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Received October 19, 2019
Accepted February 6, 2020
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Effects of magnesium loading on ammonia capacity and thermal stability of activated carbons
Korea Institute of Industrial Technology, 89, Yangdaegiro-gil, Ipjang-myeon, Seobuk-gu, Cheonan-si Chungcheongnam-do 31056, South Korea 1Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, South Korea 2Korea Institute of Energy Research, 140, Yuseong-daero, 1312 beon-gil, Yuseong-gu, Daejeon 34101, South Korea 3Department of Chemical Engineering Education, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, South Korea
Korean Journal of Chemical Engineering, June 2020, 37(6), 1029-1035(7), 10.1007/s11814-020-0508-3
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Abstract
Mg-loaded activated carbons were prepared by adding various amounts of Mg (1 to 20 wt%) via ultrasonic- assisted impregnation to investigate the effects on the adsorption and desorption characteristics of ammonia. Mgloaded activated carbons were characterized by TGA, BET, SEM, EDS mapping, and NH3-TPD analysis. Mg was homogeneously dispersed on the activated carbon and NH3-TPD analysis confirmed improved desorption and thermal stability for the 10 wt% Mg sample, named AC-Mg(10). AC-Mg(10) retained the highest desorption for five cycles and showed average desorption amount of 0.788mmol NH3/g. During the breakthrough analysis, the AC-Mg(10) showed an initial ammonia adsorption capacity of 0.81mmol NH3/g and average adsorption capacity of 0.69mmol NH3/g over 30 adsorption and desorption cycles.
References
Shipman MA, Symes MD, Catal. Today, 286, 57 (2017)
Smil V, Nature, 400, 415 (1999)
Jewell S, Kimball SM, US Geological Survey, 9, 196 (2015)
Kim K, Lee SJ, Kim DY, Yoo CY, Choi JW, Kim JN, Woo Y, Yoon HC, Han JI, ChemSusChem, 11, 120 (2018)
Chen S, Perathoner S, Ampelli C, Mebrahtu C, Su D, Centi G, Angew. Chem.-Int. Edit., 56, 2699 (2017)
Jeong EY, Yoo CY, Jung CH, Park JH, Park YC, Kim JN, Oh SG, Woo Y, Yoon HC, ACS Sustain. Chem. Eng., 5, 9662 (2017)
Kordali V, Kyriacou G, Lambrou C, Chem. Commun., 17, 1673 (2000)
Renner JN, Greenlee LF, Ayres KE, Herring AM, Electrochem. Soc. Interface, 24, 51 (2015)
Bandosz TJ, Petit C, J. Colloid Interface Sci., 338(2), 329 (2009)
Ghauri M, Tahir M, Abbas T, Khurram MS, Shehzad K, Sci. Int., 24, 411 (2012)
Goncalves M, Sanchez-Garcia L, Jardim EDO, Silvestre-Albero J, Rodriguez-Reinoso F, Environ. Sci. Technol., 45, 10605 (2011)
Guo J, Xu WS, Chen YL, Lua AC, J. Colloid Interface Sci., 281(2), 285 (2005)
Huang CC, Li HS, Chen CH, J. Hazard. Mater., 159(2-3), 523 (2008)
Kim SD, Magnone E, Park JH, Ryu JY, J. Porous Mat., 25, 297 (2018)
Rieth AJ, Dinca M, J. Am. Chem. Soc., 140(9), 3461 (2018)
Seredych M, Petit C, Tamashausky AV, Bandosz TJ, Carbon, 47, 445 (2009)
Chen Y, Zhang F, Wang Y, Yang C, Yang J, Li J, Microporous Mesoporous Mater., 258, 170 (2018)
Khabzina Y, Farrusseng D, Microporous Mesoporous Mater., 265, 143 (2018)
Qajar A, Peer M, Andalibi MR, Rajagopalan R, Foley HC, Microporous Mesoporous Mater., 218, 15 (2015)
Molina L, Hammer B, Phys. Rev. B, 69, 155424 (2004)
de Farias AMD, Barandas APMG, Perez RF, Fraga MA, J. Power Sources, 165(2), 854 (2007)
Park JH, Baek JH, Hwang RH, Yi KB, Clean Technol., 23(4), 429 (2017)
Baek JI, Ryu J, Lee JB, Eom TH, Kim KS, Yang SR, Ryu CK, Energy Procedia, 4, 349 (2011)
Zhao M, Minett AI, Harris AT, Energy Environ. Sci., 6, 25 (2013)
