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Received October 2, 2019
Accepted November 19, 2019
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Bio-extract assisted in-situ green synthesis of Ag-RGO nanocomposite film for enhanced naproxen removal
Department of Chemical Engineering, Indian Institute of Technology Guwahati, Guwahati 781039, India
somen.mondal@iitg.ac.in
Korean Journal of Chemical Engineering, February 2020, 37(2), 274-289(16), 10.1007/s11814-019-0435-3
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Abstract
The present study reports in-situ green synthesis of Ag-RGO nanocomposite film using turnip leavesextract as a reducing as well as a capping agent and its application as a highly efficient naproxen adsorbent from a contaminated aqueous solution. The nanocomposite was characterized employing XRD, Raman and FT-IR spectroscopy, FETEM and FESEM microscopy, EDS spectroscopy. The pseudo-second-order and Elovich kinetic model furnished the best correlation of the experimental data, specifying the adsorption as the rate-limiting step for naproxen (NPX) removal by Ag-RGO composite film. The Freundlich and Dubinin-Radushkevich (D-R) isotherms represented the experimental adsorption data satisfactorily, suggesting a multilayered chemical adsorption process on the heterogeneous adsorbent surfaces. The process parameters were optimized to get the maximum adsorption capacity, which was obtained as 229.25mg g-1 (92.62%). The parametric effects of pHs and NPX concentrations were tested within a range of 2.50-8.50 and 25-100mg dm-3, respectively, for the contact time of 0.33-3 min at a constant temperature (298 K) and adsorbent dose (20.2mg). The feasibility of the regeneration of the materials after adsorption is based on the experimental results. The experimentally optimized process parameters were validated using response surface methodology (RSM).
Keywords
References
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Gorny D, Guzik U, Hupert-Kocurek K, Wojcieszynska D, Ecotoxicol. Environ. Saf., 167, 505 (2019)
Im JK, Heo J, Boateng LK, Her N, Flora JRV, Yoon J, Zoh KD, Yoon Y, J. Hazard. Mater., 254, 284 (2013)
Jallouli N, Elghniji K, Hentati O, Ribeiro AR, Silva AMT, Ksibi M, J. Hazard. Mater., 304, 329 (2016)
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Suresh D, Nethravathi PC, Nagabhushana HU, Sharma SC, Ceram. Int., 41, 4810 (2015)
Park CM, Heo J, Wang DJ, Su CM, Yoon Y, Appl. Catal. B: Environ., 225, 91 (2018)
Umbreen N, Sohni S, Ahmad I, Khattak NU, Gul K, J. Colloid Interface Sci., 527, 356 (2018)
Navalon S, Dhakshinamoorthy A, Alvaro M, Garcia H, Coord. Chem. Rev., 312, 99 (2016)
Wang CL, Astruc D, Prog. Mater. Sci., 94, 306 (2018)
Tajabadi MT, Basirun WJ, Lorestani F, Zakaria R, Baradaran S, Amin YM, Mahmoudian MR, Rezayi M, Sookhakian M, Electrochim. Acta, 151, 126 (2015)
Qustia AH, Mohamed RM, Salam MA, Ceram. Int., 40, 5539 (2014)
Wang L, Shi YL, Wang TF, Zhang LL, J. Colloid Interface Sci., 505, 421 (2017)
Neella N, Gaddam V, Nayak MM, Dinesh NS, Rajanna K, Sens. Actuators A-Phys., 268, 173 (2017)
Kavinkumar T, Manivannan S, Ceram. Int., 42, 1769 (2016)
Ovsianytskyi O, Nam YS, Tsymbalenko O, Lan PT, Moon MW, Lee KB, Sens. Actuators B-Chem., 257, 278 (2018)
Deng CH, Gong JL, Zhang P, Zeng GM, Song B, Liu HY, J. Colloid Interface Sci., 488, 26 (2017)
Mangalam J, Kumar M, Sharma M, Joshi M, Nano-Structures & Nano-Objects, 17, 58 (2019).
