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Received September 11, 2019
Accepted January 5, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Silver and palladium nanoparticle embedded poly(n-isopropylacrylamide-co-2-acrylamido-2-methylpropane sulfonic acid) hybrid microgel catalyst with pH and temperature dependent catalytic activity
Abdul Haleem1
Sidra Bibi Syaal2
Muhammad Ajmal3
Jaweria Ambreen4
Sajid Rauf5
Nasir Ali6
Saz Muhammad2
Afzal Shah2 7
Muhammad Abid Zia3
Muhammad Siddiq1 3†
1CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China 2Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan 3Department of Chemistry, University of Education, Attock Campus, Attock 43600, Pakistan 4Department of Chemistry, COMSATS University Islamabad, Parkroad, 45550, Islamabad, Pakistan 5Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Faculty of Physics and Electronic Science, Hubei University, Wuhan, Hubei 430062, P. R. China 6Zhejiang Province Key Laboratory of Quantum Technology and Devices and Department of Physics, State Key Laboratory for Silicon Materials, Zhejiang University, Hangzhou, 310027, P. R. China 7Department of Chemistry, College of Science University of Bahrain, Sakhir 32038, Bahrain
Korean Journal of Chemical Engineering, April 2020, 37(4), 614-622(9), 10.1007/s11814-020-0484-7
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Abstract
Here in, we demonstrate facile fabrication of silver and palladium nanoparticles in dual responsive poly(Nisopropylacrylamide- co-2-Acrylamido-2-methylpropane sulfonic acid) microgel with temperature- and pH-dependent catalytic potential. Palladium-based catalyst showed better catalytic efficiency as compared to silver-based catalyst for degradation of Rhodamine-B and P-Nitrophenol in aqueous medium under the same set of reaction conditions. The responsive nature of the microgel was found to be useful to tune the catalytic activity of the as-prepared catalysts, and reduction rate was enhanced with the pH and temperature elevation of the reaction medium; however, the increasing trend was slowed in the volume phase transition region of the microgel. Under a specific set of reaction conditions, the reduction of Rhodamine-B was as fast as 0.968 and 0.571 min-1 when catalyzed with palladium and silver based catalysts, respectively. The hydrodynamic radius of the particles of microgel support was found to be in the range of 65- 180 nm when pH and temperature of the medium were varied in the range of 2-12 and 25-45, respectively. The estimated diameter of silver and palladium nanoparticles fabricated in the microgel support under the same set of reaction conditions was 9-15 and 7-11 nm, respectively.
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Gupta VK, Ali I, Saleh TA, Nayak A, Agarwal S, RSC Adv., 2, 6380 (2012)
Kim J, Kim K, Ye H, Lee E, Shin C, McCarty PL, Bae J, Environ. Sci. Technol., 45, 576 (2010)
Crampton AS, Rotzer MD, Ridge CJ, Schweinberger FF, Heiz U, Yoon B, Landman U, Nat. Commun., 7, 10389 (2016)
Lu Y, Wang J, Yu L, Kovarik L, Zhang X, Hoffman AS, Gallo A, Bare SR, Sokaras D, Kroll T, Nat. Catal., 2, 149 (2019)
Kuo CT, Lu Y, Kovarik L, Engelhard MH, Karim AM, ACS Catal., 9, 11030 (2019)
Farooqi ZH, Khan SR, Begum R, Mater. Sci. Technol., 33, 129 (2017)
Begum R, Naseem K, Farooqi ZH, J. Sol-Gel Sci. Technol., 77, 497 (2016)
Naseer F, Ajmal M, Bibi F, Farooqi ZH, Siddiq M, Polym. Compos., 39, 3187 (2018)
Bibi F, Ajmal M, Naseer F, Farooqi Z, Siddiq M, Int. J. Environ. Sci. Technol., 15, 863 (2018)
Ganesh VA, Baji A, Ramakrishna S, RSC Adv., 4, 53352 (2014)
Contreras-Caceres R, Sanchez-Iglesias A, Karg M, Pastoriza-Santos I, Perez-Juste J, Pacifico J, Hellweg T, Fernandez-Barbero A, Liz-Marzan LM, Adv. Mater., 20(9), 1666 (2008)
Liu J, Shu T, Su L, Zhang X, Serpe MJ, RSC Adv., 8, 16850 (2018)
Farooqi ZH, Khan SR, Begum R, Ijaz A, Rev. Chem. Eng., 32(1), 49 (2016)
Begum R, Farooqi ZH, Khan SR, Int. J. Polymer. Mater. Polymer. Biomater., 65, 841 (2016)
Farooqi ZH, Khan SR, Hussain T, Begum R, Ejaz K, Majeed S, Ajmal M, Kanwal F, Siddiq M, Korean J. Chem. Eng., 31(9), 1674 (2014)
Farooqi ZH, Ijaz A, Begum R, Naseem K, Usman M, Ajmal M, Saeed U, Polym. Compos., 39, 645 (2018)
Han DM, Zhang QM, Serpe MJ, Nanoscale, 7, 2784 (2015)
Liu YY, Liu XY, Yang JM, Lin DL, Chen X, Zha LS, Colloids Surf. A: Physicochem. Eng. Asp., 393, 105 (2012)
Sahiner N, Butun S, Turhan T, Chem. Eng. Sci., 82, 114 (2012)
Shah LA, Ambreen J, Bibi I, Sayed M, Siddiq M, J. Chem. Soc. Pak., 38, 850 (2016)
Zhang QM, Wang W, Su YQ, Hensen EJM, Serpe MJ, Chem. Mater., 28, 259 (2016)
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Larsson E, Boujemaoui A, Malmstrom E, Carlmark A, RSC Adv., 5, 77643 (2015)
Vakifli A, Demirel GB, Caykara T, J. Appl. Polym. Sci., 117(2), 817 (2010)
Zhang C, Easteal AJ, J. Appl. Polym. Sci., 104(3), 1723 (2007)
Varaprasad K, Ravindra S, Reddy NN, Vimala K, Raju KM, J. Appl. Polym. Sci., 116(6), 3593 (2010)
Mallikarjuna K, Bathula C, Reddy GD, Shrestha NK, Kim H, Noh YY, Int. J. Biol. Macromol., 126, 352 (2019)
Atta AM, Gafer AK, Al-Lohedan HA, Abdullah M, Tawfeek AM, Ezzat AO, Molecules, 24, 3867 (2019)
Ali N, Bi G, Khesro A, Khan M, Lang J, Samreen A, Wu H, New J. Chem., 42, 18991 (2018)
Zhao RY, Sun XX, Jin YR, Han JS, Wang L, Liu FS, J. Mater. Sci., 54(7), 5445 (2019)
Zhang YM, Quek XY, Wu LL, Guan YJ, Hensen EJ, J. Mol. Catal. A-Chem., 379, 53 (2013)
He F, Zhao D, Environ. Sci. Technol., 39, 3314 (2005)
Singh R, Misra V, Mudiam MKR, Chauhan LKS, Singh RP, J. Hazard. Mater., 237, 355 (2012)
Magdalane CM, Kaviyarasu K, Vijaya JJ, Siddhardha B, Jeyaraj B, Kennedy J, Maaza M, J. Alloy. Compd., 727, 1324 (2017)
