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Received September 24, 2019
Accepted January 12, 2020
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Microwave-assisted production of biodiesel using metal-organic framework Mg3(bdc)3(H2O)2
1Analysis and Evaluation Division, Egyptian Petroleum Research Institute, Nasr City, P. O. Box 11727, Cairo, Egypt 2Catalysis Department, Petroleum Refining Division, Egyptian Petroleum Research Institute, Nasr City, P. O. Box 11727, Cairo, Egypt 3Chemistry Department, Faculty of Science, Helwan University, 11795, Cairo, Egypt 4EPRI-Nanotechnology Center, Egyptian Petroleum Research Institute, Nasr City, P. O. Box 11727, Cairo, Egypt
helmaghrbi@gmail.com
Korean Journal of Chemical Engineering, April 2020, 37(4), 670-676(7), 10.1007/s11814-020-0491-8
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Abstract
Metal-organic framework Mg-MOF: (Mg3(bdc)3(H2O)2) was synthesized via microwave (MW) irradiation, then used in the microwave-assisted production of biodiesel from oleic acid. Microwave irradiation was used as an alternative ecofriendly route to conventional heating. The synthesized Mg-MOF sample was characterized by XRD, TGA, FT-IR, nitrogen adsorption/desorption and TEM techniques. The catalytic activity of Mg-MOF in the microwave- assisted production of Biodiesel from oleic acid and methanol was studied. Vacancies created upon removal of linkers, metal clusters composed MOF frameworks, small pore size and its surface area are responsible for the high catalytic activity of the prepared Mg-MOF. The results indicated that Mg-MOF catalyst showed high conversion percentage (97%) that followed pseudo-first order, under mild reaction conditions (MW power: 150watts, reaction time: 8min, molar ratio of oleic acid to methanol: 1 : 15 and catalyst amount 0.15 wt%).
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Cea M, Gonzalez ME, Abarzua M, Navia R, J. Environ. Manage., 242, 171 (2019)
Lee JH, Kim SB, Yoo HY, Lee JH, Han SO, Park C, Kim SW, Korean J. Chem. Eng., 30(6), 1335 (2013)
Fjerbaek L, Christensen KV, Norddahl B, Biotechnol. Bioeng., 102(5), 1298 (2009)
Yesiloglu Y, Process Biochem., 40(6), 2155 (2005)
Silitonga AS, Masjuki HH, Mahlia TMI, Ong HC, Atabani AE, Chong WT, Renew. Sust. Energ. Rev., 24, 514 (2013)
Vahid BR, Haghighi M, Energy Conv. Manag., 126, 362 (2016)
Kim M, DiMaggio C, Salley SO, Ng KYS, Bioresour. Technol., 118, 37 (2012)
Wan H, Chen C, Wu Z, Que Y, Feng Y, Wang W, Wang L, Guan G, Liu X, ChemCatChem., 7, 441 (2015)
Aghabarari B, Dorostkar N, J. Taiwan Inst. Chem. Eng., 45, 1468 (2014)
Istadi I, Anggoro DD, Buchori L, Rahmawati DA, Intaningrum D, Proc. Environ. Sci., 23, 385 (2015)
Soltani S, Rashid U, Yunus R, Taufiq-Yap YH, Fuel, 178, 253 (2016)
Kaduk JA, Acta Cryst. Sec. B, 58, 815 (2002)
Rood JA, Noll BC, Henderson KW, Main Group Chem., 5, 21 (2006)
Davies RP, Less RJ, Lickiss PD, White AJP, Dalton Trans., 24, 2528 (2007)
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Dietzel PDC, Blom R, Fjellvag H, Eur. J. Inorg. Chem., 23, 3624 (2008)
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Khan NR, Rathod VK, Process Biochem., 75, 89 (2018)
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Chellappan S, Aparna K, Chingakham C, Sajith V, Nair V, Fuel, 246, 268 (2019)
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Lin JJ, Chen YW, J. Taiwan Inst. Chem. E., 75, 43 (2017)
Jermolovicius LA, Cantagesso LCM, do Nascimento RB, de Castro ER, Pouzada EVD, Senise JT, Chem. Eng. Process., 122, 380 (2017)
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Ketzer F, Celante D, de Castilhos F, Microporous Mesoporous Mater., 291, 109704 (2020)
Wang YT, Fang Z, Zhang F, Catal. Today, 319, 172 (2019)
Cannilla C, Bonura G, Costa F, Frusteri F, Appl. Catal. A: Gen., 566, 121 (2018)
Alismaeel ZT, Abbas AS, Albayati TM, Doyle AM, Fuel, 234, 170 (2018)
Hykkerud A, Marchetti JM, Biomass Bioenerg., 95, 340 (2016)
Abd El Salam HM, Zaki T, Inorg. Chim. Acta., 471, 203 (2018)
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Cardoso AL, Neves SCG, da Silva MJ, Energies, 1, 79 (2008)
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El-Nahas AM, Salaheldin TA, Zaki T, El-Maghrabi HH, Marie AM, Morsy SM, Allam NK, Chem. Eng. J., 322, 167 (2017)
Gan SY, Ng HK, Chan PH, Leong FL, Fuel Process. Technol., 102, 67 (2012)
Vitillo JG, RSC Adv., 5, 36192 (2015)
Shaban M, Abukhadra MR, Hosny R, Rabie AM, Ahmed SA, Negm NA, J. Mol. Liq., 279, 224 (2019)
Cirujano FG, Corma A, Xamena FXLI, Catal. Today, 257, 213 (2015)
Pena-Rodriguez R, Marquez-Lopez E, Guerrero A, Chinas LE, Hernandez-Gonzalez DF, Rivera JM, Mater Lett., 217, 117 (2018)
Han M, Li Y, Gu Z, Shi H, Chen C, Wang Q, Wan H, Guan G, Colloids Surf. A: Physicochem. Eng. Asp., 553, 593 (2018)
Xie WL, Wan F, Chem. Eng. J., 365, 40 (2019)
