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- In relation to this article, we declare that there is no conflict of interest.
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Received April 17, 2020
Accepted July 19, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Preparation of epoxypropyl functionalized graphene oxide and its anticorrosion properties complexed with epoxy resin
School of Science, North University of China, Taiyuan 030051, China 1School of chemical Engineering, Dalian Univesity of Technoloy, Dalian 116024, China
Korean Journal of Chemical Engineering, December 2020, 37(12), 2340-2350(11), 10.1007/s11814-020-0644-9
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Abstract
Functionalized graphene oxide (GO)/epoxy resin (EP) composite coating has attracted attention due to its advantages of epoxy resin in acid resistance, anticorrosion and having the characteristics of GO such as good chemical stability and strong electrolyte barrier properties. In this study, epoxypropyl functionalized graphene oxide (EFGO) was synthesized with a new strategy by grafting epichlorohydrin (ECH) onto the surface of GO. EFGO was then crosslinked with EP by diethylenetriamine (DETA) to fabricate EFGO/EP anticorrosive coating. The structure and property of EFGO and EFGO/EP were characterized and evaluated by various methods such as FTIR, Raman, XPS, SEM, and EIS. The results showed that the graft amount of epoxypropyl on GO surface could be effectively increased by using KI-KF catalysis system. The increase of the graft amount further improved the compatibility between EFGO and EP. EFGO/EP had a network structure with EFGO as the ¨central node〃. The ¨central node〃 locked the movement of EP chain segment, as improving the thermal stability of EFGO/EP. The EFGO/EP coating fabricated by the EFGO, which grafted larger epoxypropyl, had good anticorrosion performance and adhesion with steel plates, showing a good barrier effect on electrolyte migration. The coating resistance reached up 4.88 X 10 8 Ω cm2.
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