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Received February 9, 2020
Accepted April 30, 2020
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Preparation of CO2 adsorbent with N1-(3-(trimethoxysilyl)propyl)-1,3- propanediamine and its performance
Department of Chemical Engineering, Kongju National University, 1223-24 Cheonan-daero, Seobuk-gu, Cheonan 31080, Korea
Korean Journal of Chemical Engineering, September 2020, 37(9), 1515-1521(7), 10.1007/s11814-020-0565-7
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Abstract
N1-(3-(trimethoxysilyl)propyl)-1,3-propanediamine (2NS-P), a diaminosilane having a propyl spacer between the two amino groups was successfully synthesized, and a CO2 adsorbent functionalized with 2NS-P was prepared via impregnation of it into silica. The adsorption performance and stability of 2NS-P/Kona95 were examined and compared to that of N1-(3-(trimethoxysilyl)propyl)ethane-1,2-diamine (2NS)/Kona95 having an ethyl spacer. 2NS-P/Kona95 exhibited better CO2 adsorption capacity and CO2/N efficiency. The adsorbents were subjected to ten cycles of temperature swing adsorption (TSA), demonstrating that stability of 2NS-P/Kona95 was better than that of 2NS/Kona95. The spent 2NS-P/Kona95 showed the absence of cyclic urea formation in FT-IR spectrum, explaining the better stability of 2NS-P/Kona95 than 2NS/Kona95.
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Pang SH, Lee LC, Sakwa-Novak MA, Liyely RP, Jones CW, J. Am. Chem. Soc., 139(10), 3627 (2017)
Pacia RM, Manianglung C, Ko YS, Catalysts, 9(11), 910 (2019)
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Chen CH, Shimon D, Lee JJ, Didas SA, Mehta AK, Sievers C, Jones CW, Hayes SE, Environ. Sci. Technol., 51, 6553 (2017)
