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Received September 21, 2019
Accepted January 31, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Synthesis of inorganic doped polyvinyl alcohol/hydroxypropyl methyl cellulose mixed matrix membrane for pervaporative separation of dimethyl carbonate/methanol mixtures
Department of Chemical Engineering, Engineering and Natural Science Faculty, Bursa Technical University, 16310, Bursa, Turkey
Korean Journal of Chemical Engineering, April 2020, 37(4), 698-706(9), 10.1007/s11814-020-0503-8
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Abstract
Inorganic loaded Polyvinyl Alcohol/Hydroxypropyl Methyl Cellulose (PVA/HPMC) mixed matrix composite membranes were synthesized by filling phosphomolybdic acid (PMA) into PVA/HPMC matrix. The obtained results indicate that the swelling degree of the PMA loaded PVA/HPMC blend membranes enhances with excess PMA amount or high feed methanol (MeOH) concentration. The effects of HPMC ratio in blend membranes, PMA content, feed methanol concentration and operation temperature on separation success of pervaporation (PV) were also examined. The consequences demonstrate that the separation factor decreased with PMA amount and led to the ultimate value at 4 wt% PMA amount. Then the increase of PMA content resulted in the decline of the separation factor. Under all conditions, PMA doped mixed matrix composite membrane had a higher separation factor and flux values according to the pristine PVA membrane. Of all the membranes studied, while the flux increased by the high temperature or feed methanol concentration, the separation factor of MeOH decreased. While the operation temperature was 50 °C, the feed methanol concentration was 10 wt%; 4 wt% PMA doped mixed matrix composite membrane has significant separation performance with a flux of 1.31 kg/m2h and separation factor of 121.04.
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Wijmans JG, Baker RW, J. Membr. Sci., 107(1-2), 1 (1995)
Dmitrenko M, Penkova A, Kuzminova A, Missyul A, Ermakov S, Roizard D, Polymers, 10, 571 (2018)
Sajjan AM, Kumar BKJ, Kittur AA, Kariduraganavar MY, J. Ind. Eng. Chem., 19(2), 427 (2013)
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Magalad VT, Gokavi GS, Raju KVSN, Aminabhavi TM, J. Membr. Sci., 354(1-2), 150 (2010)
Teli SB, Gokavi GS, Sairam M, Aminabhavi TM, Colloids Surf. A: Physicochem. Eng. Asp., 301, 55 (2007)
Chen JH, Liu QL, Zhu AM, Zhang QG, Fang J, J. Membr. Sci., 315(1-2), 74 (2008)
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Liu BB, Cato YM, Wang TH, Yuan Q, J. Appl. Polym. Sci., 106(3), 2117 (2007)
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Won W, Feng XS, Lawless D, J. Membr. Sci., 209(2), 493 (2002)
