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Received March 26, 2020
Accepted June 4, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Composition-dependent catalytic activity of bimetallic PtPd dendrimer-encapsulated nanoparticles having an average size of 1.7 nm for hydrolytic dehydrogenation of ammonia borane
Department of Chemistry, Research Institute for Basic Sciences, KHU-KIST Department of Converging Science and Technology, Kyung Hee University, Seoul 02447, Korea
jkim94@khu.ac.kr
Korean Journal of Chemical Engineering, August 2020, 37(8), 1387-1393(7), 10.1007/s11814-020-0604-4
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Abstract
We investigated composition-dependent catalytic activity of bimetallic PtPd dendrimer-encapsulated nanoparticles (DENs) that had a uniform size of ~1.7 nm for hydrolytic dehydrogenation of ammonia borane (AB). The PtPd DENs, composed of seven different Pt : Pd ratios, were synthesized using hydroxyl-terminated sixth-generation polyamidoamine dendrimers as a molecular template. The dendrimer-templating method allowed for synthesizing bimetallic PtPd DENs with controllable nanoparticle composition while fixing the size of the nanoparticles uniformly at ~1.7 nm. Compared with monometallic Pt and Pd DENs, the bimetallic PtPd DENs showed superior catalytic activity for the hydrolytic dehydrogenation of AB. Furthermore, the bimetallic PtPd DENs exhibited composition-dependent activity with the maximum activity (i.e., average turnover frequency=108.5 ± 15.9mol H2ㆍmol atomPt+Pd_x000D_
-1ㆍmin-1) at a Pt : Pd ratio of 1 : 1 for the catalytic hydrolysis of AB.
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References
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Crooks RM, Zhao M, Sun L, Chechik V, Yeung LK, Accounts Chem. Res., 34, 181 (2001)
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Lim H, Ju Y, Kim J, Anal. Chem., 88, 4751 (2016)
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