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Received June 17, 2020
Accepted August 17, 2020
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Synthesis and characterization of hydroxyethyl cellulose (HEC)-TiO2-based polyurethane bionanocomposites
Muhammad Fiayaz
Khalid Mahmood Zia†
Muhammad Asif Javaid1
Saima Rehman2
Shahzad Ali Shahid Chatha2
Mohammad Zuber
Department of Applied Chemistry, Government College University, Faisalabad 38030-Pakistan 1Department of Chemistry, University of Agriculture, Faisalabad 38040-Pakistan 2Department of Chemistry, Government College University, Faisalabad 38030-Pakistan
Korean Journal of Chemical Engineering, December 2020, 37(12), 2351-2358(8), 10.1007/s11814-020-0664-5
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Abstract
A novel green series of hydroxyethyl cellulose (HEC) based polyurethane (PUs) prepolymersblended with TiO2 nanoparticles were synthesized by reaction of Isophorone diisocyanate (IPDI), hydroxyl-terminated polybutadiene (HTPB), and hydroxyethyl cellulose (HEC). The chain was further extended with 1,4-butanediol (BDO) to get final HEC based polyurethane bio nanocomposites (FPUNC). A mixture of HEC based polymer and TiO2 nanoparticles was formed in solution polymerization, in which the TiO2 nanoparticles dispersed depending on interaction of TiO2 nanoparticles with polymer chains. The molecular structure of the synthesized PU bionanocomposites was confirmed by FTIR. A series of FPUNCs was prepared by varying the percent composition of the TiO2 nanoparticles into the PU matrix. The morphology of the bionanocomposites was carried out by X-ray diffraction (XRD) studies and scanning electron microscopy (SEM). SEM images verified the good dispersion of TiO2 nanoparticles into PU matrix. The thermal stability of the synthesized FPUNCs was done by thermal gravimetric analysis (TGA), and the FPUNC12 with 5% contents of TiO2 nanoparticles showed better thermal stability. The resultant HEC-TiO2 based FPUNCs material have promising bio-degradable and bio functional materials with good thermal properties and have potential applications in the field of biomaterials.
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Noreen A, Zia KM, Zuber M, Tabasum S, Saif MJ, Korean J. Chem. Eng., 33(2), 388 (2016)
Zhang Y, Jin Q, Zhao J, Wu C, Fan Q, Wu Q, Eur. Polym. J., 46, 1425 (2010)
Dogan SK, Boyacioglu S, Kodal M, Gokce O, Ozkoc G, J. Mech. Behav., Biomed. Mater., 71, 349 (2017)
Simmons A, Hyvarinen J, Poole-Warren L, Biomaterials, 27, 4484 (2006)
Alekseeva OV, Rodionova AN, Bagrovskaya NA, Agafonov AV, Noskov AV, Cellulose, 24, 1825 (2017)
Hubbe MA, Rojas OJ, Lucia LA, BioResources, 10, 6095 (2015)
Satish L, Achary K, Kumar A, Barik B, Nayak PB, Tripathy N, Kar JP, Dasha P, Sens. Actuators B-Chem., 272, 100 (2018)
Gorna K, Polowinski S, Gogolewski S, J. Polym. Sci. A: Polym. Chem., 40(1), 156 (2002)
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Zia KM, Zuber M, Saif MJ, Jawaid M, Mahmood K, Shahid M, Anjum MN, Ahmad MN, Int. J. Biol. Macromol., 62, 670 (2013)
Benhamou K, Kaddami H, Magnin A, Dufresne A, Ahmad A, Carbohydr. Polym., 122, 202 (2015)
Hubbe MA, Gardner DJ, Shen W, BioResources, 10, 8657 (2015)
Zia KM, Mahmood K, Zuber M, Jamil T, Shafiq M, Int. J. Biol. Macromol., 59, 320 (2013)
Zuber M, Zia KM, Mahboob S, Hassan M, Bhatti IA, Int. J. Biol. Macromol., 47, 196 (2010)
Mahmood K, Zia KM, Zuber M, Salman M, Anjum MN, Int. J. Biol. Macromol., 81, 877 (2015)
Youssef AM, El-Sayed SM, Salama HH, El-Sayed HS, Dufresne A, Carbohydr. Polym., 132, 274 (2015)
Rehim MHA, Youssef AM, Ghanem A, Polym. Bull., 72(9), 2353 (2015)
Youssef AM, Malhat FM, Abd El-Hakim AFA, Polym. Plast. Technol. Eng., 52, 228 (2013)
Youssef AM, RSC Adv., 4, 6811 (2014)
Hebeish AA, Abdelhady MM, Youssef AM, Carbohydr. Polym., 91, 549 (2013)
Kong X, Zhao L, Curtis JM, Carbohydr. Polym., 152, 487 (2016)
Zia KM, Zuber M, Barikani M, Jabbar A, Khosa MK, Carbohydr. Polym., 80, 539 (2010)
Fiayyaz M, Zia KM, Zuber M, Jamil T, Khosa MK, Jamal MA, Korean J. Chem. Eng., 31(4), 644 (2014)
Patterson A, Phys. Rev., 56, 978 (1939)
Noreen A, Zia KM, Tabasum S, Aftab W, Shahid M, Zuber M, Int. J. Biol. Macromol., 151, 993 (2020)
Mahmood K, Zia KM, Zuber M, Tabasum S, Rehman S, Zia F, Noreen A, Int. J. Biol. Macromol., 105, 1180 (2017)
Sun N, Wang T, Yan X, Carbohydr. Polym., 172, 49 (2017)
Fleming I, Williams D, Spectroscopic methods in organic chemistry, 7th Ed., Springer International Publishing, Springer Nature Switzerland AG (2019).
Han W, Tu M, Zeng R, Zhao J, Zhou C, Carbohydr. Polym., 90, 1353 (2012)
Taheri S, Sadeghi SMM, Appl. Clay Sci., 114, 430 (2015)
Javni I, Petrovic ZS, Guo A, Fuller R, J. Appl. Polym. Sci., 77(8), 1723 (2000)
Coimbra P, Alves P, Valente TAM, Santos R, Correia IJ, Ferreira P, Int. J. Biol. Macromol., 49, 573 (2011)
Wang W, Zhang TJ, Zhang DW, Li HY, Ma YR, Qi LM, Zhou YL, Zhang XX, Talanta, 84, 71 (2011)
Safaei M, Taran M, Int. J. Biol. Macromol., 104, 449 (2017)
Loganathan S, et al., Thermogravimetric analysis for characterization of nanomaterials at in micro and nano technologies, Elsevier, Amsterdam (2017).
