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Received April 1, 2020
Accepted May 11, 2020
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Hydrogen storage into monobenzyltoluene over Ru catalyst supported on SiO2-ZrO2 mixed oxides with different Si/Zr ratios
1Department of Chemical Engineering, Hanyang University, Seoul 04763, Korea 2Department of Chemical Engineering, Chungbuk National University, Chungbuk 28644, Korea 3Research Institute of Industrial Science, Hanyang University, Seoul 04763, Korea
Korean Journal of Chemical Engineering, August 2020, 37(8), 1427-1435(9), 10.1007/s11814-020-0577-3
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Abstract
Supported Ru catalysts have been often employed for hydrogen charge into liquid organic hydrogen carrier molecules (monobenzyltoluene in this work), and their catalytic performance largely depends upon physicochemical properties of the support materials. We prepared supported Ru catalysts on SiO2-ZrO2 with different Si/(Si+Zr) ratios ranging from 0 to 30mol% by loading Ru3(CO)12 onto Si,Zr-mixed metal hydroxide and subsequent thermolysis. The textural properties, Ru particle size, and hydrogenation activity of Ru/SiO2-ZrO2 catalysts show a volcanoshaped dependence on the content of Si added, where the maximum is achieved at the Si/(Si+Zr) ratio of 5mol%. Up to this Si content the incorporation of Si into ZrO2 improves thermal stability and decreases the particle size of tetragonal ZrO2, resulting in a positive contribution to hydrogen storage efficiency. However, the further addition of Si increases surface heterogeneity and charge imbalance, and hence induces a decrease in the density of surface OH group reacting with Ru3(CO)12, which explains the lowered activity. Therefore, the addition of up to 5mol% Si into ZrO2 is effective in enhancing the hydrogenation performance of Ru/ZrO2 owing to the improved textural properties and smaller Ru particles.
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References
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Kongwudthiti S, Praserthdam P, Tanakulrungsank W, Inoue M, J. Mater. Process. Technol., 136, 186 (2003)
Kuwahara Y, Kaburagi W, Nemoto K, Fujitani T, Appl. Catal. A: Gen., 476, 186 (2014)
Monros G, Marti MC, Carda J, Tena MA, Escribano P, Anglada M, J. Mater. Sci., 28, 5852 (1993)
Miller JB, Ko EI, J. Catal., 159(1), 58 (1996)
del Monte F, Larsen W, Mackenzie JD, J. Am. Ceram. Soc., 83(3), 628 (2000)
Nagarajan VS, Rao KJ, J. Mater. Sci., 24, 2140 (1989)
Goodwin JG, Naccache C, Appl. Catal., 4, 145 (1982)
Lamb HH, Gates BC, Knozinger H, Angew. Chem.-Int. Edit., 27, 1127 (1988)
Lee JW, Kong S, Kim WS, Kim J, Mater. Chem. Phys., 106(1), 39 (2007)
