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Received July 7, 2020
Accepted October 28, 2020
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Synergetic formulation of Cyanex 272/Cyanex 302 for hexavalent chromium removal from electroplating wastewater
Raja Norimie Raja Sulaiman1 2
Norul Fatiha Mohd Noah1
Norasikin Othman1 2†
Norela Jusoh1
Muhammad Bukhari Rosly1
1School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bahru, Johor, Malaysia 2Centre of Lipids Engineering and Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310, Skudai, Johor Bahru, Johor, Malaysia
Korean Journal of Chemical Engineering, March 2021, 38(3), 514-522(9), 10.1007/s11814-020-0702-3
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Abstract
Hazardous hexavalent chromium (Cr(VI)) released from the electroplating industry beyond the discharge concentration limit has created great concern worldwide. Solvent extraction (SX) is an effective method for metal separation from an aqueous system. Throughout this work, novel synergistic solvent extraction of Cr(VI) from rinsed electroplating wastewater was performed using a mixture of two organophosphorus acidic extractants containing di-2,4,4-trimethylpentyl phosphinic acid (Cyanex 272) and di-2,4,4-trimethylpentyl mono-thio-phosphinic acid (Cyanex 302) in kerosene. The results showed almost 99±0.816% of Cr(VI) was synergistically reduced and extracted to the less toxic trivalent chromium (Cr(III)) using the total mixture concentration of 0.1 M (0.04M Cyanex 272+0.06 M Cyanex 302). For recycling, the organic phase was recycled or reused up to 11 times for excellent extraction (99±0.471%) and stripping (99±0.942%) and became stable afterwards until a certain time. The total concentration of the mixture system was reduced by 50% (0.05M) using 0.01 M Cyanex 272 and 0.04 M Cyanex 302, with almost 100% of Cr(VI) extraction as less toxic Cr(III). The Cr(III) in the loaded organic phase was completely recovered using 7.0M hydrochloric acid (HCl). It is concluded that the synergistic extraction using Cyanex 272/Cyanex 302 system improved the Cr(VI) extraction and reduced the chemical consumption in the organic phase.
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Kumar A, Thakur A, Panesar PS, J. Ind. Eng. Chem., 70, 394 (2019)
Bhosale VK, Chana HK, Kamble SP, Kulkarni PS, J. Water Process Eng., 32, 100925 (2019)
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Detchusananard T, Im-orb K, Marechal F, Arpornwichanop A, Energy, 207, 118190 (2020)
Pugliese D, Bella F, Cauda V, Lamberti A, Sacco A, Tresso E, Bianco S, ACS Appl. Mater. Interfaces, 21, 11288 (2013)
Miccoli B, Cauda V, Bonanno A, Sanginario A, Bejtka K, Bella F, Fontana M, Demarchi D, Sci. Rep., 6, 29763 (2016)
Bella F, Pugliese D, Nair JR, Sacco A, Bianco S, Gerbaldi C, Barolo C, Bongiovanni R, Phys. Chem. Chem. Phys., 15, 3706 (2013)
Huang M, Hong C, Ma C, Luo Z, Du S, Yang F, Sci. Rep., 10, 9129 (2020)
