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Received March 20, 2020
Accepted July 14, 2020
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Simultaneous biosynthesis of reduced graphene oxide-Ag-Cu2O nanostructures by lichen extract for catalytic reduction of textile dyes
Department of Chemical Engineering, Ankara University, 06100, Tandoğan, Ankara, Turkey 1Department of Biology, Ankara University, 06100, Tandoğan, Ankara, Turkey
catila@eng.ankara.edu.tr
Korean Journal of Chemical Engineering, December 2020, 37(12), 2216-2224(9), 10.1007/s11814-020-0640-0
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Abstract
Metal/metal oxide nanostructures based reduced graphene oxide (LrGO-Ag, LrGO-Cu2O, LrGO-Ag-Cu2O) nanocomposites were obtained via green method using Cetraria islandica (L.) Ach. lichen extract. Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), scanning electron microscope energy-dispersive X-ray spectroscopy (SEM-EDX), ultraviolet-visible (UV-Vis) spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were performed to analyze the prepared nanostructures. The results indicated that thenanocomposites were synthesized effectively and Ag-Cu2O nanoparticles with the mean diameter of 27nm were well dispersed on the LrGO. The conversion of methylene blue (MB) to Leuco Methylene Blue (LMB) and 4-Nitrophenol (4- NP) to 4-Aminophenol (4-AP) was performed by biosynthesized catalysts in the presence of NaBH4. The reaction rate of LrGO-Ag-Cu2O nanocomposite during 4-NP and MB reduction was found as 0.0026 s-1 and 0.0497 s-1, respectively. The LrGO-Ag-Cu2O nanocomposite showed superior catalytic performance for the reduction of both textile dyes.
Keywords
References
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Adyani SH, Soleimani E, Int. J. Hydrog. Energy, 44(5), 2711 (2019)
Srinivasan S, Sadasivam SK, J. Water Process Eng., 22, 180 (2018)
Silva LGM, Moreira FC, Souza AAU, Souza SMAGU, Boaventura RAR, Vilar VJP, J. Clean Prod., 198, 430 (2018)
GilPavas E, Dobrosz-Gomez I, Gomez-Garcia MA, J. Water Process Eng., 22, 73 (2018)
Xu Y, Li ZH, Su KM, Fan TT, Cao L, Chem. Eng. J., 341, 371 (2018)
Herrera-Gonzalez AM, Caldera-Villalobos M, Pelaez-Cid AA, J. Environ. Manage., 234, 237 (2019)
Maham M, Nasrollahzadeh M, Sajadi SM, Nekoei M, J. Colloid Interface Sci., 497, 33 (2017)
Mangalam J, Kumar M, Sharma M, Joshi M, Nano-Struct. Nano-Objects, 17, 58 (2019).
Yilmaz E, Tut Y, Turkoglu O, Soylak M, J. Iran. Chem. Soc., 15, 1721 (2018)
Wang DS, Li YD, Adv. Mater., 23(9), 1044 (2011)
Jin Z, Xiao M, Bao Z, Wang P, Wang J, Angew. Chem.-Int. Edit., 124, 6512 (2012)
Pang M, Wang Q, Zeng HC, Chem.-Eur. J., 18, 14605 (2012)
Roy I, Bhattacharyya A, Sarkar G, Saha NR, Rana D, Ghosh PP, Palit M, Das AR, Chattopadhyay D, RSC Adv., 4, 52044 (2014)
Ping T, Mihua S, Chengwen S, Shuaihua W, Murong C, Rare Metal Mat. Eng., 45, 2214 (2016)
Wu C, An X, Gao S, Su L, RSC Adv., 5, 71259 (2015)
Meir N, La Plante IJ, Flomin K, Chockler E, Moshofsky B, Diab M, Volokh M, Mokari T, J. Mater. Chem. A, 1, 1763 (2013)
Guo XH, Ma JQ, Ge HG, Russ. J. Phys. Chem. A, 89, 1374 (2015)
Chen L, Liu MM, Zhao Y, Kou QW, Wang YX, Liu Y, Zhang YJ, Yang JH, Jung YM, Appl. Surf. Sci., 435, 72 (2018)
Dou L, Wang Y, Li Y, Zhang H, Dalton Trans., 46, 15836 (2017)
Chakravarty A, Bhowmik K, Mukherjee A, De G, Langmuir, 31(18), 5210 (2015)
Rath PC, Saikia D, Mishra M, Kao HM, Appl. Surf. Sci., 427, 1217 (2018)
Roopan SM, Surendra TV, Elango G, Kumar SHS, Appl. Microbiol. Biotechnol., 98(12), 5289 (2014)
Dauthal Preeti, Mukhopadhyay Mausumi, Ind. Eng. Chem. Res., 55(36), 9557 (2016)
Vijayaraghavan K, Ashokkumar T, J. Environ. Chem. Eng., 5, 4866 (2017)
Zikalala N, Matshetshe K, Parani S, Oluwafemi OS, Nano-Struct. Nano-Objects, 16, 288 (2018).