Ren CJ, Qiu W, Chen YQ, Sep. Purif. Technol., 107, 264 (2013)
Lee JH, Shin CH, Suh YW, Mol. Catal., 438, 272 (2017)
Flego C, Carluccio L, Rizzo C, Perego C, Catal. Commun., 2, 43 (2001)
Preuster P, Papp C, Wasserscheid P, Accounts Chem. Res., 50, 74 (2017)
Aaldto-Saksa PT, Cook C, Kiviaho J, Repo T, J. Power Sources, 396, 803 (2018)
Sievi G, Geburtig D, Skeledzic T, Bosmann A, Preuster P, et al., Energy Environ. Sci., 12, 2305 (2019)
Muller K, Thiele S, Wasserscheid P, Energy Fuels, 33(10), 10324 (2019)
Markiewicz M, Zhang YQ, Bosmann A, Bruckner N, Thoming J, Wasserscheid P, Stolte S, Energy Environ. Sci., 8, 1035 (2015)
Jorschick H, Preuster P, Durr S, Seidel A, Muller K, Bosmann A, Wasserscheid P, Energy Environ. Sci., 10, 1652 (2017)
Niermann M, Drunert S, Kaltschmitt M, Bonhoff K, Energy Environ. Sci., 12, 290 (2019)
Niermann M, Beckendorff A, Kaltschmitt M, Bonhoff K, Int. J. Hydrog. Energy, 44(13), 6631 (2019)
Modisha PM, Ouma CNM, Garidzirai R, Wasserscheid P, Bessarabov D, Energy Fuels, 33(4), 2778 (2019)
Bruckner N, Obesser K, Bosmann A, Teichmann D, Arlt W, Dungs J, Wasserscheid P, ChemSusChem, 7, 229 (2014)
Leinweber A, Muller K, Energy Technol., 6, 513 (2018)
Kim TW, Ko SH, Kim M, Suh YW, Adv. Powder Technol., 31, 1682 (2020)
Oh J, Kim TW, Jeong K, Park JH, Suh YW, ChemCatChem, 10, 3892 (2018)
Oh J, Bathula HB, Park JH, Suh YW, Commun. Chem., 2, 68 (2019)
Auer F, Blaumeiser D, Bauer T, Bosmann A, Szesni N, Libuda J, Wasserscheid P, Catal. Sci. Technol., 9, 3537 (2019)
Aakko-Saksa PA, Vehkamaki M, Kemell M, Keskivali L, Simell P, Reinikainen M, Tapper U, Repo T, Chem. Commun., 56, 1657 (2020)
Durr S, Muller M, Jorschick H, Helmin M, Bosmann A, Palkovits R, Wasserscheid P, ChemSusChem, 10, 42 (2017)
Jorschick H, Bosmann A, Preuster P, Wasserscheid P, ChemCatChem, 10, 4329 (2018)
Jorschick H, Bulgarin A, Alletsee L, Preuster P, Bosmann A, Wasserscheid P, ACS Sustainable Chem. Eng., 7, 4186 (2019)
Jorschick H, Vogl M, Preuster P, Bosmann A, Wasserscheid P, Int. J. Hydrog. Energy, 44(59), 31172 (2019)
Li LL, Yang M, Dong Y, Mei P, Cheng HS, Int. J. Hydrog. Energy, 41(36), 16129 (2016)
Oh J, Jeong K, Kim TW, Kwon H, Han JW, Park JH, Suh YW, ChemSusChem, 11, 661 (2018)
Jang M, Jo YS, Lee WJ, Shin BS, Sohn H, Jeong H, Jang SC, Kwak SK, Kang JW, Yoon CW, ACS Sustainable Chem. Eng., 7, 1185 (2019)
Alvarez-Rodriguez J, Guerrero-Ruiz A, Rodriguez-Ramos I, Arcoya-Martin A, Catal. Today, 107-108, 302 (2005)
Kim TW, Park S, Oh J, Shin CH, Suh YW, ChemCatChem, 10, 3406 (2018)
Kuznetsov VL, Bell AT, Yermakov YI, J. Catal., 65, 374 (1980)
Zecchina A, Guglielminotti E, Bossi A, Camia M, J. Catal., 74, 225 (1982)
Basset JM, Choplin A, J. Mol. Catal., 21, 95 (1983)
Asakura K, Bando KK, Iwasawa Y, J. Chem. Soc.-Faraday Trans., 86(14), 2645 (1990)