Salam HA, Rajiv P, Kamaraj M, Jagadeeswaran P, Gunalan S, Sivaraj R, Int. Res. J. Biol. Sci., 1, 85 (2012)
Vilchis-Nestor AR, Sanchez-Mendieta V, Camacho-Lopez MA, Gomez-Espinosa RM, Camacho-Lopez MA, Arenas-Alatorre JA, Mater. Lett., 62, 3103 (2008)
Martinez S, Olmos I, Carballo J, Franco I, J. Food Sci. Technol., 45, 773 (2010)
Moghayedi M, Goharshadi EK, Ghazvini K, Ahmadzadeh H, Ranjbaran L, Masoudi R, Ludwig R, Colloids Surf. B: Biointerfaces, 159, 366 (2017)
Abbaszadegan A, Ghahramani Y, Gholami A, Hemmateenejad B, Dorostkar S, Nabavizadeh M, Sharghi H, J. Nanomater., 2015, 1 (2014)
Bastus NG, Merkoci F, Piella J, Puntes V, Chem. Mater., 26, 2836 (2014)
Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)
Dutta S, Ray C, Sarkar S, Pradhan M, Negishi Y, Pal T, ACS Appl. Mater. Interfaces, 5, 8724 (2013)
Bhunia SK, Jana NR, ACS Appl. Mater. Interfaces, 6, 20085 (2014)
Shao W, Liu X, Min H, Dong G, Feng Q, Zuo S, ACS Appl. Mater. Interfaces, 7, 6966 (2015)
Jiao T, Guo H, Zhang Q, Peng Q, Tang Y, Yan X, Li B, Sci. Rep., 5, 11873 (2015)
Maryami M, Nasrollahzadeh M, Mehdipour E, Sajadi SM, Int. J. Hydrog. Energy, 41(46), 21236 (2016)
Blazquez G, Martin-Lara MA, Tenorio G, Calero M, Chem. Eng. J., 168(1), 170 (2011)
Kiran I, Akar T, Tunali S, Process Biochem., 40(11), 3550 (2005)
Meng N, Zhang S, Zhou Y, Nie W, Chen P, RSC Adv., 5, 70968 (2015)
Li YH, Zhang HY, Wu BW, Guo Z, Appl. Surf. Sci., 425, 194 (2017)
Divya KS, Chandran A, Reethu VN, Mathew S, Appl. Surf. Sci., 444, 811 (2018)
Zuccaro L, Krieg J, Desideri A, Kern K, Balasubramanian K, Sci. Rep., 5, 1 (2015)
Molleman B, Hiemstra T, Environ. Sci. Nano, 4, 1314 (2017)
Demirbas E, Dizge N, Sulak MT, Kobya M, Chem. Eng. J., 148(2-3), 480 (2009)
Sohni S, Gul K, Ahmad F, Ahmad I, Khan A, Khan N, Khan SB, Polym. Compos., 39, 3317 (2017)
Zhao GX, Li JX, Wang XK, Chem. Eng. J., 173(1), 185 (2011)
Inam E, Etim UJ, Akpabio EG, Umoren SA, J. Taibah Univ. Sci., 11, 173 (2017)
Kose TE, Demiral H, Ozturk N, Desalin. Water. Treat., 29, 110 (2011)
Argun ME, Dursun S, Ozdemir C, Karatas M, J. Hazard. Mater., 141(1), 77 (2007)
Zhang H, Ran XN, Wu XG, Zhang DB, J. Hazard. Mater., 188(1-3), 261 (2011)
Baccar R, Sarra M, Bouzid J, Feki M, Blanquez P, Chem. Eng. J., 211-212, 310 (2012)
Khazri H, Ghorbel-Abid I, Kalfat R, Trabelsi-Ayadi M, Appl. Water Sci., 7, 3031 (2016)
Jung C, Oh J, Yoon Y, Environ. Sci. Pollut. Res., 22, 10058 (2015)
Hasan Z, Choi EJ, Jhung SH, Chem. Eng. J., 219, 537 (2013)
Avila HER, Castillo DIM, Petriciolet AB, Albero JS, J. Mol. Liq., 209, 187 (2015)
Ilbay Z, Sahin S, Kerkez O, Bayazit SS, Int. J. Environ. Sci. Technol., 12, 3541 (2015)
web ref.: Infrared spectroscopy adsorption table, chemistry, Libre-Textshttps://chem.libretexts.org/Reference/Reference_Tables/Spectroscopic_Parameters/Infrared_Spectroscopy_Absorption_Table.
