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Received June 18, 2020
Accepted August 4, 2020
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Thermally stable amine-functionalized silica sorbents using one-pot synthesis method for CO2 capture at low temperature
Seong Bin Jo
Ho Jin Chae
Tae Young Kim1
Jeom-In Baek2
Dhanusuraman Ragupathy3
Soo Chool Lee†
Jae Chang Kim1†
Research Institute of Advanced Energy Technology, Kyungpook National University, Daegu 41566, Korea 1Department of Chemical Engineering, Kyungpook National University, Daegu 41566, Korea 2Korea Electric Power Research Institute, Daejeon 34056, Korea 3Department of Chemistry, National Institute of Technology Puducherry, Karaikal 609609, India
soochool@knu.ac.kr
Korean Journal of Chemical Engineering, December 2020, 37(12), 2317-2325(9), 10.1007/s11814-020-0655-6
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Abstract
Amine-functionalized silica sorbents have been widely investigated for post-combustion CO2 capture at low temperature. In previous studies, amine-functionalized silica sorbents were prepared using a synthetic hierarchically porous silica, which is not commercially available in large quantities, because porous silica support structures strongly influence CO2 capture performance. Here, we propose a feasible and facile fabrication method for amine-functionalized silica sorbents using 3-aminopropyltrimethoxy silane (APTS) and fumed silica (FS), where APTS serves as both an active material and a binder. The APTS-functionalized FS sorbents have large amounts of active amino groups and porous structures and demonstrate good multicycle stability with excellent CO2 capture performance. In addition, cetyltrimethylammonium bromide was found to improve the diffusion pathway of CO2, leading to enhanced CO2 capture capacity because of the suppression of excessive condensation during preparation. Therefore, the APTS-functionalized FS sorbents could be cost- and energy-efficiently prepared using a novel one-pot synthesis method; the resulting sorbents exhibit excellent CO2 capture performance.
Keywords
References
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Sayari A, Belmabkhout Y, Serna-Guerrero R, Chem. Eng. J., 171(3), 760 (2011)
Sethia G, Sayari A, Carbon, 93, 68 (2015)
Shen CZ, Grande CA, Li P, Yu JG, Rodrigues AE, Chem. Eng. J., 160(2), 398 (2010)
Siriwardane RV, Shen MS, Fisher EP, Poston JA, Energy Fuels, 15(2), 279 (2001)
Takamura Y, Narita S, Aoki J, Hironaka S, Uchida S, Sep. Purif. Technol., 24(3), 519 (2001)
Thompson JA, Vaughn JT, Brunelli NA, Koros WJ, Jones CW, Nair S, Microporous Mesoporous Mater., 192, 43 (2014)
Yong Z, Mata V, Rodrigues AE, J. Chem. Eng. Data, 45, 1093 (2000)
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Yong Z, Mata V, Rodrigues AE, Sep. Purif. Technol., 26(2-3), 195 (2002)
Yong Z, Mata VG, Rodrigues AE, Adsorption, 7, 41 (2001)
Yong Z, Rodrigues AE, Energy Conv. Manag., 43(14), 1865 (2002)
Zou Y, Rodrigues AE, Ads. Sci. Technol., 19, 255 (2001)
Chen C, Yang ST, Ahn WS, Ryoo R, Chem. Commun., 24, 3627 (2009)
Goeppert A, Meth S, Prakash GS, Olah GA, Energy Environ. Sci., 3, 1949 (2010)
Qi G, Wang Y, Estevez L, Switzer AK, Duan X, Yang X, Giannelis EP, Chem. Mater., 22, 2693 (2010)
Wang J, Long D, Zhou H, Chen Q, Liu X, Ling L, Energy Environ. Sci., 5, 5742 (2012)
Xu XC, Song CS, Andresen JM, Miller BG, Scaroni AW, Energy Fuels, 16(6), 1463 (2002)
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Delaney SW, Knowles GP, Chaffee AL, Fuel Chem. Div. Preprints, 47, 65 (2002)
Hahn MW, Steib M, Jentys A, Lercher JA, J. Phys. Chem. C, 119, 4126 (2015)
Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 45(9), 3248 (2006)
Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 46(2), 446 (2007)
Knowles GP, Delaney SW, Chaffee AL, Ind. Eng. Chem. Res., 45(8), 2626 (2006)
Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y, Inorg. Chim. Acta., 240, 183 (1995)
Chen C, Kim J, Ahn WS, Korean J. Chem. Eng., 31(11), 1919 (2014)
Wang J, Huang L, Yang R, Zhang Z, Wu J, Gao Y, Wang Q, O'Hare D, Zhong Z, Energy Environ. Sci., 7, 3478 (2014)
Choi W, Min K, Kim C, Ko YS, Jeon JW, Seo H, Park YK, Choi M, Nat. Commun., 7, 12640 (2016)
Quang Dang Viet, Hatton T. Alan, Abu-Zahra Mohammad R. M., Ind. Eng. Chem. Res., 55(29), 7842 (2016)
Rahman I, Jafarzadeh M, Sipaut C, Ceram. Int., 35, 1883 (2009)
Sing KS, J. Porous Mater., 2, 5 (1995)
Mittal N, Samanta A, Sarkar P, Gupta R, Energy Sci. Eng., 3, 207 (2015)
Kim HJ, Chaikittisilp W, Jang KS, Didas SA, Johnson JR, Koros WJ, Nair S, Jones CW, Ind. Eng. Chem. Res., 54, 4407 (2014)