Asakura K, Iwasawa Y, J. Chem. Soc.-Faraday Trans., 86(14), 2657 (1990)
Kim TW, Oh J, Suh YW, Appl. Catal. A: Gen., 547, 183 (2017)
Bhaskar T, Reddy KR, Kumar CP, Murthy MRVS, Chary KVR, Appl. Catal. A: Gen., 211(2), 189 (2001)
Zhou G, Tan X, Pei Y, Fan K, Qiao M, Sun B, Zong B, ChemCatChem, 5, 2425 (2013)
Rao D, Xue X, Cui G, He S, Xu M, Bing W, Shi S, Wei M, Catal. Sci. Technol., 8, 236 (2018)
Rupperta AM, Niewiadomski M, Grams J, Kwaphiski W, Appl. Catal. B: Environ., 145, 85 (2014)
Hong E, Kim C, Lim DH, Cho HJ, Shin CH, Appl. Catal. B: Environ., 232, 544 (2018)
Bosman HJ, Kruissink EC, Vanderspoel J, Vandenbrink F, J. Catal., 148(2), 660 (1994)
del Monte F, Larsen W, Mackenzie JD, J. Am. Ceram. Soc., 83(6), 1506 (2000)
Aguilar DH, Torres-Gonzalez LC, Torres-Martinez LM, Lopez T, Quintana P, J. Solid State Chem., 158, 349 (2000)
Pyen S, Hong E, Shin M, Suh YW, Shin CH, Mol. Catal., 448, 71 (2018)
Han LP, Mao DS, Yu J, Guo QS, Lu GZ, Appl. Catal. A: Gen., 454, 81 (2013)
Gu J, Xin Z, Tao M, Lv YH, Gao WL, Si Q, Appl. Catal. A: Gen., 575, 230 (2019)
Reddy GK, Loridant S, Takahashi A, Delichere P, Reddy BM, Appl. Catal. A: Gen., 389(1-2), 92 (2010)
Stolze B, Titus J, Schunk SA, Milanov A, Schwab E, Glaser R, Front. Chem. Sci. Eng., 10(2), 281 (2016)
Zhang XH, Zhang Q, Wang TJ, Ma LL, Yu YX, Chen LG, Bioresour. Technol., 134, 73 (2013)
Foraita S, Liu Y, Haller GL, Barath E, Zhao C, Lercher JA, ChemCatChem, 9, 195 (2017)
Perera G, Doremus RH, J. Am. Ceram. Soc., 74(7), 1554 (1991)
Sato S, Takahashi R, Sodesawa T, Tanaka S, Oguma K, Ogura K, J. Catal., 196(1), 190 (2000)
Damyanova S, Grange P, Delmon B, J. Catal., 168(2), 421 (1997)
Wang WJ, Zhou J, Wei D, Wan HQ, Zheng SR, Xu ZY, Zhu DQ, J. Colloid Interface Sci., 407, 442 (2013)
Lopez T, Navarrete J, Gomez R, Novaro O, Figueras F, Armendariz H, Appl. Catal. A: Gen., 125(2), 217 (1995)
Kongwudthiti S, Praserthdam P, Tanakulrungsank W, Inoue M, J. Mater. Process. Technol., 136, 186 (2003)
Kuwahara Y, Kaburagi W, Nemoto K, Fujitani T, Appl. Catal. A: Gen., 476, 186 (2014)
Monros G, Marti MC, Carda J, Tena MA, Escribano P, Anglada M, J. Mater. Sci., 28, 5852 (1993)
Miller JB, Ko EI, J. Catal., 159(1), 58 (1996)
del Monte F, Larsen W, Mackenzie JD, J. Am. Ceram. Soc., 83(3), 628 (2000)
Nagarajan VS, Rao KJ, J. Mater. Sci., 24, 2140 (1989)
Goodwin JG, Naccache C, Appl. Catal., 4, 145 (1982)
Lamb HH, Gates BC, Knozinger H, Angew. Chem.-Int. Edit., 27, 1127 (1988)
Lee JW, Kong S, Kim WS, Kim J, Mater. Chem. Phys., 106(1), 39 (2007)
Ren CJ, Qiu W, Chen YQ, Sep. Purif. Technol., 107, 264 (2013)
Lee JH, Shin CH, Suh YW, Mol. Catal., 438, 272 (2017)
Flego C, Carluccio L, Rizzo C, Perego C, Catal. Commun., 2, 43 (2001)
