Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received September 10, 2019
Accepted March 16, 2020
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Nitrogen and sulfur dual-doped porous carbon derived from coffee waste and cysteine for electrochemical energy storage
Jumi Hong1 2
Harim Kim3
Ji Eun Lee1
You Na Ko1
Ki Tae Park1
Young Eun Kim1
Min Hye Youn1
Soon Kwan Jeong1
Jinwon Park2†
Wonhee Lee1†
1Climate Change Research Division, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Korea 2School of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Korea 3Department of Chemistry, College of Natural Sciences, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Korea
Korean Journal of Chemical Engineering, July 2020, 37(7), 1218-1225(8), 10.1007/s11814-020-0544-z
Download PDF
Abstract
N/S dual-doped carbon materials were synthesized from coffee waste and cysteine for use as porous carbon electrode materials for electric double layer capacitors. The capacitance of the carbon materials was calculated from the experimental results of cyclic voltammetry and galvanostatic charge-discharge tests. The N/S-doped carbon materials obtained from heat-treatment with cysteine exhibited a higher discharge capacitance, 71.3 F/g, than that of the carbon without the cysteine treatment, 43.8 F/g, at 1 A/g. This is because the N/S dual-doped carbons possess a higher wettability than that of the other carbon material, even though the N/S doping with cysteine destroys the porous carbon structure, which reduces the BET surface area of the carbon samples. Elemental analysis was performed to determine the portions of nitrogen and sulfur elements doped into the carbon. From the XPS results, various states of nitrogen and sulfur elements were identified, and SEM/TEM images were obtained to observe their morphologies and porous structures.
References
Pandolfo AG, Hollenkamp AF, J. Power Sources, 157(1), 11 (2006)
Stoller MD, Ruoff RS, J. Energy Environ. Sci., 3, 1294 (2010)
Hao L, Li XL, Zhi LJ, Adv. Mater., 25(28), 3899 (2013)
Conway BE, Electrochemical supercapacitors: Scientific fundamentals and technological applications, Plenum Press, New York (1999).
Simon P, Gogotsi Y, Nat. Mater., 7, 845 (2008)
Kim YJ, Lee BJ, Suezaki H, Chino T, Abe Y, Yanagiura T, Park KC, Endo M, Carbon, 44, 1592 (2006)
Lee W, Kwon M, Park S, Lim D, Cha JH, Lee H, Chem.- Asian J., 8, 1569 (2013)
Lee KS, Park M, Choi S, Kim JD, Colloids Surf. A: Physicochem. Eng. Asp., 529, 107 (2017)
Kwon SH, Lee E, Kim BS, Kim SG, Lee BJ, Kim MS, Jung JC, Korean J. Chem. Eng., 32(2), 248 (2015)
Yang I, Kwon D, Kim MS, Jung JC, Carbon, 132, 503 (2018)
