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- In relation to this article, we declare that there is no conflict of interest.
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Received August 3, 2020
Accepted October 7, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Copyright © KIChE. All rights reserved.
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Morphological improvement of CH3NH3PbI3 films using blended solvents for perovskite solar cells
School of Chemical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan 38541, Korea
Korean Journal of Chemical Engineering, January 2021, 38(1), 187-194(8), 10.1007/s11814-020-0694-z
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Abstract
Perovskite solar cells with the structure of glass/florine-doped tin oxide (FTO)/electron transfer layer (ETL)/ perovskite/hole transfer layer (HTL)/Ag were fabricated. The effects of blending solvents and thermal annealing on the surface morphology, structural, and optical properties of perovskite (CH3NH3PbI3) active layer were investigated. The active layer was optimized by adding 2-butanol (2-BTA) as an eco-friendly solvent into methyl ammonium iodide (MAI) solution used for spin coating on PbI2/(dimethylformamide (DMF)+dimethyl sulfoxide (DMSO)) film in the second step. The resulting morphology of CH3NH3PbI3 films was smooth and pinholes in the films were also reduced without change in the structure. The effects of thermal annealing on the surface morphology and structural properties of active layer were also studied. The fabricated device for the optimized condition showed the maximum power conversion efficiency (PCE) of ~8.6%.
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