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Received December 16, 2019
Accepted March 13, 2020
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Gas-phase dehydration of glycerol to acrolein over different metal phosphate catalysts
School of Materials and Chemical Engineering, Chuzhou University, Chuzhou, Anhui 239000, China 1School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
matianlin951@sina.com
Korean Journal of Chemical Engineering, June 2020, 37(6), 955-960(6), 10.1007/s11814-020-0541-2
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Abstract
We conducted a comparative study of gas phase dehydration of glycerol to acrolein over aluminium phosphate, iron phosphate and nickel phosphate catalysts prepared by a simple replacement reaction method (AlP, FeP and NiP). The textural properties, acid amounts, acid types, and coke contents of the samples were studied. The results showed that all metal phosphate catalysts remained in an amorphous state. The glycerol conversion was proportional to the acid amount of metal phosphate catalyst in the glycerol dehydration reaction. Higher value of B/L was more likely to produce acrolein. Among the metal phosphate catalysts, FeP showed superior performance due to its suitable textural and acid properties. After 2 h on stream, high glycerol conversion (96%), acrolein selectivity (82%) and acrolein yield (79%) were achieved on the FeP catalyst at 280 °C. The catalyst deactivation was ascribed to carbon deposition on the catalyst surface blocking the active sites during the glycerol dehydration reaction.
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References
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