Shinde NM, Jagadale AD, Kumbhar VS, Rana TR, Kim JH, Lokhande CD, Korean J. Chem. Eng., 32(5), 974 (2015)
Venugopal N, Kim WS, Korean J. Chem. Eng., 32(9), 1918 (2015)
Lee WJ, Jeong SM, Lee H, Kim BJJ, An KH, Park YK, Jung SC, Korean J. Chem. Eng., 34(11), 2993 (2017)
Banerjee J, Dutta K, Kader MA, Nayak SK, Polym. Adv. Technol., 30, 1902 (2019)
Tian YY, Yang C, Song XF, Liu J, Zhao LP, Zhang P, Gao L, Chem. Eng. J., 374, 59 (2019)
Paraknowitsch JP, Thomas A, J. Energy Environ. Sci., 6, 2839 (2013)
Kim Y, Lee W, Kim GM, Lee JW, RSC Adv., 6, 54889 (2016)
Lee W, Kim GM, Baik S, Lee JW, Electrochim. Acta, 210, 743 (2016)
Byeon A, Lee W, Kim GM, Lee JW, J. CO2 Util., 16, 420 (2016)
Yang ZC, Xie LQ, Chen YT, Xue T, Ma B, Zhang KL, Zhao JS, Wei J, Appl. Surf. Sci., 493, 1205 (2019)
Yun YS, Park MH, Hong SJ, Lee ME, Park YW, Jin HJ, ACS Appl. Mater. Interfaces, 7, 3684 (2015)
Unni SM, George L, Bhange SN, Devi RN, Kurungot S, RSC Adv., 6, 82103 (2016)
Chung DY, Son YJ, Yoo JM, Kang JS, Ahn CY, Park S, Sung YE, ACS Appl. Mater. Interfaces, 9, 41303 (2017)
Jiang L, Sheng L, Fan Z, Sci. China Mater., 61, 133 (2018)
Srinu A, Peera SG, Parthiban V, Bhuvaneshwari B, Sahu AK, Chem Select, 3, 690 (2018)
Misnon II, Zain NKM, Jose R, Waste Biomass Valoriz., 10, 1731 (2019)
Campos-Vega R, Loarca-Pina G, Vergara-Castaneda HA, Oomah BD, Trends Food Sci. Technol., 45, 24 (2015)
Zhang J, Xia Z, Dai L, Sci. Adv., 1, e15005 (2015)
Niu S, Lv W, Zhou G, He Y, Li B, Yang QH, Kang F, Chem. Commun., 51, 17720 (2015)
Zhang HH, Niu YL, Hu WH, J. Colloid Interface Sci., 505, 32 (2017)
Wu ZS, Ren W, Xu L, Li F, Cheng HM, ACS Nano, 5, 463 (2011)
Liu J, Poh CK, Zhan D, Lai L, Lim SH, Wang L, Liu X, Sahoo NG, Li C, Shen Z, Lin J, Nano Energy, 2, 377 (2013)
Wu J, Pan Z, Zhang Y, Wang B, Peng H, J. Mater. Chem. A, 6, 12932 (2018)
Kicinski W, Szala M, Bystrzejewski M, Carbon, 68, 1 (2014)
Yan J, Wang Q, Wei T, Fan Z, Adv. Eng. Mater., 4, 130081 (2014)
Wang T, Zhang P, Sun Y, Liu B, Liu Y, Qiao ZA, Huo Q, Dai S, Chem. Mater., 29, 4044 (2017)
Wang T, Sun Y, Zhang L, Li K, Yi Y, Song S, Li M, Qiao ZA, Dai S, Adv. Mater., 31, 180787 (2019)
Quan B, Yu SH, Chung DY, Jin A, Park JH, Sung YE, Piao Y, Sci. Rep., 4, 5639 (2014)
Kim C, Lee JW, Kim JH, Yang KS, Korean J. Chem. Eng., 23(4), 592 (2006)
Yuan D, Chen J, Zeng J, Tan S, Electrochem. Commun., 10, 1067 (2008)
Stoller MD, Ruoff RS, J. Energy Environ. Sci., 3, 1294 (2010)
Hao L, Li XL, Zhi LJ, Adv. Mater., 25(28), 3899 (2013)
Conway BE, Electrochemical supercapacitors: Scientific fundamentals and technological applications, Plenum Press, New York (1999).