Sharma G, Kumar A, Sharma S, Naushad M, Dwivedi RP, ALOthman ZA, Mola GT, J. King Saud. Univ. Sci., 31, 257 (2019)
Olafsdottir ES, Ingolfsdottir K, Planta Med., 67, 199 (2001)
Yildiz N, Ates C, Yilmaz M, Demir D, Yildiz A, Calimli A, Green Process. Synth., 3, 259 (2014)
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Zhou R, Yang Y, Park SY, Nguyen TT, Seo YW, Lee KH, Lee JH, Kim KK, Hur JS, Kim H, Sci. Rep., 7, 8136 (2017)
Geim AK, Novoselov KS, Nat. Mater., 6(3), 183 (2007)
Nurunnabi M, Parvez K, Nafiujjaman M, Revuri V, Khan HA, Feng X, Lee YK, RSC Adv., 5, 42141 (2015)
Divya KS, Chandran A, Reethu VN, Mathew S, Appl. Surf. Sci., 444, 811 (2018)
Mata R, Bhaskaran A, Sadras SR, Particuology, 24, 78 (2016)
Mowry S, Ogren PJ, J. Chem. Educ., 76, 970 (1999)
Krishna R, Fernandes DM, Dias C, Freire C, Ventura J, Titus E, Mater. Today Proc., 3, 2814 (2016)
Prasad R, Lolakshi MK, Bhat BR, Synth. Met., 219, 26 (2016)
Nasrollahzadeh M, Atarod M, Jaleh B, Gandomirouzbahani M, Ceram. Int., 42, 8587 (2016)
Atarod M, Nasrollahzadeh M, Sajadi SM, J. Colloid Interface Sci., 465, 249 (2016)
Rout L, Kumar A, Dhaka RS, Reddy GN, Giri S, Dash P, Appl. Catal. A: Gen., 5238, 107 (2017)
Nirumand L, Farhadi S, Zabardasti A, Acta Chim. Slov., 65, 919 (2018)
Cıplak Z, Getiren B, Gokalp C, Yıldız A, Yıldız N, Chem. Eng. Commun., 207, 559 (2020)
Yuan X, Xiao S, Taylor TN, Science, 308, 1017 (2005)
Haghighi B, Tabrizi MA, RSC Adv., 3, 13365 (2013)
Wu L, Qu P, Zhou R, Wang B, Liao S, High Perform. Polym., 24, 486 (2015)
Guo Y, Wang H, Ma X, Jin J, Ji W, Wang X, Song W, Zhao B, He C, ACS Appl. Mater. Interfaces, 9, 19074 (2017)
Cıplak Z, Gokalp C, Getiren B, Yıldız A, Yıldız N, Green Process Synth., 7, 433 (2018)
Zhao Z, Cai Z, Yang L, Hu Z, Zhang Y, Peng X, Wang Q, Yuan X, Li G, J. Mater. Sci. Mater. Electron., 29, 17743 (2018)
Gopalakrishnan K, Ramesh C, Elango M, Thamilselvan M, ISRN Mater. Sci., 2014, 1 (2014)
Khan M, Al-Marri AH, Khan M, Shaik MR, Mohri N, et al., Nanoscale Res. Lett., 10, 281 (2015)
Das TK, Bhawal P, Ganguly S, Mondal S, Das NC, Surf. Interface, 13, 79 (2018)
Yeh CC, Wu PR, Chen DH, Mater. Lett., 136, 274 (2014)
Dubey SP, Nguyen TTM, Kwon YN, Lee C, J. Ind. Eng. Chem., 29, 282 (2015)
Sharma K, Maiti K, Kim NH, Hui D, Lee JH, Compos. Part B Eng., 138, 35 (2018)
Pang JJ, Li WT, Cao ZH, Xu JJ, Li X, Zhang XK, Appl. Surf. Sci., 439, 420 (2018)
Bozkurt PA, Ultrason. Sonochem., 35, 397 (2017)
Zhang Y, Wang JS, Qiu JJ, Jin X, Umair MM, Lu RW, Zhang SF, Tang BT, Appl. Energy, 237, 83 (2019)
Zhang W, Li X, Yang Z, Tang X, Ma Y, Li M, Hu N, Wei H, Zhang Y, Nanotechnology, 27, 265703 (2016)
Zhang W, Yin Z, Chun A, Yoo J, Diao G, Kim YS, Piao Y, J. Power Sources, 318, 66 (2016)
Shim KS, Kim JH, Kim IH, Kim K, J. Nanopart. Res., 14, 735 (2012)
Isa N, Lockman Z, Environ. Sci. Pollution R, 26, 11482 (2019)
Hamedi S, Shojaosadati SA, Mohammadi A, J. Photochem. Photobiol., 167, 36 (2017)
Yilmaz E, Soylak M, J. Iran. Chem. Soc., 14, 2503 (2017)
Hsu KC, Chen DH, Nanoscale Res. Lett., 9, 484 (2014)
Ahmad A, Wei Y, Syed F, Imran M, Khan ZUH, Tahir K, Khan AU, Raza M, Khan Q, Yuan Q, RSC Adv., 5, 99364 (2015)
Atarod M, Nasrollahzadeh M, Sajadi SM, RSC Adv., 5, 91532 (2015)
Huang C, Ye W, Liu Q, Qiu X, ACS Appl. Mater. Interfaces, 6, 14469 (2014)
Sasmal AK, Dutta S, Pal T, Dalton Trans., 45, 3139 (2016)
Kandula S, Jeevanandam P, Eur. J. Inorg. Chem., 2016, 1548 (2016)
Jiang ZJ, Liu CY, Sun LW, J. Phys. Chem. B, 109(5), 1730 (2005)
Lv JJ, Wang AJ, MA X, Xiang RY, Chen JR, Feng JJ, J. Mater. Chem. A, 3, 290 (2015)
Ye WC, Yu J, Zhou YX, Gao DQ, Wang DA, Wang CM, Xue DS, Appl. Catal. B: Environ., 181, 371 (2016)
Li X, Ma Y, Yang Z, Huang D, Xu S, Wang T, Su Y, Hu N, Zhang Y, J. Alloy. Compd., 706, 377 (2017)
Edison TJI, Sethuraman MG, Process Biochem., 47(9), 1351 (2012)
Adyani SH, Soleimani E, Int. J. Hydrog. Energy, 44(5), 2711 (2019)
