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Received May 9, 2019
Accepted August 5, 2019
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Influence of functionalized SiO2 nanoparticles on the morphology and CO2/CH4 separation efficiency of Pebax-based mixed-matrix membranes
Mineral Biochemistry Laboratory, Department of Chemistry, Iran University of Science and Technology (IUST), Narmak, Tehran, Iran 1Faculty of Mechanical Engineering, Semnan University, Semnan, Iran 2Department of Chemical Engineering, Shiraz Branch, Islamic Azad University, Shiraz, Iran 3Nanotechnology Research Institute, School of Chemical Engineering, Babol (Noshirvani) University of Technology, Babol, Iran
n_azizi@iust.ac.ir
Korean Journal of Chemical Engineering, February 2020, 37(2), 295-306(12), 10.1007/s11814-019-0350-7
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Abstract
Silica (SiO2) nanoparticles were first functionalized using (3-aminopropyl) triethoxysilane (APTES) and then utilized as filler for the preparation of poly (ether-block-amide) (Pebax®-1074) based mixed-matrix membranes (MMMs). To characterize the modified nanoparticles and the prepared membranes, Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and thermal gravimetric analysis (TGA) were conducted. The influences of the pure and amine-modified nanoparticles content, and feed temperature and pressure on CO2 and CH4 permeability and ideal CO2/CH4 selectivity values of the membranes were studied. The permeation experiments exhibited that the incorporation of 12.5 wt% of amine-functionalized SiO2 nanoparticles into the Pebax matrix raises the CO2 permeability and ideal CO2/CH4 selectivity about 100 and 32%, respectively.
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Murali RS, Ismail AF, Rahman MA, Sridhar S, Sep. Purif. Technol., 129, 1 (2014)
Azizi N, Hojjati MR, Pet. Sci. Technol., 36, 993 (2018)
Azizi N, Zarei MM, Pet. Sci. Technol., 35, 869 (2017)
Rajati H, Navarchian AH, Tangestaninejad S, Chem. Eng. Sci., 185, 92 (2018)
Rabiee H, Alsadat SM, Soltanieh M, Mousavi SA, Ghadimi A, J. Ind. Eng. Chem., 27, 223 (2015)
Ghadimi A, Mohammadi T, Kasiri N, Int. J. Hydrog. Energy, 40(31), 9723 (2015)
Ghadimi A, Norouzbahari S, Sadrzadeh M, Mohammadi T, Polym. Adv. Technol., 23, 1101 (2012)
Asghari M, Mosadegh M, Harami HR, Chem. Eng. Sci., 187, 67 (2018)
Moghadassi AR, Rajabi Z, Hosseini SM, Mohammadi M, Sep. Sci. Technol., 48(8), 1261 (2013)
Goh PS, Ismail AF, Sanip SM, Ng BC, Aziz M, Sep. Purif. Technol., 81(3), 243 (2011)
Hwang S, Chi WS, Lee SJ, Im SH, Kim JH, Kim J, J. Membr. Sci., 480, 11 (2015)
Khajouei M, Peyravi M, Jahanshahi M, J. Membr. Sci. Res., 3, 2 (2017)
Ataeivarjovi E, Tang Z, Chen J, ACS Appl. Mater. Interfaces, 10, 28992 (2018)
Sadeghi M, Talakesh MM, Ghalei B, Shafiei M, J. Membr. Sci., 427, 21 (2013)
Hassanajili S, Khademi M, Keshavarz P, J. Membr. Sci., 453, 369 (2014)
Rezakazemi M, Vatani A, Mohammadi T, RSC Adv., 5, 82460 (2015)
Isanejad M, Mohammadi T, Mater. Chem. Phys., 205, 303 (2018)
Amedi HR, Aghajani M, Microporous Mesoporous Mater., 247, 124 (2017)
Shamsabadi AA, Seidi F, Salehi E, Nozari M, Rahimpour A, Soroush M, J. Mater. Chem. A, 5, 4011 (2017)
Mallakpour S, Madani M, Prog. Org. Coat., 86, 194 (2015)
Bourgeatlami E, Espiard P, Guyot A, Polymer, 36(23), 4385 (1995)
Antony R, Manickam STD, Kollu P, Chandrasekar P, Karuppasamy K, Balakumar S, RSC Adv., 4, 24820 (2014)
Azizi S, Azizi N, Homayoon R, Silicon, 11, 2045 (2019)
