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Received September 30, 2019
Accepted May 11, 2020
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Glass ceramic coating on LiNi0.8Co0.1Mn0.1O2 cathode for Li-ion batteries
Hyeong Seop Kang
Palanisamy Santhoshkumar
Jae Woo Park
Gyu Sang Sim
Murugan Nanthagopal
Chang Woo Lee†
Department of Chemical Engineering & Center for the SMART Energy Platform, College of Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung, Yongin, Gyeonggi 17104, Korea
cwlee@khu.ac.kr
Korean Journal of Chemical Engineering, August 2020, 37(8), 1331-1339(9), 10.1007/s11814-020-0570-x
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Abstract
Alleviating the surface degradation of Ni-rich cathode materials is desirable to achieve better electrochemical performance. Herein, we report the surface coating of lithium diborate (Li2O-2B2O3) over the Ni-rich LiNi0.8Co0.1Mn0.1O2 (NCM811) cathode material and the systematic investigation of its electrochemical properties. The structural and morphological properties were characterized through X-ray diffraction (XRD), high resolution field-emission scanning electron microscopy (HR FE-SEM), and high resolution field-emission transmission electron microscopy (HR FE-TEM). As a cathode material for Li-ion batteries, the 1.0 wt% Li2O-2B2O3 coated NCM811 exhibits better electrochemical properties than the bare NCM811 as well as 0.5 and 2wt% coated electrodes at room and elevated temperatures (60 °C ). The improved electrochemical performance of 1.0 wt% Li2O-2B2O3 coated NCM811 might be due to the optimal coating amount that promotes better ion and electron movement along with prevention of surface degradation.
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Liang C, Kong F, Longo RC, Santosh KC, Kim JS, Jeon SH, Choi SA, Cho K, J. Phys. Chem. C, 120, 6383 (2016)
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Dixit M, Markovsky B, Schipper F, Aurbach D, Major DT, J. Phys. Chem. C, 121, 22682 (2017)
Mezaal MA, Qu L, Li G, Liu W, Zhao X, Fan Z, Lei L, J. Solid State Electrochem., 21, 2219 (2017)
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Zhu W, Huang X, Liu T, Xie Z, Wang Y, Tian K, Bu L, Wang H, Gao L, Zhao J, Coatings, 9, 92 (2019)
