionic liquid modified TFC membranes. To derive a predictive model for the permeability of gases in TFC membranes, correction factors (β) for fractional free volumes of TFC membranes were linearly correlated against correction factors (α) for porosity and tortuosity of the substrate in the dusty gas model using CO2 experimental permeance data at 20, 60, 100 and 140 °C. The resulting modified model showed remarkable effectiveness in the prediction of permeability of CH4 and N2 in the TFC membrane at investigated temperatures. The comparison of model predictive performance with previous models showed the supremacy of the new model in terms of average absolute relative errors (AARE) and the standard deviation of relative errors (σ).
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Meshkat S, Kaliaguine S, Rodrigue D, Sep. Purif. Technol., 200, 177 (2018)
Mozafari M, Abedini R, Rahimpour A, J. Mater. Chem. A, 6, 12380 (2018)
Dong GY, Hou JW, Wang J, Zhang YT, Chen V, Liu JD, J. Membr. Sci., 520, 860 (2016)
Zhao D, Ren JZ, Wang Y, Qiu YT, Li H, Hua KS, Li XX, Ji JM, Deng MC, J. Membr. Sci., 521, 104 (2017)
Bernardo P, Jansen JC, Bazzarelli F, Tasselli F, Fuoco A, Friess K, Izak P, Jarmarova V, Kacirkova M, Clarizia G, Sep. Purif. Technol., 97, 73 (2012)
Rabiee H, Ghadimi A, Mohammadi T, J. Membr. Sci., 476, 286 (2015)
Ghadimi A, Norouzbahari S, Lin HQ, Rabiee H, Sadatnia B, J. Membr. Sci., 563, 643 (2018)
Lito PF, Zhou CF, Santiago AS, Rodrigues AE, Rocha J, Lin Z, Silva CM, Chem. Eng. J., 165(2), 395 (2010)
Ramon GZ, Wong MCY, Hoek EMV, J. Membr. Sci., 415, 298 (2012)
Wijmans JG, Hao PJ, J. Membr. Sci., 494, 78 (2015)
Orogbemi OM, Ingham DB, Ismail MS, Hughes KJ, Ma L, Pourkashanian M, Int. J. Hydrog. Energy, 41(46), 21345 (2016)
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Zhu L, Yavari M, Jia W, Furlani EP, Lin H, Ind. Eng. Chem. Res., 56, 351 (2016)
Jia L, Xu J, Polym. J., 23, 417 (1991)
Jomekian A, Behbahani R, Mohammadi T, Kargari A, J. Solid State Chem., 235, 212 (2016)
Caldwell JR, Jackson WJ, J. Polym. Sci., Part C: Polym. Lett., 24, 15 (1968)
Mubashir M, Fong YY, Keong LK, Leng CT, Jusoh N, Sep. Purif. Technol., 199, 140 (2018)
Xiao J, Wei J, Chem. Eng. Sci., 47, 1123 (1992)
Fick A, The London, Edinburgh, & Dublin Philos. Mag. J. Sci., 10, 30 (1855).
Yasuda H, Tsai J, J. Appl. Polym. Sci., 18, 805 (1974)
Mason EA, Malinauskas A, Gas transport in porous media: the dusty-gas model, Elsevier Science Ltd., New York (1983).
Cabasso I, Robert K, Klein E, Smith J, J. Appl. Polym. Sci., 21, 1883 (1977)
Hua D, Ong YK, Wang Y, Yang TX, Chung TS, J. Membr. Sci., 453, 155 (2014)
Shen Y, Lua AC, Chem. Eng. J., 188, 199 (2012)
Bondi A, J. Phys. Chem., 68, 441 (1964)
Thran A, Kroll G, Faupel F, J. Polym. Sci. B: Polym. Phys., 37(23), 3344 (1999)
Cho HY, Kim J, Kim SN, Ahn WS, Microporous Mesoporous Mater., 169, 180 (2013)
Murali RS, Sridhar S, Sankarshana T, Ravikumar YVL, Ind. Eng. Chem. Res., 49(14), 6530 (2010)
Smith BC, Fundamentals of Fourier transform infrared spectroscopy, CRC Press, Boca Raton (2011).
Chung TS, Sep. Purif. Technol., 12(1), 17 (1997)
Vankelecom I, Moermans B, Verschueren G, Jacobs P, J. Membr. Sci., 158, 289 (1999)
Couck S, Denayer JF, Baron GV, Remy T, Gascon J, Kapteijn F, J. Am. Chem. Soc., 131(26), 9326 (2009)
Erucar I, Keskin S, Ind. Eng. Chem. Res., 52(9), 3462 (2013)
Cadena C, Anthony JL, Shah JK, Morrow TI, Brennecke JF, Maginn EJ, J. Am. Chem. Soc., 126(16), 5300 (2004)
Aquino A, Bernard F, Borges J, Mafra L, Vecchia FD, Vieira M, Ligabue R, Seferin M, Chaban VV, Cabrita E, RSC Adv., 5, 64220 (2015)
Car A, Stropnik C, Yave W, Peinemann KV, Sep. Purif. Technol., 62(1), 110 (2008)
Scofield Joel M. P., Gurr Paul A., Kim Jinguk, Fu Qiang, Kentish Sandra E., Qiao Greg G., Ind. Eng. Chem. Res., 55(30), 8364 (2016)
Sharma P, Kim YJ, Kim MZ, Alam SF, Cho CH, Nanoscale Adv., 1, 2633 (2019)
Chern RT, Koros WJ, Yui B, Hopfenberg HB, Stannett VT, J. Polym. Sci. B: Polym. Phys., 22, 1061 (1984)
Chern RT, Koros WJ, Sanders ES, Yui R, J. Membr. Sci., 15, 157 (1983)
Kim JH, Ha SY, Lee YM, J. Membr. Sci., 190(2), 179 (2001)
Hernandez S, Sket F, Molina-Aldareguia JM, Gonzalez C, Llorca J, Compos. Sci. Technol., 71, 1331 (2011)
Hajpal M, Fire Technol., 38, 373 (2002)
Kaneko K, J. Membr. Sci., 96(1-2), 59 (1994)
Zdravkov BD, Cermak JJ, Sefara M, Janku J, Cent. Eur. J. Chem., 5, 385 (2007)
Barankova E, Pradeep N, Peinemann KV, Chem. Commun., 49, 9419 (2013)
Hashemifard SA, Ismail AF, Matsuura T, J. Membr. Sci., 347(1-2), 53 (2010)
Cheng J, Hu L, Li Y, Ji C, Zhou J, Cen K, RSC Adv., 6, 2055 (2016)
Cheng J, Hu LQ, Li YN, Liu JZ, Zhou JH, Cen KF, Appl. Surf. Sci., 410, 206 (2017)
Bhattacharya M, Mandal MK, J. Clean Prod., 156, 174 (2017)
Mahdavi HR, Azizi N, Arzani M, Mohammadi T, J. Nat. Gas Sci. Eng., 46, 275 (2017)
Rahman MM, Filiz V, Shishatskiy S, Abetz C, Neumann S, Bolmer S, Khan MM, Abetz V, J. Membr. Sci., 437, 286 (2013)
Lim JY, Kim JK, Lee CS, Lee JM, Kim JH, Chem. Eng. J., 322, 254 (2017)
Li M, Zhang X, Zeng S, Gao H, Deng J, Yang Q, Zhang S, RSC Adv., 7, 6422 (2017)
