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Received January 26, 2021
Accepted May 3, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Separation of valuable metals from mixed cathode materials of spent lithium-ion batteries by single-stage extraction
Yongjie Li
Qiang Fu
Hongyun Qin
Kun Yang
Junnan Lv
Qicheng Zhang
Hui Zhang
Feng Liu
Xia Chen†
Ming Wang†
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255049, China
Korean Journal of Chemical Engineering, October 2021, 38(10), 2113-2121(9), 10.1007/s11814-021-0834-0
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Abstract
With the intensity of resource scarcities and environmental problems, the disposal and recovery of spent lithium-ion batteries, especially recovery of valuable metals, becomes vital. In this work, a method of co-extracting nickel, cobalt, manganese and being separated from lithium by single-stage solvent extraction is proposed. The extraction and separation process of D2EHPA was studied. The effects of extractant concentration, saponification percentage, extraction time and O:A on the extraction efficiency of D2EHPA were systematically studied. Nearly 100% manganese, 94% cobalt and about 90% nickel were co-extracted and separated from lithium using D2EHPA in kerosene by single-stage extraction. The maximum value of separation factors (βNi/Li, βCo/Li and βMn/Li) was 13.03, 23.42 and 1904.24. The mathematical model of extraction of four ions was developed by combination of Levenberg-Marquardt method and Universal Global Optimization method. The proposed extraction model accurately fits the experimental data and helps to predict the extraction efficiency of each metal under the corresponding conditions.
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