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Received November 26, 2019
Accepted March 26, 2020
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Reducible oxide (CeO2, ZrO2, and CeO2-ZrO2) promoted Ni-MgO catalysts for carbon dioxide reforming of methane reaction
Beom-Jun Kim
Kyung-Won Jeon1
Hyun-Suk Na
Yeol-Lim Lee
Seon-Yong Ahn
Kyoung-Jin Kim
Won-Jun Jang1
Jae-Oh Shim†
Hyun-Seog Roh†
Department of Environmental Engineering, Yonsei University, 1 Yonseidae-gil, Wonju, Gangwon 26493, Korea 1Department of Environmental and Energy Engineering, Kyungnam University, 7 Kyungnamdaehak-ro, Changwon-si, Gyeongsangnam-do 51767, Korea
Korean Journal of Chemical Engineering, July 2020, 37(7), 1130-1136(7), 10.1007/s11814-020-0551-0
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Abstract
Ni-MgO catalysts have been widely applied for carbon dioxide reforming (CDR) reaction due to their ability of anti-carbon formation. However, activation of Ni-MgO catalyst consumes considerable energy because of its very low reducibility. In this study, ZrO2, CeO2, and CeO2-ZrO2 promoted Ni-MgO catalysts were prepared via a facile coprecipitation method and applied to the CDR reaction. Among the prepared catalysts, the ZrO2-promoted Ni-MgO catalyst showed the highest methane conversion. The high catalytic performance of the ZrO2-promoted Ni-MgO catalyst is mainly due to easier reducibility, high Ni dispersion, and high specific surface area.
Keywords
References
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Ashcroft AT, Cheetham AK, Green MLH, Vernon PDF, Nature, 352, 225 (1991)
Rahemi N, Haghighi M, Babaluo AA, Jafari MF, Allahyari S, Korean J. Chem. Eng., 31(9), 1553 (2014)
Valderrama G, Kiennemann A, Goldwasser MR, J. Power Sources, 195(7), 1765 (2010)
Ozkara-Aydinoglu S, Int. J. Hydrog. Energy, 35(23), 12821 (2010)
Bradford MCJ, Vannice MA, J. Catal., 173(1), 157 (1998)
Roh HS, Jun KW, Catal. Surv. Asia, 12, 239 (2008)
Roh HS, Potdar HS, Jun KW, Catal. Today, 93, 39 (2004)
Roh HS, Potdar HS, Jun KW, Kim JW, Oh YS, Appl. Catal. A: Gen., 276(1-2), 231 (2004)
Shiraz MHA, Rezaei M, Meshkani F, Korean J. Chem. Eng., 33(12), 3359 (2016)
Wei JM, Iglesia E, J. Catal., 224(2), 370 (2004)
Wei JM, Iglesia E, J. Phys. Chem. B, 108(13), 4094 (2004)
Wei J, Iglesia E, Phys. Chem. Chem. Phys., 6, 3754 (2004)
Wei JM, Iglesia E, J. Catal., 225(1), 116 (2004)
Wei JM, Iglesia E, J. Phys. Chem. B, 108(22), 7253 (2004)
Theofanidis SA, Galvita VV, Poelman H, Marin GB, ACS Catal., 5, 3028 (2015)
Koo KY, Roh HS, Seo YT, Seo DJ, Yoon WL, Bin Park S, Appl. Catal. A: Gen., 340(2), 183 (2008)
Jun KW, Roh HS, Chary KVR, Catal. Surv. Asia, 11, 97 (2007)
Hu YH, Ruckenstein E, J. Catal., 184(1), 298 (1999)
Wang YH, Liu HM, Xu BQ, J. Mol. Catal. A-Chem., 299(1-2), 44 (2009)
Hu YH, Ruckenstein E, Langmuir, 13(7), 2055 (1997)
Hu YH, Ruckenstein E, Catal. Rev., 44, 423 (2002)
Jang WJ, Shim JO, Kim HM, Yoo SY, Roh HS, Catal. Today, 324, 15 (2019)
Shim JO, Jang WJ, Jeon KW, Lee DW, Na HS, Kim HM, Lee YL, Yoo SY, Jeon BH, Roh HS, Ko CH, Appl. Catal. A: Gen., 563, 163 (2018)
Wang SB, Lu GQ, Appl. Catal. B: Environ., 19(3-4), 267 (1998)
Zhang S, Muratsugu S, Ishiguro N, Tada M, ACS Catal., 3, 1855 (2013)
Debek R, Galvez ME, Launay F, Motak M, Grzybek T, Costa PD, Int. J. Hydrog. Energy, 41, 11611 (2016)
Yao L, Zhu JQ, Peng XX, Tong DM, Hu CW, Int. J. Hydrog. Energy, 38(18), 7268 (2013)
Liu DP, Quek XY, Cheo WNE, Lau R, Borgna A, Yang YH, J. Catal., 266(2), 380 (2009)
Faria EC, Neto RCR, Colman RC, Noronha FB, Catal. Today, 228, 138 (2014)
Shanmugam V, Zapf R, Neuberg S, Hessel V, Kolb G, Appl. Catal. B: Environ., 203, 859 (2017)
Hutchings GJ, Vedrine JC, Heterogeneous catalyst preparation, Springer Berlin Heidelberg, Berlin, Heidelberg, 215 (2004).
Platon A, Roh HS, King DL, Top. Catal., 46, 374 (2007)
Al-Doghachi FAJ, Rashid U, Taufiq-Yap YH, RSC Adv., 6, 10372 (2016)
Luengnaruemitchai A, Pojanavaraphan C, Kumyam A, Thunyaratchatanon C, Gulari E, Int. J. Hydrog. Energy, 44(3), 1686 (2019)
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Roh HS, Jun KW, Dong WS, Chang JS, Park SE, Joe YI, J. Mol. Catal. A-Chem., 181(1-2), 137 (2002)
Kim HM, Jang WJ, Yoo SY, Shim JO, Jeon KW, Na HS, Lee YL, Jeon BH, Bae JW, Roh HS, Int. J. Hydrog. Energy, 43(1), 262 (2018)
Qian Y, Liang S, Wang T, Wang Z, Xie W, Xu X, Catal. Commun., 12, 851 (2011)
Choi IH, Hwang KR, Lee KY, Lee IG, Int. J. Hydrog. Energy, 44(1), 180 (2019)
Miyamoto M, Hamajima A, Oumi Y, Uemiya S, Int. J. Hydrog. Energy, 43(2), 730 (2018)
Rezaei M, Alavi SM, Int. J. Hydrog. Energy, 44(31), 16516 (2019)
Debek R, Radlik M, Motak M, Galvez ME, Turek W, Da Costa P, Grzybek T, Catal. Today, 257, 59 (2015)
Yang Y, Liu J, Shen WF, Li J, Chien IL, Energy, 158, 820 (2018)
Khajenoori M, Rezaei M, Meshkani F, Chem. Eng. Technol., 37(6), 957 (2014)
Meshkani F, Rezaei M, Andache M, J. Ind. Eng. Chem., 20(4), 1251 (2014)
Usman M, Daud WMAW, RSC Adv., 6, 38277 (2016)
