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Received January 7, 2020
Accepted March 20, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Ethylenediamine-incorporated MIL-101(Cr)-NH2 metal-organic frameworks for enhanced CO2 adsorption
Department of Chemical Engineering, Industrial University of Ho Chi Minh City, Ho Chi Minh City, 12 Nguyen Van Bao, Go Vap, Ho Chi Minh City, Vietnam 1Department of Chemical Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, Korea
jkim21@khu.ac.kr
Korean Journal of Chemical Engineering, July 2020, 37(7), 1206-1211(6), 10.1007/s11814-020-0548-8
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Abstract
Ethylenediamine (EA)-incorporated MIL-101(Cr)-NH2 adsorbents were prepared for CO2 adsorption. First, MIL-101(Cr)-NH2 was directly prepared by the solvothermal method, followed by the EA incorporation inside the pores of MIL-101(Cr)-NH2. The prepared samples were characterized by N2 porosimetry, field-emission scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectrometry, thermogravimetric, and powder X-ray diffraction analyses. The effects of ethylenediamine loading in MIL-101(Cr)-NH2 on the CO2 adsorption capability were systematically investigated. EA-incorporated MIL-101(Cr)-NH2 showed CO2 adsorption capacity of ca. 3.4mmol/g, which was ~62% higher than the pristine MIL-101(Cr)-NH2. In addition, the amine-grafted MOF samples showed good regenerability and stability after consecutive adsorption-desorption cycles at ambient conditions. These suggest that introduction of alkylamine molecules into the pores of metal-organic frameworks can be a promising strategy to improve the CO2 soprtion ability of MOFs.
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