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Received February 15, 2020
Accepted August 9, 2020
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Using solid carriers impregnated with ammonium ionic liquids for platinum(IV) recovery from chloride solutions
1Oil Refining and Petrochemistry Department, Hanoi University of Mining and Geology, 18-Vien, Duc Thang, Bac Tu Liem, Ha Noi, Viet Nam, Vietnam 2Chemistry Department, University of Medicine and Pharmacy, 227 Hong Bang, Ho Chi Minh City, Viet Nam, Vietnam 3Institute of Chemistry, Vietnam Academy of Sciences and Technology, 18-Hoang Quoc Viet, Nghia Đo, Cau Giay, Ha Noi, Viet Nam, Vietnam 4Institute of Chemical Technology, Vietnam Academy of Sciences and Technology, 1-Mac Dinh Chi street, Hochiminh City, Viet Nam, Vietnam 5Institut de Chimie Moléculaire et des Matériaux d’Orsay, ICMMO, Université Paris-Saclay, 91405 Orsay Cedex, France
Korean Journal of Chemical Engineering, December 2020, 37(12), 2262-2272(11), 10.1007/s11814-020-0659-2
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Abstract
Platinum(IV) was extracted from chloride solution using kerosene solution of trioctyl ammonium chloride, methyltrioctylammonium chloride, and tetraoctyl ammonium chloride ionic liquids as solvents in high yields. To increase the Pt(IV) recovery and heterogenize the process for easy handling at industrial scale, these three ionic liquids were directly impregnated on some solid carriers, such as silica gel-60, silica gel-100, Amberlite XAD-7 ion-exchange resin, and Amberlite XAD-7 ion-exchange resin to form sorbents in nature of supported ionic liquid phase. The influence of some factors, such as ionic liquid and solid carrier structure, IL/Pt molar ratio, and ionic liquid loading as well as sorption isotherms, was investigated. The stripping and desorption of Pt(IV) using different eluents and reusability of ionic liquids and supported ionic liquid phases were also evaluated.
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