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Received June 16, 2020
Accepted October 3, 2020
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Bio-oil production from fast pyrolysis of furniture processing resid
1Department of Chemical Engineering, Kangwon National University, 346 Joongang-ro, Samcheok, Gangwon-do 25913, Korea 2Department of Chemical Engineering (Integrated Engineering), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin, Gyeonggi-do 17104, Korea 3Daekyung Esco, M-1903, 32, Songdowahak-ro, Yeonsu-gu, Incheon 21984, Korea
jkim21@khu.ac.kr
Korean Journal of Chemical Engineering, February 2021, 38(2), 306-315(10), 10.1007/s11814-020-0688-x
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Abstract
The pyrolysis characteristic of furniture processing residue (FPR), which was analyzed by thermogravimetric analysis (TGA) under nitrogen atmosphere, mainly decomposed between 230 °C and 500 °C. The FPR was submitted to fast pyrolysis in a bubbling fluidized-bed reactor (BFR) for converting into bio-oil, bio-char. The product distribution and characteristics of bio-oil depend on the operating conditions (temperature, fluidizing flow rate, particle size of sample). The bio-oil yield showed the highest value (50.68 wt%) at the pyrolysis temperature of 450 °C with a biomass particle size of 1.0mm and a fluidization velocity of 2.0×Umf. The bio-oil had high selectivity for dioctyl phthalate, levoglucosan, and phenolic derivatives. The carbon number proportions in bio-oils of FPR were 32.74wt% for C5- C11 fraction, 47.60 wt% for C12-C18 fraction and 19.38 wt% of C25-C38 fraction, respectively. The gas product included CO, CO2, H2, and hydrocarbons (C1-C4), and the selectivity of CO2 was the highest. The high heating value (HHV) of gas products was between 4.60 and 12.90 MJ/m3. The bio-char shows high HHV (23.87 MJ/kg) and high C content (62.47wt%) that can be applied as a solid fuel.
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