Choudhary VR, Uphade BS, Mamman AS, Catal. Lett., 32(3-4), 387 (1995)
Iriondo A, Barrio V, Cambra J, Arias P, Guemez M, Navarro R, Sanchez-Sanchez M, Fierro J, Top. Catal., 49, 46 (2008)
Parmaliana A, Arena F, Frusteri F, Coluccia S, Marchese L, Martra G, Chuvilin A, J. Catal., 141, 34 (1993)
Silva WM, Ribeiro H, Seara LM, Calado HD, Ferlauto AS, Paniago RM, Leite CF, Silva GG, J. Braz. Chem. Soc., 23, 1078 (2012)
Tian X, Hong G, Liu Y, Jiang B, Yang Y, RSC Adv., 4, 36316 (2014)
Al Amer AM, Laoui T, Abbas A, Al-Aqeeli N, Patel F, Khraisheh M, Atieh MA, Hilal N, Mater. Des., 89, 549 (2016)
Baek JH, Jeong JM, Park JH, Yi KB, Rhee YW, Trans. Korean Hydrog. New Energy Soc., 26, 423 (2015)
Jeong JM, Park JH, Baek JH, Hwang RH, Jeon SG, Yi KB, Korean J. Chem. Eng., 34(1), 81 (2017)
Wu Z, Jin R, Liu Y, Wang H, Catal. Commun., 9, 2217 (2008)
Smil V, Nature, 400, 415 (1999)
Jewell S, Kimball SM, US Geological Survey, 9, 196 (2015)
Kim K, Lee SJ, Kim DY, Yoo CY, Choi JW, Kim JN, Woo Y, Yoon HC, Han JI, ChemSusChem, 11, 120 (2018)
Chen S, Perathoner S, Ampelli C, Mebrahtu C, Su D, Centi G, Angew. Chem.-Int. Edit., 56, 2699 (2017)
Jeong EY, Yoo CY, Jung CH, Park JH, Park YC, Kim JN, Oh SG, Woo Y, Yoon HC, ACS Sustain. Chem. Eng., 5, 9662 (2017)
Kordali V, Kyriacou G, Lambrou C, Chem. Commun., 17, 1673 (2000)
Renner JN, Greenlee LF, Ayres KE, Herring AM, Electrochem. Soc. Interface, 24, 51 (2015)
Bandosz TJ, Petit C, J. Colloid Interface Sci., 338(2), 329 (2009)
Ghauri M, Tahir M, Abbas T, Khurram MS, Shehzad K, Sci. Int., 24, 411 (2012)
Goncalves M, Sanchez-Garcia L, Jardim EDO, Silvestre-Albero J, Rodriguez-Reinoso F, Environ. Sci. Technol., 45, 10605 (2011)
Guo J, Xu WS, Chen YL, Lua AC, J. Colloid Interface Sci., 281(2), 285 (2005)
Huang CC, Li HS, Chen CH, J. Hazard. Mater., 159(2-3), 523 (2008)
Kim SD, Magnone E, Park JH, Ryu JY, J. Porous Mat., 25, 297 (2018)
Rieth AJ, Dinca M, J. Am. Chem. Soc., 140(9), 3461 (2018)
Seredych M, Petit C, Tamashausky AV, Bandosz TJ, Carbon, 47, 445 (2009)
Chen Y, Zhang F, Wang Y, Yang C, Yang J, Li J, Microporous Mesoporous Mater., 258, 170 (2018)
Khabzina Y, Farrusseng D, Microporous Mesoporous Mater., 265, 143 (2018)
Qajar A, Peer M, Andalibi MR, Rajagopalan R, Foley HC, Microporous Mesoporous Mater., 218, 15 (2015)
Molina L, Hammer B, Phys. Rev. B, 69, 155424 (2004)
de Farias AMD, Barandas APMG, Perez RF, Fraga MA, J. Power Sources, 165(2), 854 (2007)
Park JH, Baek JH, Hwang RH, Yi KB, Clean Technol., 23(4), 429 (2017)
Baek JI, Ryu J, Lee JB, Eom TH, Kim KS, Yang SR, Ryu CK, Energy Procedia, 4, 349 (2011)
Zhao M, Minett AI, Harris AT, Energy Environ. Sci., 6, 25 (2013)
Choudhary VR, Uphade BS, Mamman AS, Catal. Lett., 32(3-4), 387 (1995)
Iriondo A, Barrio V, Cambra J, Arias P, Guemez M, Navarro R, Sanchez-Sanchez M, Fierro J, Top. Catal., 49, 46 (2008)
Parmaliana A, Arena F, Frusteri F, Coluccia S, Marchese L, Martra G, Chuvilin A, J. Catal., 141, 34 (1993)
Silva WM, Ribeiro H, Seara LM, Calado HD, Ferlauto AS, Paniago RM, Leite CF, Silva GG, J. Braz. Chem. Soc., 23, 1078 (2012)
Tian X, Hong G, Liu Y, Jiang B, Yang Y, RSC Adv., 4, 36316 (2014)
Al Amer AM, Laoui T, Abbas A, Al-Aqeeli N, Patel F, Khraisheh M, Atieh MA, Hilal N, Mater. Des., 89, 549 (2016)
Baek JH, Jeong JM, Park JH, Yi KB, Rhee YW, Trans. Korean Hydrog. New Energy Soc., 26, 423 (2015)
Jeong JM, Park JH, Baek JH, Hwang RH, Jeon SG, Yi KB, Korean J. Chem. Eng., 34(1), 81 (2017)
Wu Z, Jin R, Liu Y, Wang H, Catal. Commun., 9, 2217 (2008)