Isanejad M, Azizi N, Mohammadi T, J. Appl. Polym. Sci., 134, 44531 (2017)
Azizi N, Arzani M, Mahdavi HR, Mohammadi T, Korean J. Chem. Eng., 34(9), 2459 (2017)
Ghadimi A, Mohammadi T, Kasiri N, Ind. Eng. Chem. Res., 53(44), 17476 (2014)
Azizi N, Mohammadi T, Behbahani RM, J. Energy Chem., 26, 454 (2017)
Azizi N, Mohammadi T, Behbahani RM, J. Nat. Gas Sci. Eng., 37, 39 (2017)
Azizi N, Mohanunadi T, Behbahani RM, Chem. Eng. Res. Des., 117, 177 (2017)
Moghadam F, Omidkhah MR, Vasheghani-Farahani E, Pedram MZ, Dorosti F, Sep. Purif. Technol., 77(1), 128 (2011)
Rezakazemi M, Amooghin AE, Montazer-Rahmati MM, Ismail AF, Matsuura T, Prog. Polym. Sci, 39, 817 (2014)
Chen JH, Rong MZ, Ruan WH, Zhang MQ, Compos. Sci. Technol., 69, 252 (2009)
D’Agostino A, Errico ME, Malinconico M, De Rosa M, Avella M, Schiraldi C, J. Mater. Sci. -Mater. Med., 22, 481 (2011)
Kim JH, Lee YM, J. Membr. Sci., 193(2), 209 (2001)
Choi MC, Jung JY, Yeom HS, Chang YW, Polym. Eng. Sci., 53(5), 982 (2013)
Mahdavi HR, Azizi N, Arzani M, Mohammadi T, J. Nat. Gas Sci. Eng., 46, 275 (2017)
Ghadimi A, Amirilargani M, Mohammadi T, Kasiri N, Sadatnia B, J. Membr. Sci., 458, 14 (2014)
Dixon D, Boyd A, Polym. Eng. Sci., 51(11), 2203 (2011)
Wang YB, Ren JZ, Deng MC, Sep. Purif. Technol., 77(1), 46 (2011)
Murali RS, Kumar KP, Ismail A, Sridhar S, Microporous Mesoporous Mater., 197, 291 (2014)
Rabiee H, Ghadimi A, Abbasi S, Mohammadi T, Chem. Eng. Res. Des., 98, 96 (2015)
Murali RS, Sridhar S, Sankarshana T, Ravikumar YVL, Ind. Eng. Chem. Res., 49(14), 6530 (2010)
Yampolskii Y, Freeman B, Membrane gas separation, Wiley Online Library (2010).
Murali RS, Ismail AF, Rahman MA, Sridhar S, Sep. Purif. Technol., 129, 1 (2014)
Zhao D, Ren JZ, Li H, Li XX, Deng MC, J. Membr. Sci., 467, 41 (2014)
Wang SF, Liu Y, Huang SX, Wu H, Li YF, Tian ZZ, Jiang ZY, J. Membr. Sci., 460, 62 (2014)
Nordin NAHM, Racha SM, Matsuura T, Misdan N, Sani NAA, Ismail AF, Mustafa A, RSC Adv., 5, 43110 (2015)
Nordin NAHM, Ismail AF, Mustafa A, Murali RS, Matsuura T, RSC Adv., 5, 30206 (2015)
Dorosti F, Omidkhah M, Abedini R, J. Nat. Gas Sci. Eng., 25, 88 (2015)
Chowdhury P, Mekala S, Dreisbach F, Gumma S, Microporous Mesoporous Mater., 152, 246 (2012)
Serra-Crespo P, Ramos-Fernandez EV, Gascon J, Kapteijn F, Chem. Mater., 23, 2565 (2011)
Shishatskiy S, Pauls JR, Nunes SP, Peinemann KV, J. Membr. Sci., 359(1-2), 44 (2010)
Linfang W, Lei M, Aiqin W, Qian L, Zhang T, Chinese J. Catal., 28, 805 (2007)
Duan J, Higuchi M, Krishna R, Kiyonaga T, Tsutsumi Y, Sato Y, Kubota Y, Takata M, Kitagawa S, Chem. Sci., 5, 660 (2014)
Zelenak V, Badanicova M, Halamova D, Cejka J, Zukal A, Murafa N, Goerigk G, Chem. Eng. J., 144(2), 336 (2008)
Takahashi S, Paul DR, Polymer, 47(21), 7519 (2006)
Matteucci S, Kusuma VA, Sanders D, Swinnea S, Freeman BD, J. Membr. Sci., 307(2), 196 (2008)
Shariati A, Omidkhah M, Pedram MZ, Chem. Eng. Res. Des., 90(4), 563 (2012)
Rabiee H, Ghadimi A, Mohammadi T, J. Membr. Sci., 476, 286 (2015)
Adewole J, Ahmad A, Ismail S, Leo C, Int. J. Greenh Gas Control, 17, 46 (2013)
Robeson LM, J. Membr. Sci., 62, 165 (1991)
Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)
Jomekian A, Behbahani RM, Mohammadi T, Kargari A, J. Nat. Gas Sci. Eng., 31, 562 (2016)
Dai Y, Ruan XH, Yan ZJ, Yang K, Yu M, Li H, Zhao W, He GH, Sep. Purif. Technol., 166, 171 (2016)
Nafisi V, Hagg MB, J. Membr. Sci., 459, 244 (2014)
Murali RS, Ismail AF, Rahman MA, Sridhar S, Sep. Purif. Technol., 129, 1 (2014)