Simon P, Gogotsi Y, Nat. Mater., 7, 845 (2008)
Kim YJ, Lee BJ, Suezaki H, Chino T, Abe Y, Yanagiura T, Park KC, Endo M, Carbon, 44, 1592 (2006)
Lee W, Kwon M, Park S, Lim D, Cha JH, Lee H, Chem.- Asian J., 8, 1569 (2013)
Lee KS, Park M, Choi S, Kim JD, Colloids Surf. A: Physicochem. Eng. Asp., 529, 107 (2017)
Kwon SH, Lee E, Kim BS, Kim SG, Lee BJ, Kim MS, Jung JC, Korean J. Chem. Eng., 32(2), 248 (2015)
Yang I, Kwon D, Kim MS, Jung JC, Carbon, 132, 503 (2018)
Shinde NM, Jagadale AD, Kumbhar VS, Rana TR, Kim JH, Lokhande CD, Korean J. Chem. Eng., 32(5), 974 (2015)
Venugopal N, Kim WS, Korean J. Chem. Eng., 32(9), 1918 (2015)
Lee WJ, Jeong SM, Lee H, Kim BJJ, An KH, Park YK, Jung SC, Korean J. Chem. Eng., 34(11), 2993 (2017)
Banerjee J, Dutta K, Kader MA, Nayak SK, Polym. Adv. Technol., 30, 1902 (2019)
Tian YY, Yang C, Song XF, Liu J, Zhao LP, Zhang P, Gao L, Chem. Eng. J., 374, 59 (2019)
Paraknowitsch JP, Thomas A, J. Energy Environ. Sci., 6, 2839 (2013)
Kim Y, Lee W, Kim GM, Lee JW, RSC Adv., 6, 54889 (2016)
Lee W, Kim GM, Baik S, Lee JW, Electrochim. Acta, 210, 743 (2016)
Byeon A, Lee W, Kim GM, Lee JW, J. CO2 Util., 16, 420 (2016)
Yang ZC, Xie LQ, Chen YT, Xue T, Ma B, Zhang KL, Zhao JS, Wei J, Appl. Surf. Sci., 493, 1205 (2019)
Yun YS, Park MH, Hong SJ, Lee ME, Park YW, Jin HJ, ACS Appl. Mater. Interfaces, 7, 3684 (2015)
Unni SM, George L, Bhange SN, Devi RN, Kurungot S, RSC Adv., 6, 82103 (2016)
Chung DY, Son YJ, Yoo JM, Kang JS, Ahn CY, Park S, Sung YE, ACS Appl. Mater. Interfaces, 9, 41303 (2017)
Jiang L, Sheng L, Fan Z, Sci. China Mater., 61, 133 (2018)
Srinu A, Peera SG, Parthiban V, Bhuvaneshwari B, Sahu AK, Chem Select, 3, 690 (2018)
Misnon II, Zain NKM, Jose R, Waste Biomass Valoriz., 10, 1731 (2019)
Campos-Vega R, Loarca-Pina G, Vergara-Castaneda HA, Oomah BD, Trends Food Sci. Technol., 45, 24 (2015)
Zhang J, Xia Z, Dai L, Sci. Adv., 1, e15005 (2015)
Niu S, Lv W, Zhou G, He Y, Li B, Yang QH, Kang F, Chem. Commun., 51, 17720 (2015)
Zhang HH, Niu YL, Hu WH, J. Colloid Interface Sci., 505, 32 (2017)
Wu ZS, Ren W, Xu L, Li F, Cheng HM, ACS Nano, 5, 463 (2011)
Liu J, Poh CK, Zhan D, Lai L, Lim SH, Wang L, Liu X, Sahoo NG, Li C, Shen Z, Lin J, Nano Energy, 2, 377 (2013)
Wu J, Pan Z, Zhang Y, Wang B, Peng H, J. Mater. Chem. A, 6, 12932 (2018)
Kicinski W, Szala M, Bystrzejewski M, Carbon, 68, 1 (2014)
Yan J, Wang Q, Wei T, Fan Z, Adv. Eng. Mater., 4, 130081 (2014)
Wang T, Zhang P, Sun Y, Liu B, Liu Y, Qiao ZA, Huo Q, Dai S, Chem. Mater., 29, 4044 (2017)
Wang T, Sun Y, Zhang L, Li K, Yi Y, Song S, Li M, Qiao ZA, Dai S, Adv. Mater., 31, 180787 (2019)
Quan B, Yu SH, Chung DY, Jin A, Park JH, Sung YE, Piao Y, Sci. Rep., 4, 5639 (2014)
Kim C, Lee JW, Kim JH, Yang KS, Korean J. Chem. Eng., 23(4), 592 (2006)
Yuan D, Chen J, Zeng J, Tan S, Electrochem. Commun., 10, 1067 (2008)
