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Received June 10, 2020
Accepted September 21, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Facile fabrication of copper oxide modified activated carbon composite for efficient CO2 adsorption
Shandong Key Laboratory of Reactions and Isolations of Muti-phase Liquid, College of Chemical Engineering, Qingdao University of Science & Technology, Qingdao, 266042, China 1Fundamental Chemistry Experiment Center (Gaomi), Qingdao University of Science & Technology, Gaomi, 261500, China
feigao@tju.edu.cn
Korean Journal of Chemical Engineering, January 2021, 38(1), 46-54(9), 10.1007/s11814-020-0684-1
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Abstract
Copper oxide modified activated carbon (CuO/AC) composites for the CO2 capture were synthesized via a facile assembly strategy associated with a direct solid-state heat dispersion process by introducing CuO into AC using Cu(NO3)2 as the copper source. The synthesized CuO/AC composites with various CuO contents were characterized by powder X-ray diffraction, scanning electron microscopy and nitrogen adsorption-desorption measurement, and the CO2 adsorption performance was investigated. The characterization results indicate that the Cu(NO3)2 species was well dispersed into the AC pore channels and then converted to a highly dispersed CuO after the activation process. The adsorption results reveal that the CO2 adsorption performance can be significantly improved by introducing CuO onto the AC surfaces, and the CuO(0.6)/AC composite with a CuO loading of 0.6mmol/g AC shows a high CO2 adsorption capacity and adsorption selectivity and displays an excellent reversibility. Additionally, the calculated adsorption heat values of CO2 on the CuO(0.6)/AC composite are in the range of 27.3 to 33.9 kJ/mol.
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Raganati F, Ammendola P, Chirone R, Sep. Purif. Technol., 167, 24 (2016)
Liang WW, Liu ZW, Peng JJ, Zhou X, Wang X, Li Z, Energy Fuels, 33(1), 493 (2019)
