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Received July 29, 2020
Accepted January 26, 2021
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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A novel synthesis of ditrimethylolpropane biphosphoramide diethyleneamine as flame retardant and antistatic textiles
Department of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City 132022, P. R. China 1Refinery of Jilin Petrochemical Company, Jilin City 132022, P. R. China 2Department of Chemistry, Inha University, Incheon 22212, Korea
jinfanlong@163.com
Korean Journal of Chemical Engineering, April 2021, 38(4), 872-884(13), 10.1007/s11814-021-0744-1
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Abstract
A novel phosphorous- and nitrogen-containing flame retardant, ditrimethylolpropane biphosphoramide diethyleneamine (DBD), was synthesized. Its chemical structure is characterized by Fourier-transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy. The effect of DBD on the physical, mechanical, and antistatic properties, thermal stability, and flame retardancy of wool fabric was systematically investigated. Thermogravimetric analysis showed that the initial decomposition temperature of DBD was 165 oC and 243 oC under nitrogen and air atmosphere, respectively. Furthermore, after 30 washes, the treated wool fabric exhibited excellent wash durability and good antistatic properties. Vertical burning tests indicated that both the burning time and char length of the treated wool fabric were lower than those of the flame-retardant standard, leading to a B1 flame retardant rating for the treated wool fabric. Compared to untreated wool fabric, the limiting oxygen index value of treated wool fabric increased significantly from 25.7% to 34.7%.
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