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Received December 19, 2019
Accepted March 13, 2020
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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The influence of the Gemini surfactants hydrocarbon tail on in-situ synthesis of silver nanoparticles: Characterization, surface studies and biological performance

1School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Korea 2Biomedical Institute for Convergence at SKKU (BICS), Sungkyunkwan University, Suwon 16419, Korea
Dhkim1@skku.edu
Korean Journal of Chemical Engineering, June 2020, 37(6), 1008-1019(12), 10.1007/s11814-020-0542-1
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Abstract

Three different Gemini compounds containing different lengths of multi-carbonyl groups were synthesized, and the effect of their hydrocarbon tail length on the AgNPs synthesis was investigated. The Gemini surfactants with the long hydrocarbon chain tail produces small AgNPs with a narrow size distribution and high colloidal stability in an aqueous phase. The surface parameters of the aqueous solution were affected by the hydrocarbon chain length as well as phase temperature. The critical micelle concentration, assessed by surface tension and conductometric measurements, decreases with both increasing solution temperature and increasing hydrocarbon tail length. Thermodynamic calculations predicted the ability of the synthesized Gemini surfactant to adsorb on the phase surface and aggregate in a cluster.

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